Standard free enthalpy of formation of Fe(II)-Fe(III) hydroxysulphite green rust one and its oxidation into hydroxysulphate green rust two

Corrosion Science

Volumn 39, Issue 9, 1997, Pages 1673-1685

  Simon, L ^a   Genin J M R ^a   Refait, Ph ^a  

^a Laboratoire de Chimie Physique et Microbiologie pour l'Environnement   (France)

Author keywords

A. Green Rusts; B. M ssbauer spectroscopy; B. XRD; C. oxidation; C. Pourbaix diagram

Indexed keywords

COMPOSITION; ELECTROCHEMICAL ELECTRODES; ENTHALPY; FREE ENERGY; INTERCALATION COMPOUNDS; IRON COMPOUNDS; MOSSBAUER SPECTROSCOPY; PH; PHASE DIAGRAMS; PHASE EQUILIBRIA; X RAY DIFFRACTION ANALYSIS;

GREEN RUST; IRON HYDROXYSULPHITE; POURBAIX DIAGRAM; STANDARD FREE ENTHALPY OF FORMATION;

OXIDATION;

ENTHALPY; IRON; OXIDATION;

EID: 0031231035     PISSN: 0010938X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0010-938X(97)00074-7     Document Type: Article

References (25)

1. J.D. Bernal, D.R. Dasgupta and A.L. Mackay, Clay Min. Bull. 4, 15-30 (1959).
2. F. Trolard, M. Abdelmoula, G. Bourrié, B. Humbert and J.-M.R. Génin, C. R. Acad. Sci. 323(2A), 1015-1022 (1996).
3. J. Vins, J. Subrt, V. Zapletal and F. Hanousek, Coll. Czech. Chem. Commun. 52, 93-102 (1987).
4. Ph. Refait and J.-M.R. Génin, Corros. Sci. 34, 797-819 (1993).
5. A.A. Olowe and J.-M.R. Génin, Corros. Sci. 32, 965-984 (1991).
6. J.-M.R. Génin, A.A. Olowe, Ph. Refait and L. Simon, Corros. Sci. 38, 1751-1762 (1996).
7. S.H. Drissi, Ph. Refait, M. Abdelmoula and J.-M.R. Génin, Corros. Sci. 37, 2025-2041 (1995).
8. J.-M.R. Génin, L. Simon and Ph. Refait, SIF Conf. Proc. 50, 51-55 (1996).
9. Ph. Refait, C. Bon, G. Bourrié, F. Trolard, J. Bessière and J.-M.R. Génin, The standard free enthalpy of formation of Green Rusts: Fe(II)-Fe(II) hydroxy-sulphate, -chloride and -carbonate. Clay Min., submitted.
10. R.M. Taylor, Clay Min. 15, 369-382 (1980).
11. H.C.B. Hansen, Clay Min. 24, 663-669 (1989).
12. R. Allmann, Chimia 24, 99-108 (1970).
13. H.F.W. Taylor, Min. Mag. 39, 377-389 (1973).
14. Ph. Refait and J.-M.R. Génin, The mechanism of oxidation of Ni(II)-Fe(II) hydroxides in chloride-containing aqueous media: role of the pyroaurite-type of Ni-Fe hydroxychlorides, Clay Min. in press, (1997).
15. H.C.B. Hansen, O.K. Borggaard and J. Sørensen, Geochim. et Cosmochim. Acta 58, 2599-2608 (1994).
16. R. Allmann, Acta Cryst. B24, 972-977 (1968).
17. L. Ingram and H.F.W. Taylor, Min. Mag. 36, 465-479 (1967).
18. R.M. Garrels and C.L. Christ, Solutions, Minerals and Equilibria. Harper and Row, New York, 1965, p. 450.
19. Ph. Refait and J.-M.R. Génin, Corros. Sci. 36, 55-64 (1994).
20. S. Miyata, Clays Clay Min. 31, 305-311 (1983).
21. A. Mendiboure and R. Schöllhorn, Rev. Chim. Min. 23, 819-827 (1986).
22. K. Hashimoto and T. Misawa, Corros. Sci. 13, 229-231 (1973).
23. D.D. Wagman, W.H. Evans, V.B. Parker, R.H. Schumm, I. Halow, S.M. Bailey, K.L. Churney and R.L. Nutall, J. Phys. Chem. Ref. Data 11(suppl.2), 1 (1982).
24. M. Pourbaix and A. Pourbaix, Rapports Techniques CEBELCOR 159, 299 (1990).
25. G.H. Kelsall and R.A. Williams, J. Electrochem. Soc. 138, 931-940 (1991).