Thermal decomposition studies on ammonium dinitramide (ADN) and 15N and 2H isotopomers

Journal of Physical Chemistry A

Volumn 101, Issue 31, 1997, Pages 5646-5652

  Oxley, J C ^a   Smith, J L ^a   Zheng, W ^a   Rogers, E ^a   Coburn, M D ^a  

^a UNIVERSITY OF RHODE ISLAND   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; AMMONIUM COMPOUNDS; HYDROGEN; NITROGEN; POTASSIUM COMPOUNDS; REACTION KINETICS; SOLUTIONS;

AMMONIUM DINITRAMIDE; ISOTOPOMERS; POTASSIUM DINITRAMIDE;

PYROLYSIS;

EID: 0031176301     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9625063     Document Type: Article

References (36)

1. Oxley, J. C.; Kaushik, S. M.; Gilson, N. S. Thermochim. Acta 1992, 212, 77-85. Oxley, J. C.; Kaushik, S. M.; Gilson, N. S. Thermochim. Acta 1989, 153, 269-286. Brower, K. R.; Oxley, J. C.; Tewari, M. P. J. Phys. Chem. 1989, 93, 4029-4033.
2. Oxley, J. C.; Kaushik, S. M.; Gilson, N. S. Thermochim. Acta 1992, 212, 77-85. Oxley, J. C.; Kaushik, S. M.; Gilson, N. S. Thermochim. Acta 1989, 153, 269-286. Brower, K. R.; Oxley, J. C.; Tewari, M. P. J. Phys. Chem. 1989, 93, 4029-4033.
3. Oxley, J. C.; Kaushik, S. M.; Gilson, N. S. Thermochim. Acta 1992, 212, 77-85. Oxley, J. C.; Kaushik, S. M.; Gilson, N. S. Thermochim. Acta 1989, 153, 269-286. Brower, K. R.; Oxley, J. C.; Tewari, M. P. J. Phys. Chem. 1989, 93, 4029-4033.
4. Oxley, J. C; Smith, J. L; Valenzuela, B. J. Energetic Materials 1995, 13(1&2), 57-91.
5. Rosser, W. A.; Inami, S. H.; Wise, H. J. Phys. Chem. 1963, 67, 1753. Wood, B. J.; Wise, H. J. Chem. Phys. 1955, 23 (4), 693. Barclay, K. S.; Crewe, J. M. J. Appl. Chem. 1967, 17, 21. Keenan, A. G. J. Phys. Chem. 1957, 61, 780.
6. Rosser, W. A.; Inami, S. H.; Wise, H. J. Phys. Chem. 1963, 67, 1753. Wood, B. J.; Wise, H. J. Chem. Phys. 1955, 23 (4), 693. Barclay, K. S.; Crewe, J. M. J. Appl. Chem. 1967, 17, 21. Keenan, A. G. J. Phys. Chem. 1957, 61, 780.
7. Rosser, W. A.; Inami, S. H.; Wise, H. J. Phys. Chem. 1963, 67, 1753. Wood, B. J.; Wise, H. J. Chem. Phys. 1955, 23 (4), 693. Barclay, K. S.; Crewe, J. M. J. Appl. Chem. 1967, 17, 21. Keenan, A. G. J. Phys. Chem. 1957, 61, 780.
8. Rosser, W. A.; Inami, S. H.; Wise, H. J. Phys. Chem. 1963, 67, 1753. Wood, B. J.; Wise, H. J. Chem. Phys. 1955, 23 (4), 693. Barclay, K. S.; Crewe, J. M. J. Appl. Chem. 1967, 17, 21. Keenan, A. G. J. Phys. Chem. 1957, 61, 780.
9. Jacobs, P. W. M.; Whitehead, H. M. Chem. Rev. 1969, 551-590. Bircumshaw, L. L.; Newman, B. H. Proc. R. Soc. (London) 1954, A227, 115-132. Bircumshaw, L. L.; Newman, B. H. Proc. R. Soc. (London) 1955, A227, 228-241. Galwey, A. K.; Jacobs, P. W. M. J. Chem. Soc. 1959, 837-844. Response of Ammonium Perchlorate to Thermal and Mechanical Shock Stimuli; Boggs, T. L., Ed.; Naval Weapons Center TP 7053, 1990.
