Thermally controlled formation of fullerene-diene oligomers and copolymers

Macromolecules

Volumn 30, Issue 13, 1997, Pages 3949-3951

  Nie, Bing ^a   Rotello, Vincent M ^a  

^a UNIVERSITY OF MASSACHUSETTS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CHARACTERIZATION; FULLERENES; HEATING; MONOMERS; OLIGOMERS; POLYMERIZATION; STRUCTURE (COMPOSITION); THERMODYNAMIC STABILITY;

BIS ANTHRACENE; BIS DIENES; DIELS-ALDER CYCLOADDITION; FULLERENE DIENE COPOLYMER; POLYMERIZATION DEPOLYMERIZATION CYCLE; THERMOREVERSIBLE POLYMER;

COPOLYMERS;

EID: 0031164070     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma970122k     Document Type: Article

References (38)

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20. For examples of fullerene-containing polymers see: Samulski, E.; DeSimone, J.; Hunt, M.; Menceloglu, Y.; Jarnagin, R.; York, G.; Labat, K.; Wang, H. Chem. Mater. 1991, 4, 1153. Hawker, C.; Wooley, K.; Fréchet, J. J. Chem. Soc., Chem. Commun. 1994, 925. Weis, C.; Friederich, C.; Mülhaupt, R.; Frey, H. Macromolecules 1995, 28, 403. Zhang, N.; Schricker, S.; Wudl, F.; Prato, M.; Maggini, M.; Scorrano, G. Chem Mater. 1995, 7, 441-442. Dai, L.; Mau, A.; Griesser, H.; Spurling, T.; White, J. J. Phys. Chem. 1995, 99, 17302. Wang, Y. Nature 1992, 356, 585. Wang, J.; Javaher, G.; Petrie, S.; Bohme, D. K. J. Am. Chem. Soc. 1992, 114, 9665. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc., Chem. Commun. 1994, 925. Stephens, P. W.; Bortel, G.; Faigel, G.; Tegze, M.; Janossy, A.; Pekker, S.; Oszlanyi, G.; Forro, L. Nature 1994, 370, 637. Fischer, J. E. Science 1994, 264, 1548. Wang, Y.; Holden, J. M.; Bi, X.; Eklund, P. C. Chem. Phys. Lett. 1994, 217, 413. Patil, A. O.; Schrever, G. W.; Carstensen, B.; Lundberg, R. D. Polym. Bull. 1993, 30, 187. West, R.; Oka, K.; Miller, M. Abstracts of Papers, 203rd National Meeting of the American Chemical Society, San Francisco, CA, Spring, 1992; American Chemical Society: Washington, DC, 1992; p 684. Klemperer, W. G.; Zhong, B. Abstracts of Papers, 206th National Meeting of the American Chemical Society, Chicago, IL, Fall, 1993; American Chemical Society: Washington, DC, 1993; p 534. Loy, D.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977. Sun, Y.; Ma, B.; Bunker, C.; Liu, B. J. Am. Chem. Soc. 1996, 118, 12706.
21. For examples of fullerene-containing polymers see: Samulski, E.; DeSimone, J.; Hunt, M.; Menceloglu, Y.; Jarnagin, R.; York, G.; Labat, K.; Wang, H. Chem. Mater. 1991, 4, 1153. Hawker, C.; Wooley, K.; Fréchet, J. J. Chem. Soc., Chem. Commun. 1994, 925. Weis, C.; Friederich, C.; Mülhaupt, R.; Frey, H. Macromolecules 1995, 28, 403. Zhang, N.; Schricker, S.; Wudl, F.; Prato, M.; Maggini, M.; Scorrano, G. Chem Mater. 1995, 7, 441-442. Dai, L.; Mau, A.; Griesser, H.; Spurling, T.; White, J. J. Phys. Chem. 1995, 99, 17302. Wang, Y. Nature 1992, 356, 585. Wang, J.; Javaher, G.; Petrie, S.; Bohme, D. K. J. Am. Chem. Soc. 1992, 114, 9665. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc., Chem. Commun. 1994, 925. Stephens, P. W.; Bortel, G.; Faigel, G.; Tegze, M.; Janossy, A.; Pekker, S.; Oszlanyi, G.; Forro, L. Nature 1994, 370, 637. Fischer, J. E. Science 1994, 264, 1548. Wang, Y.; Holden, J. M.; Bi, X.; Eklund, P. C. Chem. Phys. Lett. 1994, 217, 413. Patil, A. O.; Schrever, G. W.; Carstensen, B.; Lundberg, R. D. Polym. Bull. 1993, 30, 187. West, R.; Oka, K.; Miller, M. Abstracts of Papers, 203rd National Meeting of the American Chemical Society, San Francisco, CA, Spring, 1992; American Chemical Society: Washington, DC, 1992; p 684. Klemperer, W. G.; Zhong, B. Abstracts of Papers, 206th National Meeting of the American Chemical Society, Chicago, IL, Fall, 1993; American Chemical Society: Washington, DC, 1993; p 534. Loy, D.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977. Sun, Y.; Ma, B.; Bunker, C.; Liu, B. J. Am. Chem. Soc. 1996, 118, 12706.
