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Volumn 30, Issue 10, 1997, Pages 2843-2847

Initiation mechanisms in radical polymerization: Reaction of tert-alkyl peroxypivalates with methyl methacrylate

Author keywords

[No Author keywords available]

Indexed keywords

INITIATION PROCESS; PHOTOCHEMICAL DEGRADATION; THERMOLYSIS;

EID: 0031139574     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9615765     Document Type: Article
Times cited : (24)

References (41)
  • 13
    • 0002351264 scopus 로고
    • Klingsberg, A., Piccininni, R. M., Salvatore, A., Baldwin, T., Eds.; Wiley-Interscience: New York
    • (a) Sheppard, C. S. In Encyclopedia of Polymer Science and Engineering, 2nd ed.; Klingsberg, A., Piccininni, R. M., Salvatore, A., Baldwin, T., Eds.; Wiley-Interscience: New York, 1988; Vol. 11, pp 1-21.
    • (1988) Encyclopedia of Polymer Science and Engineering, 2nd Ed. , vol.11 , pp. 1-21
    • Sheppard, C.S.1
  • 15
    • 0004371299 scopus 로고
    • Peroxypivalate 1 undergoes a concerted two-bond decomposition with loss of carbon dioxide and accompanied by the cage radical recombination reaction (about 50%).The half-lives of 1b and 1c at 60 °C have been reported to be 5.5 and 5.7 h respectively (in cumene). Komai, T.; Matsuyama, K.; Matsushima, M. Bull.Chem. Soc. Jpn. 1988, 61, 1641.
    • (1988) Bull.Chem. Soc. Jpn. , vol.61 , pp. 1641
    • Komai, T.1    Matsuyama, K.2    Matsushima, M.3
  • 17
    • 4043073310 scopus 로고
    • Eastmond, G. C., Ed.; Pergamon, London
    • (b) Moad, G.; Solomon, D. H. In Comprehensive Polymer Science; Eastmond, G. C., Ed.; Pergamon, London, 1989; Vol. 3; pp 116-117.
    • (1989) Comprehensive Polymer Science , vol.3 , pp. 116-117
    • Moad, G.1    Solomon, D.H.2
  • 26
    • 4043149827 scopus 로고    scopus 로고
    • note
    • The values were extrapolated to 60 °C from the data at 0, 25, and 40 °C by using the Arrhenius equation.
  • 28
    • 85087192989 scopus 로고    scopus 로고
    • note
    • 21,22


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.