Copolymerization with depropagation: Experiments and prediction of kinetics and properties of α-methylstyrene/methyl methacrylate copolymers. I. Solution copolymerization

Journal of Applied Polymer Science

Volumn 65, Issue 12, 1997, Pages 2297-2313

  Martinet, F ^a   Guillot, J ^a  

^a CNRS LCPP   (France)

Author keywords

Ceiling temperature; Copolymer composition; Equilibrium of propagation; Glass transition temperature; Kinetics; Methyl methacrylate; Molecular weights; Software calculations; methylstyrene

Indexed keywords

COMPUTER SOFTWARE; COPOLYMERIZATION; FREE RADICAL POLYMERIZATION; GLASS TRANSITION; MATHEMATICAL MODELS; MICROSTRUCTURE; MOLECULAR WEIGHT; NITROGEN COMPOUNDS; POLYMETHYL METHACRYLATES; POLYSTYRENES; REACTION KINETICS; TOLUENE;

DEPROPAGATION; POLYMETHYL STYRENE; SOLUTION COPOLYMERIZATION;

COPOLYMERS;

EID: 0031233203     PISSN: 00218995     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1097-4628(19970919)65:12<2297::aid-app5>3.0.co;2-4     Document Type: Article

References (42)

1. W. C. Calvert, U.S. Pat. 2,908,661 (1957) (to Borg Warner).
2. High Polymers, Vol. XVIII, Interscience, New York, p. 476.
3. G. G. Lowry, J. Polym. Sci., 42, 463 (1960).
4. H. W. McCormick, J. Polym. Sci., 25, 111 (1957).
5. A. V. Golubeva, N. F. Usmanova, and K. A. Sivograkova, Soviet Plast., [English transl.], 12, 6
6. L. E. Erbaugh and J. D. Calfee, U.S. Pat. 2,921,932 (1960) (to Monsanto Chemical Co.).
7. P. Wittmer, Adv. Chem. Ser., 99, 140 (1971).
8. G. D. Jones, R. E. Friedrich, T. E. Werkema, and R. L. Zimmerman, Ind. Eng. Chem., 48, 2123 (1956).
9. D. J. Worsfold and S. Bywater, J. Am. Chem. Soc., 79, 4917 (1956).
10. A. B. Hersberger, J. G. Reid, and R. G. Heilingman, Ind. Eng. Chem., 37, 1073 (1945).
11. I. V. Andreeva and M. M. Koton, Izvest. Akad. Nauk SSSR, 3, 552 (1959).
12. A. V. Golubeva, N. F. Usmanova, and A. A. Vansheidt, J. Polym. Sci., 52, 63 (1961).
13. J. M. G. Cowie, Eur. Polym. J., 11, 297 (1974).
14. N. W. Johnston, Macromolecules, 6, 453 (1973).
15. T. G. Fox, Bull. Am. Phys. Soc., 1, 123 (1956).
16. F. S. Dainton and K. J. Ivin, Nature, 162, 705 (1948).
17. F. S. Dainton and K. J. Ivin, Q. Rev. (Lond.), 12, 61 (1958).
18. D. J. Worsfold and S. Bywater, J. Polym. Sci., 26, 299 (1957).
19. D. J. Worsfold and S. Bywater, Can. J. Chem., 36, 1141 (1958).
20. H. Hoppf and H. Lüssi, Makromol. Chem., 62, 31 (1963).
21. D. E. Roberts and R. S. Jessup, J. Res. Natl. Bur. Std., 46, 11 (1951).
22. B. J. Cottam, J. M. G. Cowie, and S. Bywater, Makromol. Chem., 86, 116 (1965).
23. R. E. Cunningham, Polymer, 19, 729 (1978).
24. Polymer Handbook, 3d ed., Brandrup and Immergut, Eds., Wiley-Interscience, New York.
25. S. Bywater, Trans. Faraday Soc., 51, 1267 (1955).
26. T. Otsu, B. Yamada, T. Mari, and M. Inoue, J. Polym. Sci., Polym. Lett. Ed., 14, 283 (1976).
27. G. E. Ham, J. Polym. Sci., 45, 169 (1960).
28. G. E. Ham, J. Polym. Sci., 45, 177 (1960).
29. G. E. Ham, J. Polym. Sci., 45, 183 (1960).
30. K. F. O'Driscoll and F. P. Gaspacho, J. Macromol. Sci. Chem., A1, 643 (1967).
31. K. F. O'Driscoll and J. R. Dickson, J. Macromol. Sci. Chem. Part A2, 3, 449 (1968).
32. M. Izu and K. F. O'Driscoll, J. Polym. Sci. Part A1, 8, 1675 (1970).
33. M. Izu and K. F. O'Driscoll, J. Polym. Sci. Part A1, 8, 1687 (1970).
34. B. K. Kang, K. F. O'Driscoll, and J. A. Howel, J. Polym. Sci. A1, 10, 2349 (1972).
35. B. K. Kang and K. F. O'Driscoll, Macromolecules, 7, 886 (1974).
36. K. J. Ivin and R. H. Spensley, J. Macromol. Sci., A1, 653 (1967).
37. K. J. Ivin, Pure Appl. Chem., 4, 271 (1962).
38. J. P. Fischer, Makromol. Chem., 155, 211 (1972).
39. P. Wittmer, Makromol. Chem., 103, 188 (1967).
40. P. Wittmer, Makromol. Chem., 177, 991 (1976).
41. S. Benson, Foundations of Chemical Kinetics, McGraw-Hill, New York, 1960, p. 503.
42. F. L. Marten and A. E. Hamielec, ACS Symp. Ser., 104, 43 (1979).