The structure of diethylaminosulfur trifluoride (DAST) - A combined theoretical and nuclear magnetic resonance study

Journal of Fluorine Chemistry

Volumn 82, Issue 2, 1997, Pages 181-183

  Klapötke, Thomas M ^a   Schulz, Axel ^a  

^a UNIVERSITY OF GLASGOW   (United Kingdom)

Author keywords

14N 19F NMR; Ab initio computations; Aminosulphur trifluoride; DAST; Diethylaminosulphur trifluoride

Indexed keywords

EID: 0031138984     PISSN: 00221139     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-1139(96)03524-5     Document Type: Article

References (8)

1. [1]L.N. Markovskij, V.E. Pashinnik and A.V. Kirsanov, Synthesis, (973) 787.
2. [2] G. Hägele and A. Haas, J. Fluorine Chem., 76 (1996) 15, and references cited therein, especially refs. 2-14.
3. [3] S.P.v. Halasz and O. Glemser, Chem. Ber., 103 (1970) 594.
4. [4] S.P.v. Halasz and O. Glemser, Chem. Ber., 104 (1971) 1247.
5. [5] M.J. Frisch, G.W. Trucks, H.B. Schlegel, P.M.W. Gill, B.G. Johnson, M.A. Robb, J.R. Cheeseman, T. Keith, G.A. Petersson, J.A. Montgomery, K. Raghavachari, M.A. Al-Laham, V.G. Zakrzewski, J.V. Ortiz, J.B. Foresman, C.Y. Peng, P.Y. Ayala, W. Chen, M.W. Wong, J.L. Andres, E.S. Replogle, R. Gomperts, R.L. Martin, D.J. Fox, J.S. Binkley, D.J. Degrees, J. Baker, J.P. Stewart, M. Head-Gordon, C. Gonzalez and J.A. Pople, Gaussian 94. Revision B.2, Gaussian. Pittsburgh, PA, 1995.
6. [6] R.J. Gillespie and E.A. Robinson, Angew. Chem., 108 (1996) 539; Angew. Chem., Int. Ed. Engl., 35 (1996) 477.
7. [6] R.J. Gillespie and E.A. Robinson, Angew. Chem., 108 (1996) 539; Angew. Chem., Int. Ed. Engl., 35 (1996) 477.
8. [7] T.M. Klapötke and I.C. Tornieporth-Oetting, Nichtmetallchemie, VCH, Weinheim, 1994, p. 310.