22. For examples of fullerene-containing polymers see: Samulski, E.; DeSimone, J.; Hunt, M.; Menceloglu, Y.; Jarnagin, R.; York, G.; Labat, K.; Wang, H. Chem. Mater. 1991, 4, 1153. Hawker, C.; Wooley, K.; Fréchet, J. J. Chem. Soc., Chem. Commun. 1994, 925. Weis, C.; Friederich, C.; Mülhaupt, R.; Frey, H. Macromolecules 1995, 28, 403. Zhang, N.; Schricker, S.; Wudl, F.; Prato, M.; Maggini, M.; Scorrano, G. Chem Mater. 1995, 7, 441-442. Dai, L.; Mau, A.; Griesser, H.; Spurling, T.; White, J. J. Phys. Chem. 1995, 99, 17302. Wang, Y. Nature 1992, 356, 585. Wang, J.; Javaher, G.; Petrie, S.; Bohme, D. K. J. Am. Chem. Soc. 1992, 114, 9665. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc., Chem. Commun. 1994, 925. Stephens, P. W.; Bortel, G.; Faigel, G.; Tegze, M.; Janossy, A.; Pekker, S.; Oszlanyi, G.; Forro, L. Nature 1994, 370, 637. Fischer, J. E. Science 1994, 264, 1548. Wang, Y.; Holden, J. M.; Bi, X.; Eklund, P. C. Chem. Phys. Lett. 1994, 217, 413. Patil, A. O.; Schrever, G. W.; Carstensen, B.; Lundberg, R. D. Polym. Bull. 1993, 30, 187. West, R.; Oka, K.; Miller, M. Abstracts of Papers, 203rd National Meeting of the American Chemical Society, San Francisco, CA, Spring, 1992; American Chemical Society: Washington, DC, 1992; p 684. Klemperer, W. G.; Zhong, B. Abstracts of Papers, 206th National Meeting of the American Chemical Society, Chicago, IL, Fall, 1993; American Chemical Society: Washington, DC, 1993; p 534. Loy, D.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977. Sun, Y.; Ma, B.; Bunker, C.; Liu, B. J. Am. Chem. Soc. 1996, 118, 12706.
23. For examples of fullerene-containing polymers see: Samulski, E.; DeSimone, J.; Hunt, M.; Menceloglu, Y.; Jarnagin, R.; York, G.; Labat, K.; Wang, H. Chem. Mater. 1991, 4, 1153. Hawker, C.; Wooley, K.; Fréchet, J. J. Chem. Soc., Chem. Commun. 1994, 925. Weis, C.; Friederich, C.; Mülhaupt, R.; Frey, H. Macromolecules 1995, 28, 403. Zhang, N.; Schricker, S.; Wudl, F.; Prato, M.; Maggini, M.; Scorrano, G. Chem Mater. 1995, 7, 441-442. Dai, L.; Mau, A.; Griesser, H.; Spurling, T.; White, J. J. Phys. Chem. 1995, 99, 17302. Wang, Y. Nature 1992, 356, 585. Wang, J.; Javaher, G.; Petrie, S.; Bohme, D. K. J. Am. Chem. Soc. 1992, 114, 9665. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc., Chem. Commun. 1994, 925. Stephens, P. W.; Bortel, G.; Faigel, G.; Tegze, M.; Janossy, A.; Pekker, S.; Oszlanyi, G.; Forro, L. Nature 1994, 370, 637. Fischer, J. E. Science 1994, 264, 1548. Wang, Y.; Holden, J. M.; Bi, X.; Eklund, P. C. Chem. Phys. Lett. 1994, 217, 413. Patil, A. O.; Schrever, G. W.; Carstensen, B.; Lundberg, R. D. Polym. Bull. 1993, 30, 187. West, R.; Oka, K.; Miller, M. Abstracts of Papers, 203rd National Meeting of the American Chemical Society, San Francisco, CA, Spring, 1992; American Chemical Society: Washington, DC, 1992; p 684. Klemperer, W. G.; Zhong, B. Abstracts of Papers, 206th National Meeting of the American Chemical Society, Chicago, IL, Fall, 1993; American Chemical Society: Washington, DC, 1993; p 534. Loy, D.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977. Sun, Y.; Ma, B.; Bunker, C.; Liu, B. J. Am. Chem. Soc. 1996, 118, 12706.
