Preparation of hyperbranched macromolecules with aryl fluoride and phenol terminal functionalities using new monomers and Cs2CO3 or Mg(OH)2 as the condensation agent

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 35, Issue 10, 1997, Pages 2015-2033

  Martínez, Coromoto A ^a   Hay, Allan S ^a  

^a MCGILL UNIVERSITY   (Canada)

Author keywords

Aryl ether sulfone; Divergent approach; Hyperbranched; Polycondensation

Indexed keywords

AGENTS; CESIUM COMPOUNDS; CHEMICAL ACTIVATION; MAGNESIUM COMPOUNDS; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHENOLS; POLYCONDENSATION; SIZE EXCLUSION CHROMATOGRAPHY; SULFUR COMPOUNDS; SYNTHESIS (CHEMICAL); THERMODYNAMIC STABILITY;

ARYL FLUORIDE; DIVERGENT APPROACH; HYPERBRANCHED MACROMOLECULES; INTERNAL CYCLIZATION; PHENOL TERMINAL FUNCTIONALITY; SULFONE MOIETY;

MACROMOLECULES;

EID: 0031186679     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0518(19970730)35:10<2015::AID-POLA17>3.0.CO;2-J     Document Type: Article

References (39)

1. D. A. Tomalia, D. M. Hedestrand, and L. R. Wilson, Encyclopedia of Polymer Science and Engineering, 2nd ed., John Wiley & Sons, New York, 1990, Index Volume, p. 46.
2. G. R. Newkome and X. Lin, Macromolecules, 24, 1443 (1991).
3. K. L. Wooley, C. J. Hawker, and J. M. J. Fréchet, J. Am. Chem. Soc., 113, 4252 (1991).
4. T. M. Miller, T. X. Neeman, and H. E. Bair, Polym. Prep., 32, 627 (1990).
5. D. A. Tomalia and D. Dupont, Topics in Current Chemistry, Springer-Verlag, New York, 1993, Vol. 165, p. 193.
6. P. J. Flory, J. Am. Chem. Soc., 74, 2718 (1952).
7. Y. H. Kim and O. W. Webster, J. Am. Chem. Soc., 112, 4592 (1990).
8. C. J. Hawker, R. Lee, and J. M. J. Fréchet, J. Am. Chem. Soc., 113, 4583 (1991).
9. B. I. Volt and S. R. Turner, Polym. Prepr., 33, 184 (1992).
10. T. M. Miller, T. X. Neeman, E. W. Kwock, and S. M. Stein, J. Am. Chem. Soc., 115, 356 (1993).
11. K. E. Uhrich, C. J. Hawker, J. M. J. Frechet, and S. R. Turner, Macromolecules, 25, 4583 (1992).
12. M. Susuki, A. Ii, and T. Saegusa, Macromolecules, 25, 7071 (1992).
13. C. A. Martínez, Ph.D. Thesis, Synthesis of polymers with dendrimer architecture, McGill University, Aug. 1995; C. A. Martínez and A. S. Hay, J. Polym. Sci., Part A: Polym. Chem. to appear.
14. C. A. Martínez, Ph.D. Thesis, Synthesis of polymers with dendrimer architecture, McGill University, Aug. 1995; C. A. Martínez and A. S. Hay, J. Polym. Sci., Part A: Polym. Chem. to appear.
15. (a) H. Deckers, Hoechst Aktiengesellschaft, Fed. Rep. of Germany Pat. 4636557 (1987);
16. (b) D. R. Kelsey, Amoco Corp., Chicago, IL, U.S. Pat. 4774311 (1988).
17. (a) Z. Y. Wang, N. Berard, and A. S. Hay, J. Polym. Sci., Part A, Polym. Chem., 30, 299 (1992);
18. (b) Z. Y. Wang, H. N. de Carvalho, and A. S. Hay, J. Chem. Soc., Chem. Commun., 1221 (1991).
19. R. Prochaska, General Electric Co., U.S. Pat 3137706 (1964).
20. (a) M. Strukelj and A. S. Hay, Macromolecules, 25, 18, 4721 (1992);
21. (b) W. G. Kim and A. S. Hay, J. Macromol. Sci., Pure Appl. Chem., A29, 12, 1141 (1992).
22. Methoden Der OrganischenChemie, Band VI/lc, Phenole, Teil 2, Eugen Müller, Georg Thieme, Verlag, Stuttgart, Germany, 1976, p. 103.
23. See ref. 17a.
24. (a) R. P. Greenhalgh, Synlett, 235 (1992);
25. (b) R. J. Kennedy and A. M. Stock, J. Org. Chem., 25, 1901 (1960).
26. (a) M. E. Peach, J. Inorg. Nucl. Chem., 41, 1390 (1979);
27. (b) D. C. Bradley and C. H. Marsh, Chem. Ind., 361 (1967).
28. M. E. Peach and D. J. Sutherland, J. Fluorine Chem., 17, 225 (1981).
29. (a) M. Ueda and M. Oda, Polym. J., 21, 673 (1989);
30. (b) M. Ueda and M. Sato, Macromolecules, 20, 2675 (1987);
31. (c) M. Ueda, and T. Kano, Macromol. Chem. Rapid Commun., 5, 883 (1984);
32. (d) M. Ueda, T. Abe, and M. Oda, J. Polym. Sci., Part A, Polym. Chem., 30, 1993 (1992);
33. (e) P. E. Eaton, G. R. Carlson, and J. T. Lee, J. Org. Chem., 38, 23, 4071 (1973).
34. L. J. Andrews and W. W. Kaeding, J. Am. Chem. Soc., 73, 1007 (1951).
35. E. Behr, U.S. Pat. 1204459 (1970).
36. (a) T. B. Billece and J. T. Stults, Anal. Chem., 65, 13, 1709 (1993);
37. (b) H. S. Sahota, P. M. Lloyd, S. G. Yeates, P. J. Derrick, P. C. Taylor, and D. M. Haddleton, Chem. Soc., Chem. Commun., 2445 (1994);
38. (c) T. Kawaguchi, K. L. Walker, C. L. Wilkins, and J. S. Moore, J. Am. Chem. Soc., 117, 8, 2159 (1995);
39. (d) K. P. Chan, Y. Wang, and A. S. Hay, Macromolecules, 28, 65 (1995).