Evolution and impact of temperature patterns during hydrogen oxidation on a Ni ring

Chemical Engineering Science

Volumn 52, Issue 14, 1997, Pages 2331-2341

  Somani, M ^b   Liauw, M A ^a,b   Luss, D ^b  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b University of Houston   (United States)

Author keywords

Global coupling; Hydrogen oxidation; Rate enhancement; Spatiotemporal pattern

Indexed keywords

CATALYSTS; HYDROGEN; MIXING; NICKEL; OSCILLATIONS; REACTION KINETICS; THERMAL EFFECTS;

NICKEL RING; ROTATING TEMPERATURE PULSES; SPATIOTEMPORAL PATTERNS;

OXIDATION;

EID: 0031193855     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2509(97)00004-3     Document Type: Article

References (47)

1. Bangia, A. K., Bär, M., Kevrekidis, I. G., Graham, M. D., Rotermund, H.-H. and Ertl, G. (1996) Catalysis on microcomposite surfaces. Chem. Engng Sci. 51, 1757-1765.
2. Bär, M., Hildebrand, M., Eiswirth, M., Falcke, M., Engel, H. and Neufeld, M. (1994) Chemical turbulence and standing waves in a surface reaction model: the influence of global coupling and wave instabilities. CHAOS 4, 499-508.
3. Bassett, M. R. and Hudson, J. L. (1989) Quasi-periodicity and chaos during an electrochemical reaction. J. Phys. Chem. 93, 2731-2737.
4. Bugrim, A. E., Zhabotinsky, A. M. and Epstein, I. R. (1995) Mechanism for spontaneous formation of crossing chemical waves in a startified reaction-diffusion system. J. Phys. Chem. 99, 15,930-15,933.
5. Cross, M. C. and Hohenberg, P. C. (1993) Pattern formation outside of equilibrium. Rev. Mod. Phys. 65, 851-1112.
6. Elmer, F. J. (1988) Nonlinear and nonlocal dynamics of spatially extended systems: stationary states, bifurcations and stability. Physica D 30, 321-342.
7. Elmer, F. J. (1992) Limit-cycles of the ballast resistor caused by intrinsic instabilities. Z. Physik B 87, 377-386.
8. Field, R. J. and Burger, M. (1985) Oscillations and Traveling Waves in Chemical Systems. Wiley, New York.
9. Flätgen, G. and Krischer, K. (1995) Accelerating fronts in an electrochemical system due to global coupling. Phys. Rev. E 51, 3997-4004.
10. Glass, L. and Mackey, M. C. (1988) From Clocks to Chaos: The Rhythms of Life, pp. 155-169. Princeton University Press, Princeton, NJ.
11. Graham, M. D., Lane, S. L. and Luss, D. (1993) Temperature pulse dynamics on a catalytic ring. J. Phys. Chem. 97, 7564-7571.
12. Graham, M. D., Kevrekidis, I. G., Asakura, K., Lauterbach, J., Krischer, K., Rotermund, H.-H. and Ertl, G. (1994) Effects of boundaries on pattern formation: catalytic oxidation of CO on platinum. Science 264, 80-82.
13. Graham, M. D., Bär, M., Kevrekidis, I. G., Asakura, K., Lauterbach, J., Rotermund, H.-H. and Ertl, G. (1995) Catalysis on microstructured surfaces: pattern formation during CO oxidation in complex Pt domains. Phys. Rev. E 52, 76-93.
14. Haas, G., Bär, M., Kevrekidis, I. G., Rasmussen, P. B., Rotermund, H.-H. and Ertl, G. (1995) Observation of front bifurcations in controlled geometries: from one to two dimensions. Phys. Rev. Lett. 75, 3560-3563.
15. Hagberg, A. and Meron, E. (1994) Pattern formation in non-gradient reaction-diffusion systems: the effects of front bifurcations. Nonlinearity 7, 805-835.
16. Hagberg, A., Meron, E., Rubinstein, I. and Zaltzman, B. (1996) Controlling domain patterns far from equilibrium. Phys. Rev. Lett. 76, 427-430.
17. Kapral, R. (1995) Pattern formation in chemical systems. Physica D 86, 149-157.
18. Karfunkel, H. R. and Seelig, F. F. (1975) Excitable chemical reaction systems I. definition of excitability and simulation of model systems. J. Math. Biol. 2, 123-132.
19. Kreisberg, N., McCormick, W. D. and Swinney, H. L. (1989) Symmetry breaking in a chemical pinwheel. J. Chem. Phys. 91, 6532-6533.
20. Kulka, A., Bode, M. and Purwins, H. G. (1995) On the influence of inhomogeneities in a reaction-diffusion system. Phys. Lett. A 203, 33-39.
