Evidence for heavy atom large amplitude motions in RG-cyclopropane van der Waals complexes (RG=Ne, Ar, Kr) from rotation-tunneling spectroscopy

Journal of Chemical Physics

Volumn 106, Issue 19, 1997, Pages 7968-7980

  Xu, Yunjie ^a   Jäger, Wolfgang ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; ELECTRON TRANSITIONS; ELECTRON TUNNELING; INERT GASES; ISOMERIZATION; ISOTOPES; MICROWAVE SPECTROMETERS; MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; PROPANE; VAN DER WAALS FORCES;

CYCLOPROPANE; DIPOLE MOMENT; ISOTOPOMERS; MOLECULAR SYMMETRY; ROTATION TUNNELING SPECTROSCOPY;

ELECTRON SPECTROSCOPY;

EID: 0031145711     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.473808     Document Type: Article

References (43)

1. C. A. Coulson and W. E. Moffit, J. Chem. Phys. 15, 151 (1947); Philos. Mag. 40, 1 (1949); A. D. Walsh, Nature (London) 159, 167, 712 (1947).
2. C. A. Coulson and W. E. Moffit, J. Chem. Phys. 15, 151 (1947); Philos. Mag. 40, 1 (1949); A. D. Walsh, Nature (London) 159, 167, 712 (1947).
3. C. A. Coulson and W. E. Moffit, J. Chem. Phys. 15, 151 (1947); Philos. Mag. 40, 1 (1949); A. D. Walsh, Nature (London) 159, 167, 712 (1947).
4. The Chemistry of the Cyclopropyl Group, Part 1, edited by Z. Rappoport (Wiley, New York, 1987); The Chemistry of the Cyclopropyl Group, Part 2, edited by Z. Rappoport (Wiley, New York, 1987).
5. The Chemistry of the Cyclopropyl Group, Part 1, edited by Z. Rappoport (Wiley, New York, 1987); The Chemistry of the Cyclopropyl Group, Part 2, edited by Z. Rappoport (Wiley, New York, 1987).
6. See, for example: P. B. Karadakov, J. Gerratt, D. L. Cooper, and M. Raimondi, J. Am. Chem. Soc. 116, 7714 (1994); K. B. Wiberg, R. F. W. Bader, and C. D. H. Lau, ibid. 109, 985 (1987); D. Cremer and E. Kraka, ibid. 107, 3800 (1985).
7. See, for example: P. B. Karadakov, J. Gerratt, D. L. Cooper, and M. Raimondi, J. Am. Chem. Soc. 116, 7714 (1994); K. B. Wiberg, R. F. W. Bader, and C. D. H. Lau, ibid. 109, 985 (1987); D. Cremer and E. Kraka, ibid. 107, 3800 (1985).
8. See, for example: P. B. Karadakov, J. Gerratt, D. L. Cooper, and M. Raimondi, J. Am. Chem. Soc. 116, 7714 (1994); K. B. Wiberg, R. F. W. Bader, and C. D. H. Lau, ibid. 109, 985 (1987); D. Cremer and E. Kraka, ibid. 107, 3800 (1985).
9. J. Plíva, A. Valentin, L. Henry, F. Müller, and A. Bauder, J. Mol. Spectrosc. 168, 442 (1994), and references therein.
10. Y. Endo, M. C. Chang, and E. Hirota, J. Mol. Spectrosc. 126, 63 (1987).
11. Th. Brupbacher, Ch. Styger, B. Vogelsanger, I. Ozier. and A. Bauder, J. Mol. Spectrosc. 138, 197 (1989).
12. A. C. Legon, P. D. Aldrich, and W. H. Flygare, J. Am. Chem. Soc. 102, 7584 (1980).
13. A. C. Legon, P. D. Aldrich, and W. H. Flygare, J. Am. Chem. Soc. 104, 1486 (1982).