24. For examples of fullerene-containing polymers see: Samulski, E.; DeSimone, J.; Hunt, M.; Menceloglu, Y.; Jarnagin, R.; York, G.; Labat, K.; Wang, H. Chem. Mater. 1991, 4, 1153. Hawker, C.; Wooley, K.; Fréchet, J. J. Chem. Soc., Chem. Commun. 1994, 925. Weis, C.; Friederich, C.; Mülhaupt, R.; Frey, H. Macromolecules 1995, 28, 403. Zhang, N.; Schricker, S.; Wudl, F.; Prato, M.; Maggini, M.; Scorrano, G. Chem Mater. 1995, 7, 441-442. Dai, L.; Mau, A.; Griesser, H.; Spurling, T.; White, J. J. Phys. Chem. 1995, 99, 17302. Wang, Y. Nature 1992, 356, 585. Wang, J.; Javaher, G.; Petrie, S.; Bohme, D. K. J. Am. Chem. Soc. 1992, 114, 9665. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc., Chem. Commun. 1994, 925. Stephens, P. W.; Bortel, G.; Faigel, G.; Tegze, M.; Janossy, A.; Pekker, S.; Oszlanyi, G.; Forro, L. Nature 1994, 370, 637. Fischer, J. E. Science 1994, 264, 1548. Wang, Y.; Holden, J. M.; Bi, X.; Eklund, P. C. Chem. Phys. Lett. 1994, 217, 413. Patil, A. O.; Schrever, G. W.; Carstensen, B.; Lundberg, R. D. Polym. Bull. 1993, 30, 187. West, R.; Oka, K.; Miller, M. Abstracts of Papers, 203rd National Meeting of the American Chemical Society, San Francisco, CA, Spring, 1992; American Chemical Society: Washington, DC, 1992; p 684. Klemperer, W. G.; Zhong, B. Abstracts of Papers, 206th National Meeting of the American Chemical Society, Chicago, IL, Fall, 1993; American Chemical Society: Washington, DC, 1993; p 534. Loy, D.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977. Sun, Y.; Ma, B.; Bunker, C.; Liu, B. J. Am. Chem. Soc. 1996, 118, 12706.
25. For examples of fullerene-containing polymers see: Samulski, E.; DeSimone, J.; Hunt, M.; Menceloglu, Y.; Jarnagin, R.; York, G.; Labat, K.; Wang, H. Chem. Mater. 1991, 4, 1153. Hawker, C.; Wooley, K.; Fréchet, J. J. Chem. Soc., Chem. Commun. 1994, 925. Weis, C.; Friederich, C.; Mülhaupt, R.; Frey, H. Macromolecules 1995, 28, 403. Zhang, N.; Schricker, S.; Wudl, F.; Prato, M.; Maggini, M.; Scorrano, G. Chem Mater. 1995, 7, 441-442. Dai, L.; Mau, A.; Griesser, H.; Spurling, T.; White, J. J. Phys. Chem. 1995, 99, 17302. Wang, Y. Nature 1992, 356, 585. Wang, J.; Javaher, G.; Petrie, S.; Bohme, D. K. J. Am. Chem. Soc. 1992, 114, 9665. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc., Chem. Commun. 1994, 925. Stephens, P. W.; Bortel, G.; Faigel, G.; Tegze, M.; Janossy, A.; Pekker, S.; Oszlanyi, G.; Forro, L. Nature 1994, 370, 637. Fischer, J. E. Science 1994, 264, 1548. Wang, Y.; Holden, J. M.; Bi, X.; Eklund, P. C. Chem. Phys. Lett. 1994, 217, 413. Patil, A. O.; Schrever, G. W.; Carstensen, B.; Lundberg, R. D. Polym. Bull. 1993, 30, 187. West, R.; Oka, K.; Miller, M. Abstracts of Papers, 203rd National Meeting of the American Chemical Society, San Francisco, CA, Spring, 1992; American Chemical Society: Washington, DC, 1992; p 684. Klemperer, W. G.; Zhong, B. Abstracts of Papers, 206th National Meeting of the American Chemical Society, Chicago, IL, Fall, 1993; American Chemical Society: Washington, DC, 1993; p 534. Loy, D.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977. Sun, Y.; Ma, B.; Bunker, C.; Liu, B. J. Am. Chem. Soc. 1996, 118, 12706.
