Discrimination of ethylene/vinyl acetate copolymers with different composition and prediction of the vinyl acetate content in the copolymers using Fourier-transform Raman spectroscopy and multivariate data analysis

Vibrational Spectroscopy

Volumn 14, Issue 2, 1997, Pages 253-259

  Shimoyama, M ^a   Maeda, H ^b   Matsukawa, K ^c   Inoue, H ^c   Ninomiya, T ^a   Ozaki, Y ^b  

^a Forensic Science Laboratory   (Japan)

^b KWANSEI GAKUIN UNIVERSITY   (Japan)

^c OSAKA MUNICIPAL TECHNICAL RESEARCH INSTITUTE   (Japan)

Author keywords

Chemometrics; Ethylene vinyl acetate; FT Raman spectroscopy; Multivariate data analysis; Partial least squares regression; Polymer; Principal component analysis; Raman spectroscopy

Indexed keywords

CHEMICAL ANALYSIS; COMPOSITION; COPOLYMERS; DATA REDUCTION; LEAST SQUARES APPROXIMATIONS; POLYETHYLENES; POLYVINYL ACETATES; RAMAN SCATTERING; REGRESSION ANALYSIS;

CHEMOMETRICS; FOURIER TRANSFORM RAMAN SPECTROSCOPY; MULTIVARIATE DATA ANALYSIS; PARTIAL LEAST SQUARE REGRESSION; PRINCIPAL COMPONENT ANALYSIS; VINYL ACETATE;

RAMAN SPECTROSCOPY;

EID: 0031145717     PISSN: 09242031     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0924-2031(97)00010-6     Document Type: Article

References (25)

1. N. Everall, P. Tayler, J. Chalmers, R. Ferwerda, J. van der Maas, Polymer 35 (1994) 3184.
2. N. Everall, J. Chalmers, R.F. Erwerda, J. van der Maas, P. Hendra, J. Raman Spectrosc. 25 (1994) 43.
3. T. Shope, T. Vickers, C. Mann, Appl. Spectrosc. 42 (1988) 468.
4. M.B. Seasholtz, D.D. Archibald, A. Lorber, B.R. Kowalski, Appl. Spectrosc. 43 (1989) 1067.
5. K.P.J. Williams, R.E. Aries, D.J. Cutler, R.H. Clarke, Appl. Spectrosc. 45 (1990) 1527.
6. M. Shimoyama, H. Maeda, H. Sato, T. Ninomiya, Y. Ozaki, submitted for publication.
7. M.A. Sharaf, D.L. Illman, B.R. Kowalski, Chemometrics, John Wiley and Sons, New York, NY, 1986.
8. D.L. Massart, B.G.M. Vandeginste, S.N. Deming, Y. Michotte, L. Kaufman, Chemometrics, a Textbook, Elsevier, Amsterdam, 1988.
9. P.J. Hendra, C.H. Johes, G. Warnes, Fourier Transform Raman Spectroscopy, Instrumentation and Chemical Applications, Ellis Horwood, Chichester, 1991.
10. B. Schrader, in: J.R. Ferraro, K. Krishnan (Eds.), Practical Fourier Transform Infrared Spectroscopy, Academic Press, San Diego, CA, 1990, p. 168.
11. J.M. Willamson, R.J. Bowling, R.L. McCreery, Appl. Spectrosc. 43 (1989) 372.
12. B. Chase, Y. Talmi, Appl. Spectrosc. 45 (1991) 929.
13. C. Engert, V. Decken, W. Kiefer, S. Umapathy, H. Hamaguchi, Appl. Spectrosc. 48 (1994) 933.
14. L.A. Utracki, Polymer Alloys and Blends, Thermodynamics and Rheology, Carl Hanser, Munich, 1989.
15. R.E. Dumcan, in: Modern Plastics Encyclopedia, McGraw-Hill, New York, NY, 1988, p. 57.
16. K.W. Doak, Encyclopedia of Polymer Science and Engineering, Vol. 6, John Wiley and Sons, New York, NY, 1985, p. 421.
17. P. Robert, D. Bertrand, Sci. Aliments 5 (1985) 501.
18. P. Geladi, D. McDougall, H. Martens, Appl. Spectrosc. 39 (1985) 491.
19. T. Isaksson, T. Naes, Appl. Spectrosc. 42 (1988) 1273.
20. H.W. Siesler, K. Holland-Moritz, Infrared and Raman Spectroscopy of Polymers, Marcel Dekker, New York, NY, 1980.
21. R.G. Brown, J. Chem. Phys. 38 (1963) 221.
22. G.R. Strobl, W. Hagendorn, J. Polym. Sci. Polym. Phys. Ed. 16 (1978) 1181.
23. M. Glotin, R. Domszy, L. Mandelkern, J. Polym. Sci. Polym. Phys. Ed. 21 (1983) 285.
24. K. Matsukawa, H. Inoue, Kagaku To Kogyo Osaka 65 (1991) 355, in Japanese.
25. R.L. Wintermyer, W.C. Buzanowski, Encyclopedia of Polymer Science and Engineering, Vol. 16, John Wiley and Sons, New York, NY, 1985, p. 236.