21. Kurtanjek, Z., Sheintuch, M. and Luss, D. (1980) Surface state and kinetic oscillations in the oxidation of hydrogen on nickel. J. Catal 66, 11-27.
22. Lane, S. L. and Luss, D. (1993) Rotating temperature-pulse during hydrogen oxidation on a nickel ring. Phys. Rev. Lett. 70, 830-832.
23. Lane, S. L., Graham, M. D. and Luss, D. (1993) Spatiotemporal temperature patterns during hydrogen oxidation on a nickel disk. A.I.Ch.E. J. 39, 1497-1508.
24. Lee, K.-J., McCormick, W. D., Pearson, J. E. and Swinney, H. L. (1994) Experimental observation of self-replicating spots in a reaction-diffusion system. Nature 369, 215-218.
25. Lev, O., Sheintuch, M., Yarnitsky, H. and Pismen, L. M. (1990) Spatial current distribution during nickel anodic dissolution in sulfuric acid. Chem. Engng Sci. 45, 839-847.
26. Liauw, M. A., Jaeger, N. I. and Plath, P. J. (1993) Periodic perturbation of a drifting heterogeneous catalytic system. J. Phys. Chem. 97, 11,724-11,730.
27. Liauw, M. A., Ning, J. and Luss, D. (1996) Pattern formation on a nonuniformly active ring. J. Chem. Phys. 104, 5657-5662.
28. Lobban, L. and Luss, D. (1989) Spatial temperature oscillations during hydrogen oxidation on a nickel foil. J. Phys. Chem. 93, 6530-6533.
29. Mayer, A. G. (1914) The relation between the degree of concentration of the electrolytes of sea-water and the rate of nerve-conduction in cassiopea. Papers from the Marine Biological Laboratory at Tortugas 6, 25-54.
30. Middya, U., Luss, D. and Sheintuch, M. (1994) Spatiotemporal motions due to global interaction. J. Chem. Phys. 100, 3568-3581.
31. Middya, U. and Luss, D. (1995) Impact of global interaction on pattern formation on a disk. J. Chem. Phys. 102, 5029-5036.
32. Mikhailov, A. S. (1990) Foundations of Synergetics I: Distributed Active Systems. Springer, Berlin.
33. Nicolis, G. and Prigogine, I. (1977) Self-Organization in Nonequilibrium Systems. Wiley, New York.
34. Noszticzius, Z., Horsthemke, W., McCormick, W. D. and Swinney, H. L. (1987) Sustained chemical waves in an annular gel reactor: a chemical pin-wheel. Nature 329, 619-620.
35. Otterstedt, R. D., Plath, P. J., Jaeger, N. I. and Hudson, J. L. (1996) Rotating waves on disk and ring electrodes. J. Chem. Soc., Faraday Trans. 92, 2933-2939.
36. Sayer, J. C. and Hudson, J. L. (1995) Spatiotemporal patterns on a ring electrode. Ind. Engng Chem. Res. 34, 3246-3251.
37. Schütz, P., Bode, M. and Purwins, H. G. (1995) Bifurcations of front dynamics in a reaction-diffusion system with spatial inhomogeneities. Physica D 82, 382-397.
38. Sheintuch, M. (1989) Spatio-temporal structures of controlled catalytic wires. Chem. Engng Sci. 44, 1081-1089.
39. Silveston, P., Hudgins, R. R., and Renken, A. (1995) Periodic operation of catalytic reactors-introduction and overview. Catal. Today 25, 91-112.
40. Somani, M., Liauw, M. A. and Luss, D. (1996) Hot spot formation on a catalyst. Chem. Engng Sci. 51, 4259-4269.
41. Steinbock, O., Kettunen, P. and Showalter, K. (1995) Anisotropy and spiral organizing centers in patterned excitable media. Science 269, 1857-1860.
42. Terman, D. and Wang, D. (1995) Global competition and local cooperation in a network of neural oscillators. Physica D 81, 148-176.
43. 2 oxidation on Ni. Surf. Sci. 187, 165-174.
44. Tyson, J. J. and Keener, J. P. (1988) Singular perturbation theory of traveling waves in excitable media. Physica D 32, 327-361.
45. Veser, G., Mertens, F., Mikhailov, A. S. and Imbihl, R. (1993) Global coupling in the presence of defects: synchronization in an oscillatory surface reaction. Phys. Rev. Lett. 71, 935-938.
46. Willebrand, H., Hünteler, T., Niedernostheide, F.-J., Dohmen, R. and Purwins, H.-G. (1992) Periodic and turbulent behavior of solitary structures in distributed active media. Phys. Rev. A 45, 8766-8775.
47. Yamamoto, S. Y., Surko, C. M., Maple, M. B. and Pina, R. K. (1995) Pulse propagation in the catalytic oxidation of carbon monoxide on platinum. Phys. Rev. Lett. 74, 4071-4074.