26. For examples of fullerene-containing polymers see: Samulski, E.; DeSimone, J.; Hunt, M.; Menceloglu, Y.; Jarnagin, R.; York, G.; Labat, K.; Wang, H. Chem. Mater. 1991, 4, 1153. Hawker, C.; Wooley, K.; Fréchet, J. J. Chem. Soc., Chem. Commun. 1994, 925. Weis, C.; Friederich, C.; Mülhaupt, R.; Frey, H. Macromolecules 1995, 28, 403. Zhang, N.; Schricker, S.; Wudl, F.; Prato, M.; Maggini, M.; Scorrano, G. Chem Mater. 1995, 7, 441-442. Dai, L.; Mau, A.; Griesser, H.; Spurling, T.; White, J. J. Phys. Chem. 1995, 99, 17302. Wang, Y. Nature 1992, 356, 585. Wang, J.; Javaher, G.; Petrie, S.; Bohme, D. K. J. Am. Chem. Soc. 1992, 114, 9665. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc., Chem. Commun. 1994, 925. Stephens, P. W.; Bortel, G.; Faigel, G.; Tegze, M.; Janossy, A.; Pekker, S.; Oszlanyi, G.; Forro, L. Nature 1994, 370, 637. Fischer, J. E. Science 1994, 264, 1548. Wang, Y.; Holden, J. M.; Bi, X.; Eklund, P. C. Chem. Phys. Lett. 1994, 217, 413. Patil, A. O.; Schrever, G. W.; Carstensen, B.; Lundberg, R. D. Polym. Bull. 1993, 30, 187. West, R.; Oka, K.; Miller, M. Abstracts of Papers, 203rd National Meeting of the American Chemical Society, San Francisco, CA, Spring, 1992; American Chemical Society: Washington, DC, 1992; p 684. Klemperer, W. G.; Zhong, B. Abstracts of Papers, 206th National Meeting of the American Chemical Society, Chicago, IL, Fall, 1993; American Chemical Society: Washington, DC, 1993; p 534. Loy, D.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977. Sun, Y.; Ma, B.; Bunker, C.; Liu, B. J. Am. Chem. Soc. 1996, 118, 12706.
27. For examples of fullerene-containing polymers see: Samulski, E.; DeSimone, J.; Hunt, M.; Menceloglu, Y.; Jarnagin, R.; York, G.; Labat, K.; Wang, H. Chem. Mater. 1991, 4, 1153. Hawker, C.; Wooley, K.; Fréchet, J. J. Chem. Soc., Chem. Commun. 1994, 925. Weis, C.; Friederich, C.; Mülhaupt, R.; Frey, H. Macromolecules 1995, 28, 403. Zhang, N.; Schricker, S.; Wudl, F.; Prato, M.; Maggini, M.; Scorrano, G. Chem Mater. 1995, 7, 441-442. Dai, L.; Mau, A.; Griesser, H.; Spurling, T.; White, J. J. Phys. Chem. 1995, 99, 17302. Wang, Y. Nature 1992, 356, 585. Wang, J.; Javaher, G.; Petrie, S.; Bohme, D. K. J. Am. Chem. Soc. 1992, 114, 9665. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc., Chem. Commun. 1994, 925. Stephens, P. W.; Bortel, G.; Faigel, G.; Tegze, M.; Janossy, A.; Pekker, S.; Oszlanyi, G.; Forro, L. Nature 1994, 370, 637. Fischer, J. E. Science 1994, 264, 1548. Wang, Y.; Holden, J. M.; Bi, X.; Eklund, P. C. Chem. Phys. Lett. 1994, 217, 413. Patil, A. O.; Schrever, G. W.; Carstensen, B.; Lundberg, R. D. Polym. Bull. 1993, 30, 187. West, R.; Oka, K.; Miller, M. Abstracts of Papers, 203rd National Meeting of the American Chemical Society, San Francisco, CA, Spring, 1992; American Chemical Society: Washington, DC, 1992; p 684. Klemperer, W. G.; Zhong, B. Abstracts of Papers, 206th National Meeting of the American Chemical Society, Chicago, IL, Fall, 1993; American Chemical Society: Washington, DC, 1993; p 534. Loy, D.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977. Sun, Y.; Ma, B.; Bunker, C.; Liu, B. J. Am. Chem. Soc. 1996, 118, 12706.
