A Thermodynamic Model for the Partition of All Ionic Species in Reverse Micellar Extraction of Amino Acids with a Cationic Surfactant

Separation Science and Technology

Volumn 32, Issue 7, 1997, Pages 1189-1208

  Wang, W ^a   Vera, J H ^a  

^a MCGILL UNIVERSITY   (Canada)

Author keywords

Amino acids; Cationic surfactant; Extraction; Reverse micelles; Thermodynamics

Indexed keywords

COMPUTATIONAL METHODS; EXTRACTION; MATHEMATICAL MODELS; MICELLES; SURFACE ACTIVE AGENTS; THERMODYNAMICS;

CATIONIC SURFACTANTS; REVERSE MICELLAR EXTRACTION;

AMINO ACIDS;

EID: 0031121959     PISSN: 01496395     EISSN: None     Source Type: Journal    
DOI: 10.1080/01496399708000955     Document Type: Article

References (37)

1. Adachi, M., Harada, M., Shioi, A., and Sato, Y., "Extraction of Amino Acids to Microemulsion," J. Phys. Chem., 95, 7925-7931 (1991).
2. Allen, R. M., and Addison, P. A., "Ion Exchange Equilibria for Ternary Systems from Binary Exchange Data," Chem. Eng. J., 44, 113-118 (1990).
3. Ashrafizadeh, S. N., Weber, M. E., and Vera, J. H., "Cation Exchange with Reverse Micelles," Ind. Eng. Chem. Res., 32, 125-132 (1993).
4. Bratko, D., Luzar, A., and Chen, S. H., "Electrostatic Model for Protein/Reverse Micelle Complexation," J. Chem. Phys., 89, 545-550 (1988).
5. Bruno, P., Caselli, M., Luisi, P. L., Maestro, M., and Traini, A., "A Simplified Thermodynamic Model for Protein Uptake by Reverse Micelles: Theoretical and Experimental Results," J. Phys. Chem., 94, 5908-5917 (1990).
6. Caponetti, E., Lizzio, A., and Triolo, R., "Alcohol Partition in a Water-in-Oil Microemulsion from Small-Angle Neutron Scattering," Langmuir, 8, 1554-1562 (1992).
7. Curry, J. E., Feller, S. E., and Mcquarrie, D. A., "A Variational Solution of the Nonlinear Poisson-Boltzmann Equation Inside a Sphere Cavity," J. Colloid Interface Sci., 143, 527-531 (1991).
8. Fletcher, P. D. I., "The Partitioning of Solutes between Water-in-Oil Microemulsions and Conjugate Aqueous Phases," J. Chem. Soc., Faraday Trans. I, 82, 2651-2664 (1986).
9. Furusaki, S., and Kishi, K., "Extraction of Amino Acids by Reversed Micelles," J. Chem. Eng. Jpn., 23, 91-93 (1990).
10. Goklen, K. E., and Hatten, T. A., "Liquid-Liquid Extraction of Low Molecular-Weight Proteins by Selective Solubilization in Reversed Micelles," Sep. Sci. Technol., 22, 831-841 (1987).
11. Hano, T., Ohtake, T., Matsumoto, M., Kitayama, D., Hori, E., and Nakashio, F., "Extraction Equilibria of Amino Acids with Quaternary Ammonium Salt," J. Chem. Eng. Jpn., 24, 20-24 (1991).
12. Jolivalt, C., Minier, M., and Renon, H., "Extraction of α-Chymotrypsin Using Reversed Micelles," J. Colloid Interface Sci., 135, 85-96 (1990).
13. Karpe, P., and Ruckenstein, E., "Effect of Hydration Ratio on the Degree of Counterion Binding and pH Distribution in Reverse Micelles with Aqueous Core," Ibid., 137, 408-424 (1990).
14. Karpe, P., and Ruckenstein, E., "The Enzymatic Superactivity in Reverse Micelles: Role of the Dielectric Constant," Ibid., 141, 534-552 (1991).
15. Krei, G. A., and Hustedt, H., "Extraction of Enzymes by Reverse Micelles," Chem. Eng. Sci., 47, 99-110 (1992).
16. Lang, J., Mascolo, G., Zana, R., and Luisi, P. L., "Structure and Dynamics of Cetyltrimethyl Ammonium Bromide Water-in-Oil Microemulsions," J. Phys. Chem., 94, 3069-3074 (1990).
