Reactions of electrons in radiolysis of sulfoxides

Radiation Physics and Chemistry

Volumn 49, Issue 4, 1997, Pages 451-457

  Shishlov, N M ^a   Vasil'ev, Yu V ^b   Konovalov, V V ^c   Korobeynikova, V N ^a  

^a INSTITUTE OF ORGANIC CHEMISTRY   (Russian Federation)

^b INSTITUTE OF PHYSICS OF MOLECULES AND CRYSTALS   (Russian Federation)

^c INSTITUTE OF CHEMICAL KINETICS AND COMBUSTION   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTATIONAL METHODS; CRYSTAL LATTICES; ELECTRON RESONANCE; ELECTRONS; IONS; MASS SPECTROMETRY; SULFUR COMPOUNDS; THERMODYNAMIC STABILITY;

ANION RADICAL PAIRS (ARP); DIMETHYLSULFONE; RADIOLYSIS; RESONANCE ELECTRON CAPTURE; SULFOXIDES;

RADIATION DAMAGE;

SULFOXIDE;

ARTICLE; CONTROLLED STUDY; ELECTRON; RADIOLYSIS;

EID: 0031128308     PISSN: 0969806X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0969-806X(96)00156-9     Document Type: Article

References (20)

1. Alfassi, Z. B. (1988) Radiation chemistry of sulfoxides and sulfones. In The Chemistry of Sulphones and Sulphoxides (Edited by S. Patai, Z. Rappoport and Ch. Stirling), p. 889, Wiley, New York.
2. Blais, J.-C., Cottin, M. and Gitton, B. (1970). Ionization positive et negative dans le dimethylsulfoxide en phase gazeuse. J. Chim. Phys. Physiochim. Biol. 67, 1475.
3. 6 sulfoxide at 77 K. J. Phys. Chem. 78, 1882.
4. Cooper, T. K., Walker, D. C., Gillis, H. A. and Klassen, N. V. (1973). The pulse radiolysis of dimethylsulfoxide and binary mixtures with water. Can. J. Chem. 51, 2195.
5. Farrant, J. (1965). Mechanism of cell damage during freezing and thawing and its prevention. Nature 205, 1284.
6. Gollnick, K. and Stracke, H.-U. (1973). Direct and sensitized photolysis of DMSO in solution. Pure and Appl. Chem. 33, 217.
7. Khvostenko, V. I. (1981) Mass-spectrometry of Negative Ions in Organic Chemistry, p. 38. Nauka, Moscow.
8. 2O solutions by photoelectron emission method. Khim. Vysokikh Ener. 18, 5.
9. Koulkes-Pujo, A. M., Michael, B. D. and Hart, E. J. (1971). Scavenger studies of electron pulse irradiated solutions at hydrated electron half lives in the range 35-0.35 nanoseconds. Radiat. Phys. Chem. 3, 333.
10. Meissner, G., Henglein, A. and Beck, G. (1967). Pulsradiolytische untersuchung von Dimethyltioather und Dimethylsulfoxyd in wasriger Losung. Z. Naturforsch 22b, 13.
11. Mozumder, A. and Magee, J. Z. (1975). The early events of radiation chemistry. Radiat. Phys. Chem. 7, 83.
12. Nelson, D. J. (1978). CIDNP in pulse radiolysis of aqueous dimethyl sulfoxide. J. Phys. Chem. 82, 1400.
13. Ohno, S. (1967). The photochemistry of aqueous hexacyanoferrate (II) solutions - IV. A study of the mechanism of the photoelectron detachment. Bull. Chem. Soc. Jpn. 40, 1779.
14. Rassmussen, D. H. and Mackenzie, A. P. (1968). Phase diagram for the system water-dimethylsulfoxide. Nature 220, 1315.
15. Razem, D. and Hamill, W. H. (1978). Temperature dependence of electron scavenging in ethanol and ethanol-o-d. J. Phys. Chem. 82, 1347.
16. 6. Khim. Vysokikh. Ener. 16, 523.
17. Shishlov, N. M., Korobeynikova, V. N., Mazunov, V. A., Panasenko, A. A. and Sadykov, R. A. (1983a). Anion-radical pairs in diethylsulfoxide. Khim. Vyosokikh. Ener. 17, 179.
18. Shishlov, N. M., Ivanov, A. I., Sadykov, R. A., Panasenko, A. A. and Korobeynikova, V. N. (1983b). Qualitative model of anion-radical pair in sulfoxides. Khim. Vysokikh. Ener. 17, 554.
19. Shishlov, N. M., Sadykov, R. A., Panasenko, A. A. and Mazunov, V. A. (1990). Comparison of electron capture processes in gaseous and condensed phases on example of dimethylsulfoxide. Khim. Vysokikh, Ener. 24, 108.
20. Symons, M. C. R. (1976). Unstable intermediates, Part CLXIII, Methyl radical anion adducts: radiation effects on dimethyl sulfoxide, dimethyl sulphone and their solutions in water and methanol. J. Chem. Soc. Perkin II, p. 908.