28. For examples of fullerene-containing polymers see: Samulski, E.; DeSimone, J.; Hunt, M.; Menceloglu, Y.; Jarnagin, R.; York, G.; Labat, K.; Wang, H. Chem. Mater. 1991, 4, 1153. Hawker, C.; Wooley, K.; Fréchet, J. J. Chem. Soc., Chem. Commun. 1994, 925. Weis, C.; Friederich, C.; Mülhaupt, R.; Frey, H. Macromolecules 1995, 28, 403. Zhang, N.; Schricker, S.; Wudl, F.; Prato, M.; Maggini, M.; Scorrano, G. Chem Mater. 1995, 7, 441-442. Dai, L.; Mau, A.; Griesser, H.; Spurling, T.; White, J. J. Phys. Chem. 1995, 99, 17302. Wang, Y. Nature 1992, 356, 585. Wang, J.; Javaher, G.; Petrie, S.; Bohme, D. K. J. Am. Chem. Soc. 1992, 114, 9665. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc., Chem. Commun. 1994, 925. Stephens, P. W.; Bortel, G.; Faigel, G.; Tegze, M.; Janossy, A.; Pekker, S.; Oszlanyi, G.; Forro, L. Nature 1994, 370, 637. Fischer, J. E. Science 1994, 264, 1548. Wang, Y.; Holden, J. M.; Bi, X.; Eklund, P. C. Chem. Phys. Lett. 1994, 217, 413. Patil, A. O.; Schrever, G. W.; Carstensen, B.; Lundberg, R. D. Polym. Bull. 1993, 30, 187. West, R.; Oka, K.; Miller, M. Abstracts of Papers, 203rd National Meeting of the American Chemical Society, San Francisco, CA, Spring, 1992; American Chemical Society: Washington, DC, 1992; p 684. Klemperer, W. G.; Zhong, B. Abstracts of Papers, 206th National Meeting of the American Chemical Society, Chicago, IL, Fall, 1993; American Chemical Society: Washington, DC, 1993; p 534. Loy, D.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977. Sun, Y.; Ma, B.; Bunker, C.; Liu, B. J. Am. Chem. Soc. 1996, 118, 12706.
29. For examples of fullerene-containing polymers see: Samulski, E.; DeSimone, J.; Hunt, M.; Menceloglu, Y.; Jarnagin, R.; York, G.; Labat, K.; Wang, H. Chem. Mater. 1991, 4, 1153. Hawker, C.; Wooley, K.; Fréchet, J. J. Chem. Soc., Chem. Commun. 1994, 925. Weis, C.; Friederich, C.; Mülhaupt, R.; Frey, H. Macromolecules 1995, 28, 403. Zhang, N.; Schricker, S.; Wudl, F.; Prato, M.; Maggini, M.; Scorrano, G. Chem Mater. 1995, 7, 441-442. Dai, L.; Mau, A.; Griesser, H.; Spurling, T.; White, J. J. Phys. Chem. 1995, 99, 17302. Wang, Y. Nature 1992, 356, 585. Wang, J.; Javaher, G.; Petrie, S.; Bohme, D. K. J. Am. Chem. Soc. 1992, 114, 9665. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc., Chem. Commun. 1994, 925. Stephens, P. W.; Bortel, G.; Faigel, G.; Tegze, M.; Janossy, A.; Pekker, S.; Oszlanyi, G.; Forro, L. Nature 1994, 370, 637. Fischer, J. E. Science 1994, 264, 1548. Wang, Y.; Holden, J. M.; Bi, X.; Eklund, P. C. Chem. Phys. Lett. 1994, 217, 413. Patil, A. O.; Schrever, G. W.; Carstensen, B.; Lundberg, R. D. Polym. Bull. 1993, 30, 187. West, R.; Oka, K.; Miller, M. Abstracts of Papers, 203rd National Meeting of the American Chemical Society, San Francisco, CA, Spring, 1992; American Chemical Society: Washington, DC, 1992; p 684. Klemperer, W. G.; Zhong, B. Abstracts of Papers, 206th National Meeting of the American Chemical Society, Chicago, IL, Fall, 1993; American Chemical Society: Washington, DC, 1993; p 534. Loy, D.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977. Sun, Y.; Ma, B.; Bunker, C.; Liu, B. J. Am. Chem. Soc. 1996, 118, 12706.
