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Volumn 101, Issue 44, 1997, Pages 8166-8173

Molecular mechanism of radiationless deactivation of aminoanthraquinones through intermolecular hydrogen-bonding interaction with alcohols and hydroperoxides

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; AROMATIC COMPOUNDS; ELECTRON ENERGY LEVELS; ELECTRON TRANSITIONS; FLUORESCENCE; HYDROGEN BONDS; HYDROGEN PEROXIDE; KETONES; REACTION KINETICS;

EID: 0031244738     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp970581n     Document Type: Article
Times cited : (96)

References (57)
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    • The correlation coefficient was greater than 0.995 in each case.
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    • note
    • -1, which is almost 10 times larger than the observed deactivation rate constants in ethanol. It strongly suggests that the rate-determining step of fluorescence decay in ethanol is the deactivation from the relaxed hydrogen-bonded excited state.
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