Synthesis of high molecular weight nylon 6 by anionic polymerization of ε-caprolactam. Mechanism and kinetics

Polymer Journal

Volumn 29, Issue 7, 1997, Pages 568-573

  Ueda, Kazue ^a   Nakai, Makoto ^a   Hosoda, Masahiro ^a   Tai, Kazuo ^a  

^a UNITIKA LTD   (Japan)

Author keywords

Anionic Polymerization; High Molecular Weight; Kinetics; Mechanism; Nylon 6; Schlenk Equilibrium; Caprolactam

Indexed keywords

ACTIVATION ENERGY; ANIONIC POLYMERIZATION; CATALYSTS; COMPOSITION EFFECTS; INITIATORS (CHEMICAL); MONOMERS; NUMERICAL METHODS; REACTION KINETICS; SYNTHESIS (CHEMICAL);

CAPROLACTAM; SCHLENK EQUILIBRIUM;

NYLON POLYMERS;

EID: 0031192703     PISSN: 00323896     EISSN: None     Source Type: Journal    
DOI: 10.1295/polymj.29.568     Document Type: Article

References (35)

1. J. Sebenda, "Comprehensive Chemical Kinetics," Vol. 15, C. H. Bamfordand and C. F. H. Tipper, Ed., Elsevier, Amsterdam, 1976, p 279.
2. H. Sekiguchi, "Ring-opening Polymerization," Vol. 2, K. J. Ivin and T. Saegusa, Ed., Elsevier, London, 1984, p 832.
3. J. Sebenda, "Comprehensive Polymer Science,"Vol. 3, C. F. H. Tipper and C. H. Bamford, Ed., Pergamon Press, Oxford, 1988.
4. R. Puffr, "Lactam-Based Polyamides," Vol. 1, R. Puffr and V. Kubánek, Ed., CRC Press, Boca Raton, 1991.
5. J. Sebenda and J. Kralicek, Collect. Czech. Chem. Commun., 23, 766 (1958).
6. O. Wichterle, J. Sebenda, and J. Kralicek, Fortsch. Hochpolym. Forsch., 2, 578 (1961).
7. J. Sebenda, J. Macromol. Sci. Chem., A6, 1145 (1972).
8. G. Champetier and H. Sekiguchi, J. Polym. Sci., 48, 309 (1960).
9. H. Sekiguchi and B. Coutin, J. Polym. Sci., Chem. Ed., 11, 1601 (1973).
10. T. M. Frunze, V. A. Kotel'nikov, T. V. Volkova, V. V. Kurashev, S. P. Davtyan, and V. V. Korshak, Dokl. Akad. Nauk S.S.S.R., 255, 612 (1980).
11. T. M. Frunze, V. A. Kotel'nikov, T. V. Volkova, V. V. Kurashev, S. P. Davtyan, and I. V. Stankevich, Acta Polym., 32, 31 (1981).
12. T. M. Frunze, V. A. Kotel'nikov, T. V. Volkova, and V. V. Kurashev, Eur. Polym. J., 17, 1079 (1981).
13. N. Mougin, C. A. Veith, R. E. Cohen, and Y. Gnanou, Macromolecules, 25, 2004 (1992).
14. N. Mougin, P. Rempp, and Y. Gnanou, Macromolecules, 25, 6739 (1992).
15. H. Tani and T. Konomi, J. Polym. Sci., Part A-1, 6, 2295 (1968).
16. E. Sittler and J. Sebenda, Collect. Czech. Chem. Commun., 33, 270 (1968).
17. E. Sittler and J. Sebenda, Collect. Czech. Chem. Commun., 33, 3182 (1968).
18. J. Sebenda, J. Polym. Sci., Part C, 23, 169 (1968).
19. A. Rigo, G. Fabbri, and G. Talamini, J. Polym. Sci., Polym. Lett. Ed., 13, 469 (1975).
20. J. Sebenda, A. Stiborová, L. Lochman, and Z. Bukac, Org. Prepr. Proced. Int., 12, 289 (1980); Chem. Abstr., 94, 16165 (1981).
21. J. Sebenda, A. Stiborová, L. Lochman, and Z. Bukac, Org. Prepr. Proced. Int., 12, 289 (1980); Chem. Abstr., 94, 16165 (1981).
22. S. A. Bolgov, V. P. Begishev, A. Ya. Malkin, and V. G. Frolov, Polym. Sci., U.S.S.R., 23, 1485 (1981).
23. J. Stehlicek, J. Labsky, and J. Sebenda, Collect. Czech. Chem. Commun., 32, 545 (1987).
24. T. M. Frunze, S. P. Davtyan, V. A. Kotel'nikov, T. V. Volkova, and V. V. Kurashev, Vysokomol. Soedin., Ser. B, 23, 388 (1981).
25. V. G. Frolov, Vysokomol. Soedin., Ser. B, 25, 134 (1983).
26. S. Barzakay, M. Levy, and D. Vofsi, J. Polym. Sci., Part A-1, 5, 965 (1967).
27. J. Stehlicek and R. Puffr, Macromol. Chem., 193, 2539 (1992).
28. R. Z. Greenley, J. C. Stauffer, and J. E. Kurz, Macromolecules, 2, 561 (1969).
29. D. J. Lin, J. M. Ottino, and E. L. Thomas, Polym. Eng. Sci., 25, 1155 (1985).
30. K. Ueda, K. Yamada, M. Nakai, T. Matsuda, M. Hosoda, and K. Tai, Polym. J., 28, 446 (1996).
31. K. Ueda, M. Nakai, M. Hosoda, and K. Tai, Polym. J., 28, 1084 (1996).
32. S. Barzakay, M. Levy, and D. Vofsi, J. Polym. Sci. Part A-1, 4, 2211 (1966).
33. H. Sekiguchi, Bull. Soc. Chim. Fr., 1831 (1960).
34. Y. Yamamoto and Y. Naruta, "Yukikagakukoza, Vol. 6, Yukikinzokukagaku," Maruzen, Tokyo,1983, p 29.