Synthesis and characterization of the mixed valence Cu(I)/Cu(II) 3,5-bis(trifluoromethyl)-pyrazolate complex, [Cu(II)2Cu(I)(F6dmpz)5]

Canadian Journal of Chemistry

Volumn 75, Issue 5, 1997, Pages 491-498

  Ehlert, Martin K ^a   Storr, Alan ^a   Summers, David A ^a   Thompson, Robert C ^a  

^a UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

3,5 bis(trifluoromethyl)pyrazolates; Antiferromagnetism; Copper; Trimetallic; X ray structure

Indexed keywords

ANTIFERROMAGNETISM; COPPER COMPOUNDS; CRYSTAL STRUCTURE; CURVE FITTING; LEAST SQUARES APPROXIMATIONS; MAGNETIC COUPLINGS; MAGNETIC PERMEABILITY; MOLTEN MATERIALS; SYNTHESIS (CHEMICAL);

BLEANEY BOWERS EQUATION;

ORGANOMETALLICS;

EID: 0031142851     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v97-057     Document Type: Article

References (17)

1. G. La Monica and G.A. Ardizzoia. Prog. Inorg. Chem. In press. (1997).
2. M.K. Ehlert, S.J. Rettig, A. Storr, R.C. Thompson, and J. Trotter. Can. J. Chem. 67, 1970 (1989).
3. M.K. Ehlert, S.J. Rettig, A. Storr, R.C. Thompson, and J. Trotter. Can. J. Chem. 69, 432 (1991).
4. M.K. Ehlert, S.J. Rettig, A. Storr, R.C. Thompson, and J. Trotter. Can. J. Chem. 70, 1121 (1992).
5. M.K. Ehlert, S.J. Rettig, A. Storr, R.C. Thompson, and J. Trotter. Can. J. Chem. 67, 331 (1993).
6. S. Trofimenko. J. Am. Chem. Soc. 89, 3165 (1967).
7. M.K. Ehlert, S.J. Rettig, A. Storr, R.C. Thompson, and J. Trotter. Can. J. Chem. 68, 1444 (1990).
8. M.K. Ehlert, S.J. Rettig, A. Storr, R.C. Thompson, and J. Trotter. Can. J. Chem. 70, 2161 (1992).
9. W.W. Porterfield. Inorganic chemistry. A unified approach. Addison - Wesley, Reading, Mass. 1984. p. 168.
10. M. Angaroni, G.A. Ardizzoia, T. Beringhelli, G. LaMonica, D. Gatteschi, N. Masciocchi, and M. Moret. J. Chem. Soc. Dalton Trans. 3305 (1990).
11. F.B. Hulsbergen, R.W.M. ten Hoedt, G.C. Verschoor, J. Reedijk, and A.L. Spek. J. Chem. Soc. Dalton Trans. 539 (1983).
12. B. Bleaney and K.D. Bowers. Proc. R. Soc. London, Ser. A: 226, 95 (1952).
13. E. Konig. Landolt-Börnstein numerical data and functional relationships in science and technology. New series. Vol. II/2. Edited by K.H. Hellwege and A.M. Hellewege. Springer-Verlag, Berlin. 1966.
14. T.N. Doman, D.E. Williams, J.F. Banks, R.M. Buchanan, H.-R. Chang, R.J. Webb, and D.M. Hendrickson. Inorg. Chem. 29, 1058 (1990), and refs. therein.
15. T. Kamiusuki, H. Okawa, N. Matsumoto, and S. Kida. J. Chem. Soc. Dalton Trans. 195 (1990).
16. J. Pons, X. López, J. Casabó, F. Teixidor, A. Caubet, J. Ruis, and C. Miravitlles. Inorg. Chim. Acta, 195, 61 (1992).
17. B. Mernari, F. Abraham, M. Legrenee, M. Drillon, and P. Legoll. J. Chem. Soc Dalton Trans. 1707 (1993).