Syntheses and radical polymerization behavior of methacrylamides having peptide moieties: Effect of the methylene chain introduced between the methacrylamide and peptide moieties on the polymerizability and polymer structure

Macromolecules

Volumn 30, Issue 10, 1997, Pages 2902-2906

  Murata, Hironobu ^a   Sanda, Fumio ^a   Endo, Takeshi ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

FREE RADICAL POLYMERIZATION; GEL PERMEATION CHROMATOGRAPHY; INFRARED SPECTROSCOPY; MOLECULAR WEIGHT DISTRIBUTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYPEPTIDES; POLYSTYRENES; SYNTHESIS (CHEMICAL); THERMOGRAVIMETRIC ANALYSIS;

POLYMETHACRYLAMIDE;

POLYMERS;

EID: 0031144023     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma970131t     Document Type: Article

References (12)

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4. (a) Ishikawa, K.; Endo, T. J. Am. Chem. Soc. 1988, 110, 2061.
5. (b) Ishikawa, K.; Endo, T. J. Polym. Sci., Part C: Polym. Lett. 1989, 27, 339.
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7. (d) Ishikawa, K.; Endo, T. J. Polym. Sci., Part A: Polym. Chem. 1990, 28, 3525.
8. Sanda, F.; Nakamura, M.; Endo, T.; Takata, T.; Handa, H. Macromolecules 1994, 23, 1455.
9. Murata, H.; Sanda, F.; Endo, T. Macromolecules 1996, 29, 5535.
10. IR measurement in DMF was unsatisfactory because of the overlap of the amide earbonyl absorption peaks of the monomers and DMF.
11. Townend, R.; Kumosinski, T. F.; Timasheff, S. N.; Fasman, G. D.; Davidson, B. Biochem. Biophys. Res. Commun. 1966, 23, 163.
12. The similar CD patterns of poly(MA-LA-M) and poly(MA-L-M) indicate the special conformation of the two polymers is derived to the same principle (see supporting information, Figure SI). The larger isotacticity of poly(MA-L-M) (syndio: hetero:iso = 46:41:13) than that of poly(MMA) (syndio:hetero: iso = 59:36:5) prepared in a similar radical condition may be concerned with the special conformation.