Critical evaluation of thermodynamics of complex formation of metal ions in aqueous solutions II. Hydrolysis and hydroxo-complexes of Cu2+ at 298.15 K

Hydrometallurgy

Volumn 45, Issue 1-2, 1997, Pages 37-51

  Plyasunova, Natalia V ^a,b   Wang, Mingsheng ^a   Zhang, Yu ^a   Muhammed, Mamoun ^a  

^a ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

^b INSTITUTE OF EXPERIMENTAL MINERALOGY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; HYDROLYSIS; MATHEMATICAL MODELS; REACTION KINETICS; SOLUTIONS; THERMODYNAMIC PROPERTIES;

HYDROXO COMPLEXES; SPECIFIC INTERACTION THEORY (SIT);

COPPER;

EID: 0031140774     PISSN: 0304386X     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0304-386x(96)00073-4     Document Type: Article

References (32)

1. Smith, R.M. and Martell, A.E., Critical stability Constants, Vol. 4: Inorganic Complexes. Plenum Press, New York (1976).
2. Martell, A.E. and Smith, R.M., Critical Stability Constants, Vol. 5: First Supplement. Plenum Press, New York (1982).
3. Smith, R.M. and Martell, A.E., Critical Stability Constants, Vol. 6: Second Supplement. Plenum Press, New York (1989).
4. Wang, M., Zhang, Yu and Muhammed, M., Critical evaluation of thermodynamics of complex formation of metal ions in aqueous solutions I. Description of evaluation methods. Hydrometallurgy, 45 (1997): 21-36, this issue.
5. Chase, M.W., Jr., Davies, C.A., Downey, J.R., Jr., Frurip, D.J., McDonald, R.A. and Syverud, A.N., JANAF Thermochemical Tables, 3rd ed. J. Phys. Chem. Ref. Data, 14 (1985), Suppl. No. 1.
6. Näsänen, R. and Tamminen, V., The equilibria of cupric hydroxy salts in mixed aqueous solutions of cupric and alkali salts at 25°C. J. Am. Chem. Soc., 71 (1949): 1994-1998.
7. Sircar, S.C. and Prasad, B., A note on the solubility of hydrated copper oxide in nitric acid. J. Ind. Chem. Soc., 33 (1956): 361.
8. 2+. Helv. Chim. Acta, 53 (1970): 186-197.
9. Cox, J.D., Wagman, D.D. and Medvedev, V.A., CODATA Key Values for Thermodynamics. HPC, New York (1989).
10. Schindler, P., Althaus, H., Hofer, F. and Minder, W., Löslichkeitsprodukte von Metalloxiden und -hydroxiden, Löslichkeitsprodukte von Zinkoxid, Kupferhydroxid und Kupferoxid in Abhändigkeit von Teilchengröss und molarer Oberfläche. Ein Beitrag zur Thermodynamik von Grenzflächen fest-flussig. Helv. Chim. Acta, 48 (1965) 5, 1205-1215.
11. McDowell, L.A. and Johnston, H.L., The solubility of cupric oxide in alkali and the second dissociation constant of cupric acid, The analysis of very small amounts of copper. J. Am. Chem. Soc., 58 (1936): 2009-2014.
12. Akhmetov, K.M., Buketov, E.A. and Ugorets, M.I., Tr. Khim. Metall. Inst. Akad. Nauk Kaz. SSR, 3 (1967): 119-128.
13. Grenthe, I., Fuger, J., Konings, R.J.M., Lemire, R.J., Mueller, A.B., Nguen-Trung, C. and Wanner, H., Chemical Thermodynamics of Uranium. Elsevier, Amsterdam (1992).
14. Var'ash, L.N., Hydrolysis of bivalent copper at temperatures of 25-350°C. Geochemistry (Russia), (1985): 1003-1013.
15. 2+ oxide solubility behavior in aqueous sodium phosphate solutions at elevated temperatures, J. Sol. Chem., 21 (1992): 179-200.
16. 2+ ion hydrolysis in aqueous solution, J. Sol. Chem., 9 (1980): 269-277.
17. Stella, R. and Ganzerli-Valentini, M.T., Copper ion-selective electrode for determination of inorganic copper species in fresh water. Anal. Chem., 51 (1979): 2148-2151.
18. 2+ hydrolysis by copper ion-selective electrode. Anal. Chim. Acta, 156 (1984): 19-31.
19. Pedersen, K.J., Kgl. Danske Videnskap Selskab Mater. Fys. Meddl., 20 (7).
20. 2+. Arkiv Kemi., 9 (1956): 175-189.
21. 2+ ion. J. Chem. Soc., (1960): 3189-3196.
22. Achenza, F., Hydrolysis of the Cu+ + ion. Ann. Chim. (Rome), 54 (1964): 240-245.
23. Childs, C.W., A potentiometric study of equilibria in aqueous divalent metal orthophosphate solutions. Inorg. Chem., 9 (1970): 2465-2469.
24. 2+ ion in heavy water, Bull. Chem. Soc. Jpn., 43 (1970): 3155-3158.
25. 4 as an ionic medium, Bull. Chem. Soc. Jpn., 45 (1972): 1735-1738.
26. Arena, G., Cali, R., Rizzarelli, E. and Sammartano, S., Thermodynamic study on the formation of the cupric ion hydrolytic species. Thermochim. Acta, 16 (1976): 315-321.
27. 2+. J. Chem. Soc. Dalton Trans., (1979): 232-235.
28. 2+ ions hydrolysis at 25 and 50°C, Zh. Neorg. Khim., 27 (1982): 1455-1459.
29. 2+ ion concentrations and 25°C. Acta Chem. Scand., A38 (1984): 517-522.
30. 2+. Transit. Met. Chem., 10 (1985): 1-4.
31. 2 solutions. Acta Chem. Scand., 22 (1968): 1097-1101.
32. 2+ ions at 25 and 50°C. Zh. Neorg. Khim., 27 (1982): 1455-1459.