Hydration and dynamics in reverse micelles of the triblock copolymer EO13PO30EO13 in water/o-xylene mixtures: A spin probe study

Macromolecules

Volumn 30, Issue 10, 1997, Pages 2923-2933

  Caragheorgheopol, Agneta ^a,c   Pilar, Jan ^b   Schlick, Shulamith ^a  

^a University of Detroit Mercy   (United States)

^b INSTITUTE OF MACROMOLECULAR CHEMISTRY   (Czech Republic)

^c ACADEMY OF ROMANIAN SCIENTISTS   (Romania)

Author keywords

[No Author keywords available]

Indexed keywords

ANISOTROPY; ELECTRON SPIN RESONANCE SPECTROSCOPY; HYDRATION; INTERFACES (MATERIALS); MIXTURES; POLYETHYLENE OXIDES; POLYPROPYLENES;

REVERSE MICELLES; TRIBLOCK COPOLYMERS;

BLOCK COPOLYMERS;

EID: 0031139688     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9617328     Document Type: Article

References (41)

1. Reverse Micelles; Luisi, P. L., Straub, B. E., Eds.; Plenum Press: New York, 1984.
2. Structure and Reactivity in Reverse Micelles; Pileni, M. P., Ed.; Elsevier: Amsterdam, 1989.
3. Haering, G.; Luisi, P. L.; Hauser, H. J. Phys. Chem. 1988, 92, 3574.
4. Lossia, S. A.; Flore, S. G.; Nimmala, S.; Li, H.; Schlick, S. J. Phys. Chem. 1992, 96, 6071.
5. Okazaki, M.; Toriyama, K. J. Magn. Reson. 1988, 79, 158.
6. Ravey, J. C.; Buzier, M.; Picot, J. C. J. Colloid Interface Sci. 1984, 97, 9.
7. Ravey, J. C.; Buzier, M.; In Surfactants in Solution; Mittal, K. L., Lindman, B., Ed.; Plenum Press: New York, 1985; Vol. 3, p 1759.
8. Olsson, U.; Würz, U.; Strey, R. J. Phys. Chem. 1993, 97, 4535.
9. Friberg, S. E.; Christenson, H.; Bertrand, G.; Larsen, D. W. In Reverse Micelles; Luisi, P. L., Straub, B. E., Eds.; Plenum Press: New York, 1984; p 105.
10. Strey, R. Colloid Polym. Sci. 1994, 272, 1005.
11. Zhu, D.-M.; Wu, X.; Schelly, Z. A. J. Phys. Chem. 1992, 96, 7121 and references therein.
12. Caldararu, H.; Caragheorgheopol, A.; Dimonie, M.; Donescu, D.; Dragutan, I.; Marinescu, N. J. Phys. Chem. 1992, 96, 7109.
13. Caldararu, H.; Caragheorgheopol, A.; Vasilescu, M.; Dragutan, I.; Lemmetyinen, H. J. Phys. Chem. 1994, 98, 5320.
14. Almgren, M.; Brown, W.; Hvidt, S. Colloid Polym. Sci. 1995, 273, 2.
15. Alexandridis, P.; Hatton, T. A. Colloids Surf. A 1995, 96, 1.
16. Pluronic and Tetronic Surfactants; Technical Brochure; BASF Corp.: Parsipanny, NJ, 1989.
17. (a) Karlstrom, G. J. Chem. Phys. 1985, 89, 4962.
18. (b) Anderson, M.; Karlstrom, G. J. Chem. Phys. 1985, 89, 4957.
19. Linse, P. (a) Macromolecules 1993, 26, 4437
20. (b) J. Phys. Chem. 1993, 97, 13896.
21. Hurter, P. N.; Scheutjens, J. M. H. M.; Hatton, T. A. Macromolecules 1993, 26, 5030.
22. Holland, R. J.; Parker, E. J.; Guiney, K.; Zeld, F. R. J. Phys. Chem. 1995, 99, 11981.
23. Israelachvili, J. Intermolecular and Surface Forces, 2nd. ed.; Academic Press: London, 1991; p 381.
24. Wu, G.; Zhou, Z.; Chu, B. Macromolecules 1993, 26, 2117.
25. Wu, G.; Chu, B.; Schneider, D. K. J. Phys. Chem. 1994, 98, 12018.
26. Alexandridis, P.; Olsson, U.; Lindman, B. Macromolecules 1995, 28, 7700.
27. Zhou, L.; Schlick, S. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1996, 37, 829.
28. Malka, K.; Schlick, S. Macromolecules 1997, 30, 456.
29. Szajdzinska-Pietek, E.; Schlick, S.; Plonka, A. Langmuir 1994, 10, (a) 1101. (b) 2188. (c) Szajdzinska-Pietek, E.; Schlick, S. In Ionomers: Characterization, Theory and Applications; Schlick, S., Ed.; CRC Press: Boca Raton, FL, 1996, Chapter 7.
30. Szajdzinska-Pietek, E.; Schlick, S.; Plonka, A. Langmuir 1994, 10, (a) 1101. (b) 2188. (c) Szajdzinska-Pietek, E.; Schlick, S. In Ionomers: Characterization, Theory and Applications; Schlick, S., Ed.; CRC Press: Boca Raton, FL, 1996, Chapter 7.
31. Kutsumizu, S.; Schlick, S. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1996, 37, 825.
32. Kutsumizu, S.; Hara, H.; Schlick, S. Macromolecules, in press.
33. Gaffney, B. J. In Spin Labeling, Theory and Applications; Berliner, L. J., Ed.; Academic Press: New York, 1976; p 570.
34. Szajdzinska-Pietek, E.; Pilar, J.; Schlick, S. J. Phys. Chem. 1995, 99, 313.
35. Goldman, S. A.; Bruno, G. V.; Polnazsek, C. F.; Freed, J. H. J. Chem. Phys. 1972, 56, 716.
36. Ottaviani, M. F.; Baglioni, P.; Martini, G. J. Phys. Chem. 1983, 87, 3147.
37. Bales, B. In Biological Magnetic Resonance; Berliner, L. J., Reuben, J. Eds.; Plenum Press: New York, 1989; Vol. 8, Chapter 2.
38. I as done in this paper, B is negative. In some cases, for instance in ref 34, ΔH is defined in terms of the spectral index M, and B becomes positive.
39. Pilar, J.; Labsky, J.; Schlick, S. J. Phys. Chem. 1995, 99, 12947.
40. calc.
41. Zhang, K.; Khan, A. Macromolecules 1995, 28, 3807.