Kinetics of Selective Partial Oxidation of C3-C6 α-Olefins over an Iron Antimony Oxide Catalyst

Industrial and Engineering Chemistry Research

Volumn 36, Issue 9, 1997, Pages 3568-3575

  Schnobel, Michael ^a   Van Steen, Eric ^a  

^a UNIVERSITY OF CAPE TOWN   (South Africa)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST SELECTIVITY; DEHYDROGENATION; IRON COMPOUNDS; ISOMERIZATION; MATHEMATICAL MODELS; MOLECULAR STRUCTURE; OLEFINS; REACTION KINETICS;

CARBON NUMBER; IRON ANTIMONY OXIDE;

OXIDATION;

EID: 0031237177     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie960742u     Document Type: Article

References (17)

1. rd International Congress on Catalysis; Sachtler, W. H. M., Schuit, G. C. A., Zwietering, P., Eds.; North-Holland Publishing Co.: Amsterdam, 1965; p 240.
2. Allen, M.; Betteley, R.; Bowker, M.; Hutchings, G. J. The Partial Oxidation of Propene on Fe/Sb Oxide Catalysts. Catal. Today 1991, 9, 97.
3. 4 Mixed Oxides. I. Mechanism of Propene Oxidation. J. Catal. 1980, 64, 29.
4. Bielański, A.; Haber, J. Oxygen in Catalysis; Marcel Dekker Inc.: New York, 1991.
5. Borman, P. C.; Westerterp, K. R. An Experimental Study of the Kinetics of the Selective Oxidation of Ethene over a Silver on α-Alumina Catalyst. Ind. Eng. Chem. Res. 1995, 34, 49.
6. Burrington, J. D.; Kartisek, C. T.; Graselli, R. K. Surface Intermediates in Selective Propene Oxidation and Ammoxidation over Heterogeneous Molybdate and Antimonate Catalysts. J. Catal. 1984, 87, 363.
7. Carbucicchio, M.; Centi, G.; Trifiró, F. The Role of Excess Antimony as a Promoter of Activity and Selectivity in Selective Oxidation in the Fe-Sb System. J. Catal. 1985, 91, 85.
8. Draper, N. R.; Smith, H. Applied Regression Analysis, 2nd ed.; Wiley & Sons: New York, 1981.
9. Froment, G. F.; Hosten, L. H. Catalytic Kinetics: Modelling. In Catalysis Science and Technology; Anderson, J. R., Boudart, M., Eds.; Springer Verlag: Berlin, 1981; Vol. 2.
10. Keulks, G. W.; Lo, M.-Y. Catalytic Oxidation of Propylene. 11. An Investigation of the Kinetics and Mechanism over Iron Antimony Oxide. J. Phys. Chem. 1986, 90, 4768.
11. 12. J. Catal. 1980, 64, 295.
12. Mars, P.; van Krevelen, D. W. Oxidation carried out by means of Vanadium Oxide Catalysts. Chem. Eng. Sci. 1954, 3, 41.
13. 9. J. Catal. 1981, 68, 51.
14. Press, W. H.; Flannery, B. P.; Teukolsky, S. A.; Vetterling, W. T. Numerical Recipes in Pascal; Cambridge University Press: Cambridge, 1989.
15. Snyder, T. P.; Hill, C. G. The Mechanism for the Partial Oxidation of Propylene over Bismuth Molybdate Catalysts. Catal. Rev. Sci. Eng. 1989, 37, 43.
16. Tan, H. S.; Downie, J.; Bacon, D. W. The Kinetics of the Oxidation of Propylene over a Bismuth Molybdate Catalyst. Can. J. Chem. Eng. 1988, 66, 611.
17. van Steen, E.; Schnobel, M.; O'Connor, C. T. Selective Partial Oxidation of α-Olefins over Iron Antimony Oxide. In ACS Symposium Series; Oyama, S. T., Warren, B. K., Eds.; American Chemical Society: Washington, DC, 1996; Vol. 638, p 276.