10. Jacobs, P. W. M.; Whitehead, H. M. Chem. Rev. 1969, 551-590. Bircumshaw, L. L.; Newman, B. H. Proc. R. Soc. (London) 1954, A227, 115-132. Bircumshaw, L. L.; Newman, B. H. Proc. R. Soc. (London) 1955, A227, 228-241. Galwey, A. K.; Jacobs, P. W. M. J. Chem. Soc. 1959, 837-844. Response of Ammonium Perchlorate to Thermal and Mechanical Shock Stimuli; Boggs, T. L., Ed.; Naval Weapons Center TP 7053, 1990.
11. Jacobs, P. W. M.; Whitehead, H. M. Chem. Rev. 1969, 551-590. Bircumshaw, L. L.; Newman, B. H. Proc. R. Soc. (London) 1954, A227, 115-132. Bircumshaw, L. L.; Newman, B. H. Proc. R. Soc. (London) 1955, A227, 228-241. Galwey, A. K.; Jacobs, P. W. M. J. Chem. Soc. 1959, 837-844. Response of Ammonium Perchlorate to Thermal and Mechanical Shock Stimuli; Boggs, T. L., Ed.; Naval Weapons Center TP 7053, 1990.
12. Jacobs, P. W. M.; Whitehead, H. M. Chem. Rev. 1969, 551-590. Bircumshaw, L. L.; Newman, B. H. Proc. R. Soc. (London) 1954, A227, 115-132. Bircumshaw, L. L.; Newman, B. H. Proc. R. Soc. (London) 1955, A227, 228-241. Galwey, A. K.; Jacobs, P. W. M. J. Chem. Soc. 1959, 837-844. Response of Ammonium Perchlorate to Thermal and Mechanical Shock Stimuli; Boggs, T. L., Ed.; Naval Weapons Center TP 7053, 1990.
13. Jacobs, P. W. M.; Whitehead, H. M. Chem. Rev. 1969, 551-590. Bircumshaw, L. L.; Newman, B. H. Proc. R. Soc. (London) 1954, A227, 115-132. Bircumshaw, L. L.; Newman, B. H. Proc. R. Soc. (London) 1955, A227, 228-241. Galwey, A. K.; Jacobs, P. W. M. J. Chem. Soc. 1959, 837-844. Response of Ammonium Perchlorate to Thermal and Mechanical Shock Stimuli; Boggs, T. L., Ed.; Naval Weapons Center TP 7053, 1990.
14. ADN was reportedly synthesized in the USSR in 1971 (Lukyanov, O. A.; Anikin, V. P.; Gorelik, V. P.; Tartakovsky, V. A. Russ. Chem. Bull. 1994, 43 (9), 1457. Shlyapochnikov, V. A.; Cherskya, N. O.; Lukyanov, O. A.; Gorelik, V. P.; Tartakovsky, V. A. Ibid. 1994, 43 (9), 1522) and in the United States at SRI in 1991 (Rossi, M. J.; Bottaro, J. C.; McMillen, D. F. Int. J. Chem. Kinet. 1993, 25, 549. Bottaro, J. C.; Schmidt, R. J.; Pennwell, P. E.; Ross, D. S. U.S. Patent No. 5,198,205 & 5,254,324. Schmidt, R. J.; Bottaro, J. C.; Pennwell, P. E.; Bomberger. U.S. Patent No. 5,415,852).
