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Volumn 380, Issue 2-3, 1997, Pages

Adsorption mode change from adlayer-to restructuring-type with increasing coverage, evidenced by structural determination of c(2 × 2)→(4 × 4)→(5 × 5) sequence formed on Ni(001) by Li deposition

Author keywords

Alkali metals; Alloys; Catalysis; Low energy electron diffraction (LEED); Metal metal interfaces

Indexed keywords

ADSORPTION; ATOMS; CATALYSIS; CRYSTAL ORIENTATION; DEPOSITION; INTERFACES (MATERIALS); LITHIUM; LOW ENERGY ELECTRON DIFFRACTION; MONOLAYERS; SUBSTRATES; SURFACE STRUCTURE;

EID: 0031143722     PISSN: 00396028     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0039-6028(97)00006-X     Document Type: Article
Times cited : (10)

References (28)
  • 19
    • 30244529827 scopus 로고    scopus 로고
    • note
    • The coverage is defined to be the ratio of the number density of adatoms to that of substrate surface atoms in the ideal top layer of substrate surface.
  • 21
    • 30244452349 scopus 로고    scopus 로고
    • note
    • max = 6 is sufficient for the determination of structures in the Ni(001)-Li system.
  • 25
    • 30244505728 scopus 로고    scopus 로고
    • note
    • The c(n√2 × √2)R45, where n = 9,7,5, and quasihexagonal structures would follow the c(2 × 2), successively, with increasing Li coverage on Ni(001) at 370 K, because these structures are formed at 230 K (see Refs. [18,22]).
  • 26
    • 30244568217 scopus 로고    scopus 로고
    • personal communication
    • T. Oguchi, personal communication.
    • Oguchi, T.1
  • 27
    • 30244482539 scopus 로고    scopus 로고
    • note
    • The ratios of alkali-metal atoms' radii with respect to substrate atoms' radii are almost the same at 1.18, 1.27 and 1.21 for Li-Cu, Na-Ag and Li-Ni systems, respectively.
  • 28
    • 30244485442 scopus 로고    scopus 로고
    • note
    • The reason why the (3 × 3) SAS is not formed for Li/Ni(001) can be understood by considering the change in the adsorption mode that occurs at a coverage in a range of 0.556 0.625.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.