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Volumn 30, Issue 13, 1997, Pages 3942-3945

Adsorbed monolayers based on functionalized diblock copolymers

Author keywords

[No Author keywords available]

Indexed keywords

CONFORMATIONS; INTERFACIAL ENERGY; MACROMOLECULES; MECHANICAL PROPERTIES; METALS; MONOLAYERS; RING OPENING POLYMERIZATION; SEPARATION; SURFACES; SYNTHESIS (CHEMICAL);

EID: 0031168766     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma961648s     Document Type: Article
Times cited : (5)

References (29)
  • 21
    • 85033185112 scopus 로고    scopus 로고
    • note
    • Attemtps to characterize these copolymers by gel permeation chromatography have been unsuccessful to date due to the amine groups sticking to the columns. Typically, polydispersities for functionalized block copolymers prepared by living ROMP are less than 1.1. A qualitative indication of the polydispersity of the block copolymer is the sharpness and number of peaks observed in small angle scattering from bulk films. For the present copolymers, small angle scattering data are indeed consistent with a very low polydispersity. Furthermore, information regarding the extent of reaction and polydispersity can be inferred from the color of the solution and the reaction kinetics, which indicate complete reaction of the first monomer before addition of the second. All indicators suggest complete sequential reaction of each monomer.
  • 25
    • 85033168370 scopus 로고    scopus 로고
    • note
    • At 20 °C, the surface tension of n-propylamine is 22.4 dyn/ cm (CRC Handbook of Chemistry and Physics) while that of allylimidazole is 42.3 dyn/cm (measured in our laboratory).
  • 28
    • 0000077862 scopus 로고
    • Biosensors and Chemical Sensors: Optimizing Performance Through Polymeric Materials
    • American Chemical Society: Washington, DC
    • Biosensors and Chemical Sensors: Optimizing Performance Through Polymeric Materials: Edelman P. G., Wang, J., Eds.; ACS Symposium Series 487, American Chemical Society: Washington, DC, 1992.
    • (1992) ACS Symposium Series 487
    • Edelman, P.G.1    Wang, J.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.