15. ADN was reportedly synthesized in the USSR in 1971 (Lukyanov, O. A.; Anikin, V. P.; Gorelik, V. P.; Tartakovsky, V. A. Russ. Chem. Bull. 1994, 43 (9), 1457. Shlyapochnikov, V. A.; Cherskya, N. O.; Lukyanov, O. A.; Gorelik, V. P.; Tartakovsky, V. A. Ibid. 1994, 43 (9), 1522) and in the United States at SRI in 1991 (Rossi, M. J.; Bottaro, J. C.; McMillen, D. F. Int. J. Chem. Kinet. 1993, 25, 549. Bottaro, J. C.; Schmidt, R. J.; Pennwell, P. E.; Ross, D. S. U.S. Patent No. 5,198,205 & 5,254,324. Schmidt, R. J.; Bottaro, J. C.; Pennwell, P. E.; Bomberger. U.S. Patent No. 5,415,852).
16. ADN was reportedly synthesized in the USSR in 1971 (Lukyanov, O. A.; Anikin, V. P.; Gorelik, V. P.; Tartakovsky, V. A. Russ. Chem. Bull. 1994, 43 (9), 1457. Shlyapochnikov, V. A.; Cherskya, N. O.; Lukyanov, O. A.; Gorelik, V. P.; Tartakovsky, V. A. Ibid. 1994, 43 (9), 1522) and in the United States at SRI in 1991 (Rossi, M. J.; Bottaro, J. C.; McMillen, D. F. Int. J. Chem. Kinet. 1993, 25, 549. Bottaro, J. C.; Schmidt, R. J.; Pennwell, P. E.; Ross, D. S. U.S. Patent No. 5,198,205 & 5,254,324. Schmidt, R. J.; Bottaro, J. C.; Pennwell, P. E.; Bomberger. U.S. Patent No. 5,415,852).
17. ADN was reportedly synthesized in the USSR in 1971 (Lukyanov, O. A.; Anikin, V. P.; Gorelik, V. P.; Tartakovsky, V. A. Russ. Chem. Bull. 1994, 43 (9), 1457. Shlyapochnikov, V. A.; Cherskya, N. O.; Lukyanov, O. A.; Gorelik, V. P.; Tartakovsky, V. A. Ibid. 1994, 43 (9), 1522) and in the United States at SRI in 1991 (Rossi, M. J.; Bottaro, J. C.; McMillen, D. F. Int. J. Chem. Kinet. 1993, 25, 549. Bottaro, J. C.; Schmidt, R. J.; Pennwell, P. E.; Ross, D. S. U.S. Patent No. 5,198,205 & 5,254,324. Schmidt, R. J.; Bottaro, J. C.; Pennwell, P. E.; Bomberger. U.S. Patent No. 5,415,852).
18. ADN was reportedly synthesized in the USSR in 1971 (Lukyanov, O. A.; Anikin, V. P.; Gorelik, V. P.; Tartakovsky, V. A. Russ. Chem. Bull. 1994, 43 (9), 1457. Shlyapochnikov, V. A.; Cherskya, N. O.; Lukyanov, O. A.; Gorelik, V. P.; Tartakovsky, V. A. Ibid. 1994, 43 (9), 1522) and in the United States at SRI in 1991 (Rossi, M. J.; Bottaro, J. C.; McMillen, D. F. Int. J. Chem. Kinet. 1993, 25, 549. Bottaro, J. C.; Schmidt, R. J.; Pennwell, P. E.; Ross, D. S. U.S. Patent No. 5,198,205 & 5,254,324. Schmidt, R. J.; Bottaro, J. C.; Pennwell, P. E.; Bomberger. U.S. Patent No. 5,415,852).
19. Oehrle, S. A. J. Energ. Mater. 1996, 14, 37-45. Basom, K. E. Analysis of Ammonium Dinitramide by Ion Chromatography. JANNAF Propellent Development & Characterization Subcommittee Mtg; April 1996, CPIA Pub. 642, pp 221-229.
20. Oehrle, S. A. J. Energ. Mater. 1996, 14, 37-45. Basom, K. E. Analysis of Ammonium Dinitramide by Ion Chromatography. JANNAF Propellent Development & Characterization Subcommittee Mtg; April 1996, CPIA Pub. 642, pp 221-229.
