Estimation of Kinetic Parameters in Transition-Metal-Catalyzed Gas-Phase Olefin Copolymerization Processes

Industrial and Engineering Chemistry Research

Volumn 36, Issue 4, 1997, Pages 1095-1102

  Choi, Kyu Yong ^a   Tang, Shihua ^a   Sirohi, Ashuraj ^a  

^a UNIVERSITY OF MARYLAND   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTORS; COMPUTATIONAL METHODS; DENSITY (SPECIFIC GRAVITY); MATHEMATICAL MODELS; MONOMERS; OLEFINS; REACTION KINETICS;

KINETIC PARAMETERS;

COPOLYMERIZATION;

EID: 0031119276     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie9603631     Document Type: Article

References (9)

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2. Böhm, L. L. Homo- and Copolymerization with a Highly Active Ziegler-Natta Catalyst. J. Appl. Polym. Sci. 1984, 29, 279-289.
3. Chen, C. M.-P. Gas Phase Copolymerization with Ziegler-Natta Catalysts. Ph.D. Thesis, University of Wisconsin, Madison, 1993.
4. Choi, K. Y.; Ray, W. H. The Dynamic Behavior of a Fluidized Bed Reactor for Solid Catalyzed Gas Phase Olefin Polymerization. Chem. Eng. Sci. 1985, 40 (12), 2261-2279.
5. Cozewith, C.; Ver Strate, G. Ethylene-Propylene Copolymers. Reactivity Ratios, Evaluation, and Significance. Macromolecules 1971, 4 (4), 482-489.
6. Hutchinson, R. A.; Ray, W. H. Polymerization of Olefins through Heterogeneous Catalysis. VIII. Monomer Sorption Effects. J. Appl. Polym. Sci. 1990, 41, 51-81.
7. Hutchinson, R. A.; Chen, C. M.; Ray, W. H. Polymerization of Olefins through Heterogeneous Catalysis. X:Modeling of Particle Growth and Morphology. J. Appl. Polym. Sci. 1992, 44, 1389-1414.
8. McAuley, K. N.; MacGregor, J. F.; Hamielec, A. E. A Kinetic Model for Industrial Gas-Phase Ethylene Copolymerization. AIChEJ. 1990, 36 (6), 837-850.
9. Sirohi, A.; Choi, K. Y. On-Line Parameter Estimation in a Continuous Polymerization Process. Ind. Eng. Chem. Res. 1996, 35 (4), 1332-1343.