14. L. W. Buxton, P. D. Aldrich, J. A. Shea, A. C. Legon, and W. H. Flygare, J. Chem. Phys. 75, 2681 (1981).
15. S. G. Kukolich, J. Chem. Phys. 78, 4832 (1983).
16. A. M. Andrews, K. W. Hillig II, and R. L. Kuczkowski, J. Am. Chem. Soc. 114, 6765 (1992).
17. A. M. Andrews, K. W. Hillig II, and R. L. Kuczkowski, J. Chem. Phys. 96, 1784 (1992).
18. S. E. Forest and R. L. Kuczkowski, Chem. Phys. Lett. 218, 349 (1994).
19. S. E. Forest and R. L. Kuczkowski, J. Am. Chem. Soc. 118, 217 (1996).
20. A. D. Buckingham, C. Graham, and J. H. Williams, Mol. Phys. 49, 703 (1983).
21. G. C. Maitland, M. Rigby, E. B. Smith, and W. A. Wakeham, Intermolecular Forces, Their Origin and Determination (Clarendon, Oxford 1981).
22. W. Jäger, Y. Xu, and M. C. L. Gerry, J. Chem. Phys. 99, 919 (1993).
23. T. J. Balle and W. H. Flygare, Rev. Sci. Instrum. 52, 33 (1981).
24. U. Andresen, H. Dreizier, J.-U. Grabow, and W. Stahl, Rev. Sci. Instrum. 61, 3694 (1990).
25. J.-U. Grabow and W. Stahl, Z. Naturforsch. 45, 1043 (1990).
26. D. R. Rodham, S. Suzuki, R. D. Suenram, F. J. Lovas, S. Dasgupta, W. A. Goddard III, and G. A. Blake, Nature 362, 735 (1993).
27. Th. Brupbacher, J. Makarewicz, and A. Bauder, J. Chem. Phys. 101, 9736 (1994).
28. E. Arunan, T. Emilsson, and H. S. Gutowsky, J. Chem. Phys. 101, 861 (1994).
29. Th. Brupbacher and A. Bauder, Chem. Phys. Lett. 173, 435 (1990).
30. T. D. Klots, T. Emilsson, and H. S. Gutowsky, J. Chem. Phys. 97, 5335 (1992).
31. K. I. Peterson and W. J. Klemperer, J. Chem. Phys. 81, 3842 (1984); 85, 725 (1986).
32. K. I. Peterson and W. J. Klemperer, J. Chem. Phys. 81, 3842 (1984); 85, 725 (1986).
33. P. A. Block, L. G. Pedersen, and R. E. Miller, J. Chem. Phys. 98, 3754 (1993).
34. J. K. G. Watson, Vibrational Spectra and Structure: A Series of Advances, edited by J. R. Durig (Elsevier, New York, 1977), Vol. 6, pp. 1-89.
35. T. Ogata, W. Jäger, I. Ozier, and M. C. L. Gerry, J. Chem. Phys. 98, 9399 (1993).
36. A. D. Buckingham and W. Urland, Chem. Rev. 75, 113 (1975).
37. A. D. Buckingham and L. Fan-Chen, Int. Rev. Phys. Chem. 1, 253 (1981).
38. Y. Xu and A. R. W. McKellar, Mol. Phys. 88, 859 (1996).
39. L. Zachilas and S. C. Farantos, Chem. Phys. 154, 55 (1991).
40. R. J. LeRoy, LEVELO.O, A Computer Program Solving the Radial Schrödinger Equation for Bound and Quasibound Levels, and Calculating Various Expectation Values and Matrix Elements, University of Waterloo, Chemical Physics Research Report CP-555 (1995).
41. P. R. Bunker, Molecular Symmetry and Spectroscopy (Academic, New York, 1979).
42. P. R. Bunker, Y. Xu, and W. Jäger (unpublished).
43. M. D. Brookes, D. J. Hughes, and B. J. Howard, J. Chem. Phys. 104, 5391 (1996).