The molecular basis of fracture in crosslinked glassy polymers

Journal of Applied Polymer Science

Volumn 65, Issue 5, 1997, Pages 1001-1011

  Sambasivam, M ^a,c   Klein, A ^a,b   Sperling, L H ^a,b  

^a LEHIGH UNIVERSITY   (United States)

^b Lehigh University   (United States)

^c Polyset Company   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIUM COMPOUNDS; CARBOXYLIC ACIDS; CHEMICAL BONDS; CROSSLINKING; FRACTURE TESTING; HYDROLYSIS; MOLECULAR STRUCTURE; PHOTOCHEMICAL REACTIONS; POLYMERIZATION; POLYMETHYL METHACRYLATES; POLYSTYRENES;

ACRYLIC ACID ANHYDRIDE; FRACTURE ENERGY; METHACRYLIC ACID ANHYDRIDE;

POLYMERIC GLASS;

EID: 0031208958     PISSN: 00218995     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1097-4628(19970801)65:5<1001::aid-app18>3.0.co;2-4     Document Type: Article

References (33)

1. N. Mohammadi, A. Klein, and L. H. Sperling, Macromolecules, 26, 1019 (1993).
2. M. Sambasivam, A. Klein, and L. H. Sperling, Macromolecules, 28, 152 (1995).
3. A. J. Kinloch and R. J. Young, Fracture Behavior of Polymers, 2nd ed., Applied Science Publishers, London, 1983.
4. H.-H. Kausch, Polymer Fracture, 2nd ed., Springer Verlag, Berlin, 1987.
5. N. R. Langley and K. E. Polmanter, J. Polym. Sci., Polym. Phys. Ed., 12, 1023 (1974).
6. L. J. Broutman and F. J. McGarry, J. Appl. Polym. Sci., 9, 609 (1965)
7. J. P. Berry, Fracture VII, Liebowitz, Ed., Academic Press, New York, 1972.
8. P. J. Flory, N. Rabjohn, and M. C. Shaffer, J. Polym. Sci,. 4, 435 (1949).
9. R. Natarajan and P. E. Reed, J. Polym. Sci. A-2, 10, 585 (1972).
10. A. N. Gent, G. L. Liu, and M. Mazurek, J. Polym. Sci., Polym. Phys. Ed., 32, 271 (1994).
11. D. L. Siegfried, J. A. Manson, and L. H. Sperling, J. Polym. Sci., Polym. Phys., 16, 583 (1978).
12. J. R. Millar, J. Chem. Soc., 1311 (1960).
13. K. Shibyama and Y. Suzuki, Kobunshi Kagaku, 23, 24 (1966).
14. J. L. Thiele and R. E. Cohen, Polym. Eng. Sci., 19, 284 (1979).
15. M. Sambasivam, A. Klein, and L. H. Sperling, J. Appl. Polym. Sci., 58, 357 (1995).
16. M. Sambasivam, A. Klein, and L. H. Sperling, Polym. Adv. Technol., 7, 507 (1996).
17. L. H. Sperling, K. B. Ferguson, J. A. Manson, E. M. Corwin, and D. L. Siegfried, Macromolecules, 9, 743 (1976).
18. P. J. Flory and J. Rehner, J. Chem. Phys., 11, 521 (1943).
19. L. H. Sperling, Introduction to Physical Polymer Science, 2nd ed., John Wiley & Sons, Inc., New York, 1992, p. 414.
20. K. E. Evans, J. Polym. Sci., Polym. Phys. Ed., 25, 353 (1987).
21. G. J. Lake and A. G. Thomas, Proc. R. Soc. Lond. Ser. A, A300, 108 (1967).
22. M. J. Sundell, E. O. Pajunen, O. E. Hormi, and J. H. Nasman, J. Polym. Sci., Polym. Chem. Ed., 31, 2305 (1993).
23. R. A. Pearson and A. F. Yee, J. Mater. Sci., 24, 2571 (1986).
24. (a) R. P. Wool, Structure and Strength of Polymer Interfaces, Hanser Press, New York, 1995;
25. (b) R. P. Wool, Macromolecules, 26, 1574 (1993).
26. H. Mark, Cellulose and Cellulose Derivatives, Vol. IV, Emil Ott, Ed., Interscience Publishers Inc., New York, 1943.
27. M. Sambasivam, A. Klein, and L. H. Sperling, J. Polym. Mater., 13, 1 (1996).
28. M. Sambasivam, A. Klein, and L. H. Sperling, in Film Formation in Waterborne Coatings, T. Provder, M. A. Winnik, and M. W. Urban, Eds., ACS Symp. Ser. No. 648, American Chemical Society, Washington, DC, 1996.
29. N. R. Langley, Macromolecules, 1, 348 (1968).
30. P. J. Flory, Chem. Rev., 35, 51 (1944).
31. J. Scanlan, J. Polym. Sci., 43, 501 (1960).
32. P. Miller and E. J. Kramer, J. Mater. Sci., 25, 1751 (1990).
33. E. J. Kramer, in Advances in Polymer Science, vols. 52/53, Springer Verlag, Berlin, 1983.