Formation and characterization of self-assembled films of thiol-derivatized poly(dimethylsiloxane) on gold

Macromolecules

Volumn 30, Issue 19, 1997, Pages 5913-5919

  Tsao, Mei Wei ^a,d   Pfeifer, Karl Heinz ^a,e   Rabolt, John F ^a,d   Castner, David G ^b   Häussling, Lukas ^c   Ringsdorf, Helmut ^c  

^a IBM ALMADEN RESEARCH CENTER   (United States)

^b University of Washington   (United States)

^c JOHANNES GUTENBERG UNIVERSITY   (Germany)

^d UNIVERSITY OF DELAWARE   (United States)

^e BOEHRINGER INGELHEIM PHARMA GMBH AND CO KG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CALCULATIONS; CHARACTERIZATION; CHEMISORPTION; ELLIPSOMETRY; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GOLD; RUBBER FILMS; SECONDARY ION MASS SPECTROMETRY; SURFACES; WETTING; X RAY PHOTOELECTRON SPECTROSCOPY;

CONTACT ANGLE MEASUREMENT; POLYDIMETHYLSILOXANE; SURFACE WETTING;

POLYMERS;

EID: 0031234591     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma970126p     Document Type: Article

References (36)

1. Clarson, S. J.; Semlyen, J. A. Siloxane Polymers; PTR Prentice-Hall Inc.: New Jersey, 1993.
2. Owen, M. J. Ind. Eng. Chem. Prod. Res. Dev., 1980, 19, 97.
3. Arkles, B. CHEMTECH 1983, 542.
4. Wilbur, J. L.; Kim, E.; Xia, Y.; Whitesides, G. M. Adv. Mater. 1995, 7, 649.
5. (a) Polymeropoulos, E. E.; Sagiv, J. J. Chem. Phys. 1978, 69, 1836.
6. (b) Sagiv, J. J. Am Chem. Soc. 1980, 102, 92.
7. (c) Nuzzo, R. G.; Allara, D. L. J. Am. Chem. Soc. 1983, 105, 4481.
8. Swalen, J. D.; Allara, D. L.; Andrade, J. D.; Chandross, E. A.; Garoff, S.; Israelachvilli, J.; McCarthy, T. J.; Murray, R.; Pease, R. F.; Rabolt, J. F.; Wynne, K. J. Langmuir 1987, 3, 932.
9. Whitesides, G. M. Chimia 1990, 44, 310.
10. Ulman, A. An Introduction to Ultrathin Organic Films; Academic Press: New York, 1991.
11. Whitesides, G. M.; Ferguson, G. S.; Allara, D.; Scherson, D.; Speaker, L.; Ulman, A. Crit. Rev. Surf. Chem. 1993, 3 (1), 49-65.
12. Stouffer, J. M.; McCarthy, T. J. Macromolecules 1988, 21, 1204.
13. Lenk, T. J.; Hallmark, V. M.; Rabolt, J. F.; Häussling, L.; Ringsdorf, H. Macromolecules 1993, 26, 1230.
14. Sun, F.; Grainger, D. W.; Castner, D. G.; Leach-Scampavla, D. K. Macromolecules 1994, 27, 3053.
15. Rice, J. E.; Horn, H.; Lengsfield, B. H.; McLean, A. D.; Carter, J. T.; Replogle, E. S.; Barnes, L. A.; Maluendes, S. A.; Lie, G. C.; Gutowski, M.; Rudge, W. E.; Sauer, S. P. A.; Lindh, R.; Andersson, K; Chevalier, T. S.; Widmark, P.-O.; Bouzida, D.; Pacansky, G.; Singh, S.; Gillan, C. J.; Carnevali, P.; Swope, W. C.; Liu, B. Mulliken: a computational quantum chemistry program developed at International Business Machines Corp.
16. Tsao, M.-W.; Pfeiffer, K-H.; Rabolt, J. F.; Holt, D. B.; Farmer, B. L.; Interrante, L. V.; Shen, Q. Macromolecules. 1996, 29, 7130.
17. Application notes from Surface Science Instruments, Mountain View, CA, 1987.
18. Scofield, J. H. J. Electron. Spectrosc. Relat. Phenom. 1976, 8, 129.
19. Tyler, B. J.; Castner, D. G.; Ratner, B. D. J. Vac. Sci. Technol. 1989, A7, 1646.
20. Tyler, B. J.; Castner, D. G.; Ratner, B. D. Surf. Interface Anal. 1989, 14, 443.
21. Seah, M. P.; Dench, W. A. Surf. Interface Anal. 1979, 1, 2.
22. Osifchin, R. G.; Mahoney, W.; Andres, R. P.; Dorogi, M.; Reifenberger, R. G.; Feng, S.; Henderson, J. I.; Bein, T.; Kubiak, C. P. Polym. Mater. Sci. Eng. 1995, 73, 208.
23. Israelachvili, J. N. Intermodular & Surfaces Forces; Academic Press: San Diego, CA 1992.
24. Snyder, R. G.; Strauss, H. L.; Elliger, C. A. J. Phys. Chem. 1982, 86, 5145.
25. Smith, A. L. Spectrochim. Acta 1963, 19, 849.
26. Dobos, S.; Fogarasi, G.; Castellucci, E. Spectrochim. Acta 1972, 28, 877.
27. Pfeiffer, K-H.; Tsao, M.-W.; Rabolt, J. F. Manuscript in preparation.
28. All the calculated frequencies have all been scaled by 0.89 from the raw data because SCF harmonic vibrational frequencies determined at this level of theory typically overestimate the observed fundamentals by an average of 12%. See: (a) Hehre, W. H.; Radom, L.; Schleyer, P. v. R.; Pople, J. A. An Initio Molecular Orbital Theory; Wiley: New York, 1986. (b) Pople, J. A.; Head-Gordon, M.; Fox, D. J.; Raghavachari, K.; Curtiss, L. A. J. Chem. Phys. 1989, 90, 5622.
29. All the calculated frequencies have all been scaled by 0.89 from the raw data because SCF harmonic vibrational frequencies determined at this level of theory typically overestimate the observed fundamentals by an average of 12%. See: (a) Hehre, W. H.; Radom, L.; Schleyer, P. v. R.; Pople, J. A. An Initio Molecular Orbital Theory; Wiley: New York, 1986. (b) Pople, J. A.; Head-Gordon, M.; Fox, D. J.; Raghavachari, K.; Curtiss, L. A. J. Chem. Phys. 1989, 90, 5622.
30. Data adapted from: Lin-Vien, D.; Colthup, N. B.; Fateley, W. G.; Grasselli, J. G. The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules; Academic Press: San Diego, CA, 1991.
31. Granick, S.; Soga, I. Private communication.
32. Ren, Y.; Hoffmann, C. L.; Tsao, M.-W.; Rabolt, J. F.; Castner, D. G.; Hsu, S. L.; Häussling, L.; Ringsdorf, H. Manuscript in preparation.
33. Castner, D. G.; Hinds, K.; Grainger, D. W. Langmuir 1996, 12, 5083.
34. Bletsos, I. V.; Hercules, D. M.; van Leyen, D.; Benninghoven, A. Macromolecules 1987, 20, 407.
35. Zhang, X. K.; Stuart, J. O.; Clarson, S. J.; Sabata, A.; Beaucage, G. Macromolecules 1994, 27, 5229.
36. Miller, W. J.; Gupta, V. K.; Abbott, N. L.; Tsao, M.-W.; Rabolt, J. F. Liq. Cryst. 1997, 23, 175.