21. ASTM Method E 698-79 (reapproved 1993) Standard Test Method for Arrhenius Kinetic Constants for Thermally Unstable Materials. 1995 Annual Book of ASTM Standards; ASTM: Philadelphia, PA, 1995; Vol. 14.02.
22. Tartakovsky, V.; Manelis, G. B. Lecture at NAWC, China Lake, CA; Feb. 27-Mar 1, 1995. Manelis, G. B. 84th AGARD Meeting, Norway, Aug 29-Sept 3, 1994.
23. Tartakovsky, V.; Manelis, G. B. Lecture at NAWC, China Lake, CA; Feb. 27-Mar 1, 1995. Manelis, G. B. 84th AGARD Meeting, Norway, Aug 29-Sept 3, 1994.
24. Brill, T. B.; Brush, P. J.; Patil, D. G. Combust. Flame 1993, 92, 178.
25. Russell, T. P.; Stern, A. G.; Koppes, W. M.; Bedford, C. D. Thermal Decomposition and Stabilization of Ammonium Dinitramid. CPIA 29th JANNAF Combustion Subcommittee Meeting Hampton, VA; Oct 1992; Vol II, p 339. Russell, T. P.; Piermarini, G. J.; Block, S.; Miller, P. J. J. Phys. Chem. 1996, 100, 3248.
26. Russell, T. P.; Stern, A. G.; Koppes, W. M.; Bedford, C. D. Thermal Decomposition and Stabilization of Ammonium Dinitramid. CPIA 29th JANNAF Combustion Subcommittee Meeting Hampton, VA; Oct 1992; Vol II, p 339. Russell, T. P.; Piermarini, G. J.; Block, S.; Miller, P. J. J. Phys. Chem. 1996, 100, 3248.
27. Vyazovkin, S.; Wight, C. A. J. Phys. Chem., submitted.
28. Doyle, R. J. Org. Mass Spectrom 1993, 28, 83-91.
29. Rossi, M. J.; McMillen, D. F.; Golden, D. M. Low Pressure Thermal Decomposition Studies Selected Nitramine and Dinitramine Energetic Materials. ONR Final Report AD-A247 972, March 1992. Rossi, M. J.; Bottaro, J. C.; McMillen, D. F Int. J. Chem. Kinet. 1993, 25, 549.
30. Rossi, M. J.; McMillen, D. F.; Golden, D. M. Low Pressure Thermal Decomposition Studies Selected Nitramine and Dinitramine Energetic Materials. ONR Final Report AD-A247 972, March 1992. Rossi, M. J.; Bottaro, J. C.; McMillen, D. F Int. J. Chem. Kinet. 1993, 25, 549.
31. Pace, M. D. J. Phys. Chem. 1994, 98, 6251.
32. Politzer, P.; Seminario, M. C.; Concha, M. C.; Redfern, P. J. Mol. Struct. (THEOCHEM) 1993, 287, 235. Politzer, P.; Seminario, M. C. Chem. Phys. Lett. 1993, 216, 348.
33. Politzer, P.; Seminario, M. C.; Concha, M. C.; Redfern, P. J. Mol. Struct. (THEOCHEM) 1993, 287, 235. Politzer, P.; Seminario, M. C. Chem. Phys. Lett. 1993, 216, 348.
34. Mebel, A. M.; Lin, M. C.; Morokuma, K.; Melius, C. F. J. Phys. Chem. 1995, 99, 6842.
35. Oxley, J.; Smith, J.; Zheng, W.; Rogers, E.; Coburn, M. J. Phys. Chem. 1997, 101, 4375.
36. Politzer, P.; Seminario, J.; Concha, M. J. Mol. Struct. (THEOCHEM), submitted.