Photodissociation of HCl at 193.3 nm: Spin-orbit branching ratio

Journal of Chemical Physics

Volumn 107, Issue 5, 1997, Pages 1403-1405

  Zhang, J ^a,b   Dulligan, M ^a   Wittig, C ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRON ENERGY LEVELS; ELECTRON TRANSITIONS; HYDROCHLORIC ACID; HYDROGEN; LASER APPLICATIONS; PHOTOLYSIS; POLARIZATION; SPECTRUM ANALYSIS; ULTRAVIOLET RADIATION;

ATOM ANGULAR DISTRIBUTION; PHOTODISSOCIATION; PHOTOEXCITATION; SPIN ORBIT BRANCHING RATIO; ULTRAVIOLET PHOTOLYSIS LASER POLARIZATION;

PHOTOCHEMICAL REACTIONS;

EID: 0031206761     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.474494     Document Type: Article

References (25)

1. E. F. van Dishoeck, M. C. van Hemert, and A. Dalgarno, J. Chem. Phys. 77, 3693 (1982).
2. (a) Y. Matsumi, P. K. Das, and M. Kawasaki, J. Chem. Phys. 92, 1696 (1990);
3. (b) Y. Matsumi, K. Tonokura, M. Kawasaki, and T. Ibuki, ibid. 93, 7981 (1990).
4. E. Tiemann, H. Kanamori, and E. Hirota, J. Chem. Phys. 88, 2457 (1988).
5. J. Park, Y. Lee, and G. W. Flynn, Chem. Phys. Lett. 186, 441 (1991); 192, 138 (1992).
6. J. Park, Y. Lee, and G. W. Flynn, Chem. Phys. Lett. 186, 441 (1991); 192, 138 (1992).
7. (a) Y. Matsumi, P. K. Das, and M. Kawasaki, K. Tonokura, T. Ibuki, G. Inoue, S. Satyapal, and R. Bersohn, J. Chem. Phys. 97, 5261 (1992);
8. (b) K. Tonokura, Y. Matsumi, M. Kawasaki, S. Tasaki, and R. Bersohn, ibid. 97, 8210 (1992).
9. R. Liyanage, Y. Yang, S. Hashimoto, R. J. Gordon, and R. W. Field, J. Chem. Phys. 103, 6811 (1995).
10. S. C. Givertz and G. G. Balint-Kurti, J. Chem. Soc. Faraday Trans. 82, 1231 (1986).
11. M. H. Alexander, B. Pouilly, and T. Duhoo, J. Chem. Phys. 99, 1752 (1993).
12. I. H. Gersonde, S. Hennig, and H. Gabriel, J. Chem. Phys. 101, 9558 (1994).
13. T. Duhoo and B. Pouilly, J. Chem. Phys. 103, 182 (1995).
14. L. Schneider, W. Meier, K. H. Welge, M. N. R. Ashfold, and C. Western, J. Chem. Phys. 92, 7027 (1990).
15. J. Segall, Y. Wen, R. Lavi, R. Singer, and C. Wittig, J. Phys. Chem. 95, 8078 (1991).
16. J. Zhang, C. W. Riehn, M. Dulligan, and C. Wittig, J. Chem. Phys. 104, 7027 (1996).
17. The polarization of the polarizer at 193.3 nm was estimated by the following approaches: (a) our previous study on HF (Ref. 13);
18. (b) a calculation based on discussions in Chapter 5, Handbook of Optics, edited by M. Bass et al. (McGraw-Hill, New York, 1995);
19. polarization measurement at 266 nm (polarized output from a Nd:YAG laser) and extrapolation to 193.3 nm.
20. C. E. Moore, Atomic Energy Levels (National Stand. Ref. Data Ser., National Bureau of Standards, Washington District of Columbia, 1971).
21. K. P. Huber and G. Herzberg, Molecular Spectra and Molecular Structure IV. Constants of Diatomic Molecules (Van Nostrand, New York, 1979).
22. R. N. Zare, Mol. Photochem. 4, 1 (1972).
23. M. Dzvonik, S. Yang, and R. Bersohn, J. Chem. Phys. 61, 4408 (1974).
24. G. N. A. Van Veen, K. A. Mohamed, T. Baller, and A. E. De Vries, Chem. Phys. 80, 113 (1983).
25. S. J. Singer, K. F. Freed, and Y. B. Band, Adv. Chem. Phys. 61, 1 (1985).