17. Lang, J., Lalem, N., and Zana, R., "Quaternary Water in Oil Microemulsions. 1. Effect of Alcohol Chain Length and Concentration on Droplet Size and Exchange of Material between Droplets," Ibid., 95, 9533-9541 (1991).
18. Leodidis, E. B., and Hatton, T. A., "Specific Ion Effects in Electrical Double Layers: Selective Solubilization of Cations in AOT Reversed Micelles," Langmuir, 5, 741-753 (1989).
19. Leodidis, E. B., and Hatton, T. A., "Amino Acids in Reversed Micelles. 4. Amino Acids as Cosurfactants," J. Phys. Chem., 95, 5957-5965 (1991).
20. Lewis, G. N., and Randall, M. (revised by Pitzer, K. S., and Brewer, L.), Thermodynamics, 2nd ed., McGraw-Hall, New York, 1961.
21. Nishiki, T., Sato, L., Kataoka, T., and Kato, D., "Partitioning Behavior and Enrichment of Proteins with Reversed Micellar Extraction: 1. Forward Extraction of Proteins from Aqueous to Reversed Micellar Phase," Biotech. Bioeng., 42, 596-600 (1993).
22. Osseo-Asare, K., "Liquid-Liquid Distribution in Reversed Micellar Systems," Colloids Surf., 29, 403-410 (1988).
23. Pitzer, K. S., "Electrolytes. From Dilute Solutions to Fused Salts," J. Am. Chem. Soc., 102, 2902-2906 (1980).
24. Smith, R. E., and Luisi, P. L., "Micellar Solubilization of Biopolymers in Hydrocarbon Solvents. III. Empirical Definition of an Acidity Scale in Reverse Micelles," Helv. Chim. Acta, 63, 2302-2311 (1980).
25. Tanford, C., "Micelle Shape and Size," J. Phys. Chem., 76, 3020-3024 (1972).
26. Thien, M. P., Hatton, T. A., and Wang, D. I. C., "Separation and Concentration of Amino Acids Using Liquid Emulsion Membranes," Biotech. Bioeng., 32, 604-615 (1988).
27. Vijayalakshmi, C. S., and Gulari, E., "An Improved Model for the Extraction of Multivalent Metals in Winsor II Microemulsion Systems," Sep. Sci. Technol.,26, 291-299 (1990).
28. Wang, W., "Reverse Micellar Extraction of Amino Acids Using a Two-Tailed Cationic Surfactant," Ph.D. Thesis, McGill University, Montreal, 1994.
29. Wang, W., and Vera, J. H., "Statistical Thermodynamics of Disordered and Ordered Systems. A Properly Normalized Local Order Theory," Fluid Phase Equil., 85, 1-18 (1993).
30. Wang, W., and Vera, J. H., "Liquid-Liquid Equilibrium Calculations with Excess Gibbs Energy Models Based on the Renormalization of Guggenheim's Canonical Partition Function," Ibid., 104, 207-228 (1995).
31. Wang, W., Weber, M. E., and Vera, J. H., "Effect of Alcohol and Salt on Water Uptake of Reverse Micelles Formed by Dioctyldimethyl Ammonium Chloride (DODMAC) in Isooctane," J. Colloid Interface Sci., 168, 422-427 (1994).
32. Wang, W., Weber, M. E., and Vera, J. H., "Reverse-Micellar Extraction of Amino Acids Using Dioctyldimethyl Ammonium Chloride (DODMAC)," Ind. Eng. Chem. Res., 34, 599-606 (1995).
33. Wang, W., Weber, M. E., and Vera, J. H., "Effect of the Concentration of DODMAC and 1-Decanol on the Behavior of Reverse Micelles in the Extraction of Amino Acids," Biotech. Bioeng., 46, 343-350 (1995).
34. Weber, M. E., Personal Communication, 1994.
35. Woll, J. M., and Hatton, T. A., "A Simple Phenomenological Thermodynamic Model for Protein Partitioning in Reversed Micellar Systems," Bioprocess Eng., 4, 193-199 (1989).
36. 2O in Reversed Micelles," J. Am. Chem. Soc., 99, 4730-4736 (1977).
37. Wong, M., Thomas, J. K., and Grätzel, M., "Fluorescence Probing of Inverted Micelles. The State of Solubilized Water Clusters in Alkane/Diisooctyl Sulfosuccinate (Aerosol OT) Solution," Ibid., 98, 2391-2397 (1976).