Methyl-Diethanolamine Degradation - Mechanism and Kinetics

Canadian Journal of Chemical Engineering

Volumn 75, Issue 5, 1997, Pages 861-871

  Chakma, A ^a,c   Meisen, A ^b  

^a UNIVERSITY OF CALGARY   (Canada)

^b UNIVERSITY OF BRITISH COLUMBIA   (Canada)

^c UNIVERSITY OF REGINA   (Canada)

Author keywords

Gas treating; Methyl diethanolamine; Reaction mechanism; Solvent degradation

Indexed keywords

CARBON DIOXIDE; DEGRADATION; GAS CHROMATOGRAPHY; HIGH TEMPERATURE EFFECTS; MASS SPECTROMETRY; MATHEMATICAL MODELS; PRESSURE EFFECTS; REACTION KINETICS; SOLUTIONS;

GAS TREATING PROCESSES; METHYL DIETHANOLAMINE; SOLVENT DEGRADATION;

AMINES;

EID: 0031248424     PISSN: 00084034     EISSN: None     Source Type: Journal    
DOI: 10.1002/cjce.5450750506     Document Type: Article

References (19)

1. Barth, D., C. Tondre, G. Lappai and J. J. Delpuech, "Kinetic Study of Carbon Dioxide Reaction With Tertiary Amines in Aqueous Solutions", J. Phys. Chem. 85, 3660-3667 (1981).
2. Barth, D., C. Tondre and J. J. Delpuech, "Kinetics and Mechanisms of the Reactions of Carbon Dioxide Reaction With Alkanolamines: A Discussion Concerning the Cases of MDEA and DEA", Chem. Eng. Sci. 39, 1753-1757 (1984).
3. 2S", Hydroc. Proc. 60, 111-116 (1981).
4. Chakma, A. and A. Meisen, "Identification of Methyl Diethanolamine Degradation Products by Gas Chromatography-Mass Spectrometry", J. Chromatogr. 457, 287-297 (1988).
5. 2 in Aqueous Methyldiethanolamine and N.N-Bis(hydroxyethyl)piperazine Solutions", Ind. Eng. Chem. Res. 26, 2461-2466 (1987).
6. Crooks, J. E. and J. P. Donnellan, "Kinetics of Reactions between Carbon Dioxide and Tertiary Amines", J. Org. Chem., 1372-1374 (1990).
7. Daviet, G. R., R. Sundermann, S. T. Donnely and J. A. Bullin, "Simulation Values Prove Out in DEA to MDEA Switch", Oil Gas J. 82, 47-50 (1984).
8. Donaldson, T. L. and Y. N. Nguyen, "Carbon Dioxide Reaction Kinetics and Transport in Aqueous Amine Membranes", Ind. Eng. Chem. Fundam., 19, 260-266 (1980).
9. 2 into Aqueous Methyldiethanolamine", Sep. Sci. Technol. 22, 921-947 (1987).
10. 2 in Aqueous Methyldiethanolamine Solutions", Ind. Eng. Chem. Process Des. Dev. 21, 539-544 (1982).
11. Kennard, M. L. and A. Meisen, "Gas Chromatographic Technique For Analysing Partially Degraded Diethanolamine Solutions", J. Chromatog. 267, 373-380 (1983).
12. Kennard, M. L. and A. Meisen, "Mechanisms and Kinetics of Diethanolamine Degradation", Ind. Eng. Chem. Fundam. 24, 129-140 (1985).
13. Littel, R. J., W. P. M. van Swaaij and G. F. Versteeg, "Kinetics of Carbon Dioxide with Tertiary Amines in Aqueous Solutions", AIChE J., 36, 1633-1640 (1990).
14. Matar, S. and L. F. Hatch, "Chemistry of Petrochemical Processes", Gulf Publishing Co., Houston, TX (1994).
15. Moore, C., "UBC NLP - Zeros of Nonlinear Equations", UBC NLP, University of B.C. Computing Centre Document, Vancouver, B.C. (1984).
16. 2O into Aqueous Solutions of Methyldiethanolamine", AIChE J., 35, 861-864 (1989).
17. Vaessen, W., "UBC NLP - Nonlinear Function Optimization", University of B.C. Computing Centre Document, Vancouver, B.C. (1983).
18. 2S Selectively From Sour Gas", Hydroc. Proc. 56, 333-337 (1977).
19. Yu, W. C., G. Astarita, and D. W. Savage, "Kinetics of carbon Dioxide Absorption in Solutions of Methyldiethanolamine", Chem. Eng. Sci. 40, 1585-1590 (1985).