30. For examples of fullerene-containing polymers see: Samulski, E.; DeSimone, J.; Hunt, M.; Menceloglu, Y.; Jarnagin, R.; York, G.; Labat, K.; Wang, H. Chem. Mater. 1991, 4, 1153. Hawker, C.; Wooley, K.; Fréchet, J. J. Chem. Soc., Chem. Commun. 1994, 925. Weis, C.; Friederich, C.; Mülhaupt, R.; Frey, H. Macromolecules 1995, 28, 403. Zhang, N.; Schricker, S.; Wudl, F.; Prato, M.; Maggini, M.; Scorrano, G. Chem Mater. 1995, 7, 441-442. Dai, L.; Mau, A.; Griesser, H.; Spurling, T.; White, J. J. Phys. Chem. 1995, 99, 17302. Wang, Y. Nature 1992, 356, 585. Wang, J.; Javaher, G.; Petrie, S.; Bohme, D. K. J. Am. Chem. Soc. 1992, 114, 9665. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc., Chem. Commun. 1994, 925. Stephens, P. W.; Bortel, G.; Faigel, G.; Tegze, M.; Janossy, A.; Pekker, S.; Oszlanyi, G.; Forro, L. Nature 1994, 370, 637. Fischer, J. E. Science 1994, 264, 1548. Wang, Y.; Holden, J. M.; Bi, X.; Eklund, P. C. Chem. Phys. Lett. 1994, 217, 413. Patil, A. O.; Schrever, G. W.; Carstensen, B.; Lundberg, R. D. Polym. Bull. 1993, 30, 187. West, R.; Oka, K.; Miller, M. Abstracts of Papers, 203rd National Meeting of the American Chemical Society, San Francisco, CA, Spring, 1992; American Chemical Society: Washington, DC, 1992; p 684. Klemperer, W. G.; Zhong, B. Abstracts of Papers, 206th National Meeting of the American Chemical Society, Chicago, IL, Fall, 1993; American Chemical Society: Washington, DC, 1993; p 534. Loy, D.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977. Sun, Y.; Ma, B.; Bunker, C.; Liu, B. J. Am. Chem. Soc. 1996, 118, 12706.
31. For examples of fullerene-containing polymers see: Samulski, E.; DeSimone, J.; Hunt, M.; Menceloglu, Y.; Jarnagin, R.; York, G.; Labat, K.; Wang, H. Chem. Mater. 1991, 4, 1153. Hawker, C.; Wooley, K.; Fréchet, J. J. Chem. Soc., Chem. Commun. 1994, 925. Weis, C.; Friederich, C.; Mülhaupt, R.; Frey, H. Macromolecules 1995, 28, 403. Zhang, N.; Schricker, S.; Wudl, F.; Prato, M.; Maggini, M.; Scorrano, G. Chem Mater. 1995, 7, 441-442. Dai, L.; Mau, A.; Griesser, H.; Spurling, T.; White, J. J. Phys. Chem. 1995, 99, 17302. Wang, Y. Nature 1992, 356, 585. Wang, J.; Javaher, G.; Petrie, S.; Bohme, D. K. J. Am. Chem. Soc. 1992, 114, 9665. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc., Chem. Commun. 1994, 925. Stephens, P. W.; Bortel, G.; Faigel, G.; Tegze, M.; Janossy, A.; Pekker, S.; Oszlanyi, G.; Forro, L. Nature 1994, 370, 637. Fischer, J. E. Science 1994, 264, 1548. Wang, Y.; Holden, J. M.; Bi, X.; Eklund, P. C. Chem. Phys. Lett. 1994, 217, 413. Patil, A. O.; Schrever, G. W.; Carstensen, B.; Lundberg, R. D. Polym. Bull. 1993, 30, 187. West, R.; Oka, K.; Miller, M. Abstracts of Papers, 203rd National Meeting of the American Chemical Society, San Francisco, CA, Spring, 1992; American Chemical Society: Washington, DC, 1992; p 684. Klemperer, W. G.; Zhong, B. Abstracts of Papers, 206th National Meeting of the American Chemical Society, Chicago, IL, Fall, 1993; American Chemical Society: Washington, DC, 1993; p 534. Loy, D.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977. Sun, Y.; Ma, B.; Bunker, C.; Liu, B. J. Am. Chem. Soc. 1996, 118, 12706.
