Synthesis of high molecular weight nylon 6 by anionic polymerization of ε-caprolactam: Evaluation of molecular weight and molecular weight distribution

Kobunshi Ronbunshu

Volumn 54, Issue 6, 1997, Pages 401-406

  Ueda, Kazue ^a   Nakai, Makoto ^a   Hattori, Kohzi ^a   Yamada, Kazunobu ^a   Tai, Kazuo ^a  

^a UNITIKA LTD   (Japan)

Author keywords

Anionic Polymerization; High Molecular Weight; Intrinsic Viscosity; Light Scattering; Mark Houwink Sakurada Equation; Nylon 6; Polydispersity; Weight Average Molecular Weight

Indexed keywords

ANIONIC POLYMERIZATION; COMPOSITION EFFECTS; GEL PERMEATION CHROMATOGRAPHY; INITIATORS (CHEMICAL); LIGHT SCATTERING; MOLECULAR WEIGHT; MOLECULAR WEIGHT DISTRIBUTION; NITROGEN COMPOUNDS; SYNTHESIS (CHEMICAL); VISCOSITY MEASUREMENT;

CAPROLACTAM; INTRINSIC VISCOSITY; MARK HOUWINK SAKURADA EQUATION; NYLON 6; POLYDISPERSITY;

NYLON POLYMERS;

MOLECULAR WEIGHT DISTRIBUTION; NYLON 6; VISCOSITY;

EID: 0031172033     PISSN: 03862186     EISSN: None     Source Type: Journal    
DOI: 10.1295/koron.54.401     Document Type: Article

References (29)

1. J. Sebenda, in "Comprehensive Chemical Kinetics", Vol. 15, C. H. Bamford and C. F. H. Tipper, Ed., Elsevier, Amsterdam (1976), Chapter 6.
2. H. Sekiguchi, in "Ring-Opening Polymerization", Vol. 2, K. J. Ivin and T. Saegusa, Ed., Elsevier, London (1984), p. 832.
3. J. Sebenda, in "Comprehensive Polymer Science", Vol. 3, C. F. H. Tipper and C. H. Bamford, Ed., Pergamon Press, Oxford (1988).
4. R. Puffr, in "Lactam-Based Polyamides", Vol. 1, R. Puffr and V. Kuba'ek, Ed., CRC Press, Boca Raton, Florida (1991).
5. S. Karger-Kocsis and L. Kiss, J. Polym. Sci., Polym. Symp., 69, 67 (1981).
6. R. Puffr and N. Vladimirov, Makromol. Chem., 194, 1765 (1993).
7. J. Sebenda, J. Macromol. Sci., Chem., A6, 1145 (1972).
8. H. Sekiguchi and B Coutin, J. Polym. Sci., Polym. Chem. Ed., 11, 1601 (1973).
9. T. M. Frunze, V. A. Kotel'nikov, T. V. Volkova, and V. V. Kurashev, Eur. Polym. J., 17, 1079 (1981).
10. N. Mougin, C. A. Veith, R. E. Cohen, and Y. Gnanou, Macromolecules, 25, 2004 (1992).
11. E. Sittler and J. Sebenda, Collect. Czech. Chem. Commun., 33, 270 (1968).
12. E. Sittler and J. Sebenda, Collect. Czech. Chem. Commun., 33, 3182 (1968).
13. J. Stehlicek and J. Sebenda, Eur. Polym. J., 22, 769 (1986).
14. T. M. Frunze, S. P. Davtyan, V. A. Kotel'nikov, T. V. Volkova, and V. V. Kurashev, Vysokomol. Soedin., Ser. B, 23, 388 (1981).
15. V. G. Frolov, Vysokomol. Soedin., Ser. B, 25, 134 (1983).
16. J. Stehlicek and R. Puffr, Makromol. Chem., 193, 2539 (1992).
17. K. Ueda, K. Yamada, M. Nakai, T. Matsuda, M. Hosoda, and K. Tai, Polym. J., 28, 446 (1996).
18. P. Biernacki and M. Wlodarczyk, Eur. Polym. J., 20, 635 (1984).
19. C. A. Veith and R. E. Cohen, Polymer, 30, 942 (1989).
20. G. Pezzin, J. Appl. Polym. Sci., 8, 2195 (1964).
21. C. V. Goebel, P. Cefelin, J. Stehlicek, and J. Sebenda, J. Polym. Sci., Polym. Chem. Ed., 10, 1411 (1972).
22. S. Chrzczonowlcz, J. Kowalski, and M. Wlodarczyk, Bull. Acad. Polon. Sci., Sér. sci. chim., 14, 751 (1966).
23. G. Pastuska, U. Just, and H. August, Angew. Makromol. Chem., 107, 173 (1982).
24. J. J. Chien, L. H. Shih, and K. I. Shih, Acta Chem. Sinica, 21, 50 (1955).
25. G. Rafler and G. Reinisch, Faserforsh. Textiltechn., 21, 91 (1970).
26. K. Hoshino and M. Watanabe, J. Am. Chem. Soc., 73, 4816 (1951).
27. Millipore Catalogue, (1996).