32. For examples of fullerene-containing polymers see: Samulski, E.; DeSimone, J.; Hunt, M.; Menceloglu, Y.; Jarnagin, R.; York, G.; Labat, K.; Wang, H. Chem. Mater. 1991, 4, 1153. Hawker, C.; Wooley, K.; Fréchet, J. J. Chem. Soc., Chem. Commun. 1994, 925. Weis, C.; Friederich, C.; Mülhaupt, R.; Frey, H. Macromolecules 1995, 28, 403. Zhang, N.; Schricker, S.; Wudl, F.; Prato, M.; Maggini, M.; Scorrano, G. Chem Mater. 1995, 7, 441-442. Dai, L.; Mau, A.; Griesser, H.; Spurling, T.; White, J. J. Phys. Chem. 1995, 99, 17302. Wang, Y. Nature 1992, 356, 585. Wang, J.; Javaher, G.; Petrie, S.; Bohme, D. K. J. Am. Chem. Soc. 1992, 114, 9665. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc., Chem. Commun. 1994, 925. Stephens, P. W.; Bortel, G.; Faigel, G.; Tegze, M.; Janossy, A.; Pekker, S.; Oszlanyi, G.; Forro, L. Nature 1994, 370, 637. Fischer, J. E. Science 1994, 264, 1548. Wang, Y.; Holden, J. M.; Bi, X.; Eklund, P. C. Chem. Phys. Lett. 1994, 217, 413. Patil, A. O.; Schrever, G. W.; Carstensen, B.; Lundberg, R. D. Polym. Bull. 1993, 30, 187. West, R.; Oka, K.; Miller, M. Abstracts of Papers, 203rd National Meeting of the American Chemical Society, San Francisco, CA, Spring, 1992; American Chemical Society: Washington, DC, 1992; p 684. Klemperer, W. G.; Zhong, B. Abstracts of Papers, 206th National Meeting of the American Chemical Society, Chicago, IL, Fall, 1993; American Chemical Society: Washington, DC, 1993; p 534. Loy, D.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977. Sun, Y.; Ma, B.; Bunker, C.; Liu, B. J. Am. Chem. Soc. 1996, 118, 12706.
33. Schlueter, J.; Seaman, J.; Taha, S.; Cohen, H.; Lykke, K.; Wang, H.; Williams, J. J. Chem. Soc., Chem. Commun. 1993, 972. Komatsu, K.; Murata, Y.; Sugita, N.; Takeuchi, K.; Wan, T. Tetrahedron Lett. 1993, 8473.
34. Schlueter, J.; Seaman, J.; Taha, S.; Cohen, H.; Lykke, K.; Wang, H.; Williams, J. J. Chem. Soc., Chem. Commun. 1993, 972. Komatsu, K.; Murata, Y.; Sugita, N.; Takeuchi, K.; Wan, T. Tetrahedron Lett. 1993, 8473.
35. 2: C, 86.59; H, 7.64. Found: C, 86.45; H, 7.65.
36. 60 (20 mg, 28 μmol) in toluene (15 mL) was stirred at room temperature for 5 days. Addition of THF (5 mL) resulted in the formation of a precipitate (7.1 mg, 20% weight of the total product).
37. 3 Å, 5 μm, Column Resolution Inc.), and Permagel column (500 Å, 5 μm, 7.8 × 300 mm, Pacific Column Co.).
38. The actual molecular weights should be higher due to the lower hydrodynamic radius of 2 arising from the lower solubility of this polymer in THF relative to polystyrene.