Application of the Elovich Equation to the Kinetics of Metal Sorption with Solvent-Impregnated Resins

Industrial and Engineering Chemistry Research

Volumn 36, Issue 3, 1997, Pages 813-820

  Juang, Ruey Shin ^a   Chen, Muh Lian ^a  

^a YUAN ZE UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; COBALT; COPPER; IMPREGNATION; IONS; IRON; NICKEL; ORGANIC ACIDS; PH; REACTION KINETICS; TEMPERATURE; ZINC;

ELOVICH EQUATION; METAL SORPTION; SOLVENT IMPREGNATED RESIN;

SORPTION;

METALS; RESINS; SORPTION; STIRRED TANKS;

EID: 0031105118     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie960351f     Document Type: Article

References (39)

1. Aharoni, C.; Tompkins, F. C. Kinetics of Adsorption and Desorption and the Elovich Equation. In Advances in Catalysis and Related Subjects; Eley, D. D., Pines, P., Weisz, P. B., Eds.; Academic Press: New York, 1970; Vol. 21, pp 1-49.
2. 4. J. Phys. Chem. 1984, 88, 5334-5342.
3. Akita, S.; Takeuchi, H. Sorption and Separation of Divalent Metals by a Macromolecular Resin Containing Organophosphorus Acids. J. Chem. Eng. Data 1992, 37, 303-306.
4. Akita, S.; Takeuchi, H. Column Sorption and Separation of Divalent Metals by a Macromolecular Resin Containing Organophosphorus Acids. J. Chem. Eng. Jpn. 1993, 26, 442-444.
5. Akita, S.; Maeda, T.; Takeuchi, H. Metal Sorption Characteristics of a Macromolecular Resin Containing D2EHPA. J. Chem. Eng. Jpn. 1994, 27, 126-129.
6. Boyd, G. E.; Soldano, B. A. Self-Diffusion of Cations in and through Sulfonated Polystyrene Cation-Exchange Polymers. J. Am. Chem. Soc. 1953, 75, 6091-6099.
7. Chien, S. H.; Clayton, W. R. Application of Elovich Equation to the Kinetics of Phosphate Release and Sorption in Soils. Soil Sci. Soc. Am. J. 1980, 44, 265-268.
8. Cortina, J. L.; Miralles, N.; Sastre, A.; Aguilar, M.; Profumo, A.; Pesavento, M. Solvent Impregnated Resin Containing Cyanex 272. Preparation and Application to the Extraction and Separation of Divalent Metals. React. Polym. 1992, 18, 67-75.
9. Cortina, J. L.; Miralles, N.; Sastre, A.; Aguilar, M.; Profumo, A.; Pesavento, M. Solvent Impregnated Resins Containing Di(2,4,4,-trimethylpentyl)phosphinic Acid. I. Comparative Study of Di(2,4,4-trimethylpentyl)phosphinic Acid Adsorbed into Amberlite XAD-2 and Dissolved in Toluene. React. Polym. 1993a, 21, 89-101.
10. Cortina, J. L.; Miralles, N.; Sastre, A.; Aguilar, M.; Profumo, A.; Pesavento, M. Solvent Impregnated Resins Containing Di(2,4,4-trimethylpentyl)phosphinic Acid. II. Study of the Distribution Equilibria of Zn, Cu and Cd. React. Polym. 1993b, 21, 103-116.
11. Cortina, J. L.; Miralles, N.; Aguilar, M.; Sastre, A. M. Solvent Impregnated Resins Containing Di(2-ethylhexyl)phosphoric Acid. II. Study of the Distribution Equilibria of Zn, Cu and Cd. Solvent Extr. Ion Exch. 1994a, 12, 371-391.
12. Cortina, J. L.; Miralles, N.; Aguilar, M.; Sastre, A. M. Extraction Studies of Zn(II), Cu(II) and Cd(II) with Impregnated and Levextrel Resins Containing Di(2-ethylhexyl)phosphoric Acid. Hydrometallurgy 1994b, 36, 131-142.
13. Cortina, J. L.; Miralles, N.; Aguilar, M.; Sastre, A. M. Extraction Studies of Zn(II), Cu(II) and Cd(II) with Impregnated and Levextrel Resins Containing Di(2-ethylhexyl)phosphoric Acid. Hydrometallurgy 1994c, 36, 131-142.
14. Crook, E. H.; McDonnell, R. P.; McNulty, J. T. Removal and Recovery of Phenols from Industrial Waste Effluents with Amberlite XAD Polymeric Adsorbents. Ind. Eng. Chem. Prod. Res. Dev. 1975, 14, 113-118.
15. 4 System Using the Rotating Diffusion Cell Technique. Solvent Extr. Ion Exch. 1989, 7, 335-360.
16. Gonzalez-Luque, S.; Streat, M. Uranium Sorption from Phosphoric Acid Solutions Using Selective Ion Exchange Resins. Part II. Kinetic Studies. Hydrometallurgy 1983, 11, 227-245.
17. Guan, Y.; Wu, X. Y.; Hu, H. F. Kinetic Studies of Solvent Impregnated Resins for Sorption of Spiramycin. Huagong Xuebao 1991, (5), 603-610.
18. Helfferich, F. Ion Exchange; McGraw-Hill: New York, 1962; pp 250-266.
19. House, W. A.; Denison, F. H.; Armitage, P. D. Comparison of the Uptake of Inorganic Phosphorus to a Suspended and Stream Bed-Sediment. Water Res. 1995, 29, 767-779.
20. Hughes, M. A.; Purdey, C. Use of Solvent-Impregnated Polymer to Extract Copper from Certain Acid Solutions. Trans. Inst. Min. Metall., Sect. C 1976, 85, 124-132.
21. Jerabek, K.; Hankova, L.; Strikovsky, A. G.; Warshawsky, A. Solvent Impregnated Resins: Relation between Impregnation Process and Polymer Support Morphology I. Di(2-ethylhexyl)-dithiophosphoric Acid. React. Funct. Polym, 1996, 28, 201-207.
22. Juang, R. S.; Lo, R. H. Kinetics of the Coupled Transport of Vanadium(IV) from Sulfate Solutions through Supported Liquid membranes. Ind. Eng. Chem. Res. 1994, 33, 1011-1016.
23. Juang, R. S.; Lin, H. C. Metal Sorption with Extractant-Impregnated Macroporous Resins. 1. Particle Diffusion Kinetics. J. Chem. Technol. Biotechnol. 1995a, 62, 132-140.
24. Juang, R. S.; Lin, H. C. Metal Sorption with Extractant-Impregnated Macroporous Resins. 2. Chemical Reaction and Particle Diffusion Kinetics. J. Chem. Technol. Biotechnol. 1995b, 62, 141-147.
25. Juang, R. S.; Lee, S. H. Analysis of the Transport Rates of Europium(III) Across an Organophosphinic Acid Supported Liquid Membrane. J. Membr. Sci. 1996, 110, 13-23.
26. Juang, R. S.; Chen, M. L. Comparative Equilibrium Studies on the Sorption of Metal Ions with Macroporous Resins Containing a Liquid Ion-Exchanger. Sep. Sci. Technol. 1996 (accepted for publication).
27. Klusacek, K.; Hudgins, R. R.; Silveston, P. L. Multiple Steady States of an Isothermal Catalytic Reaction with Elovich Equation. Chem. Eng. Sci. 1989, 44, 2377-2381.
28. Matsuyama, H.; Miyake, Y.; Izumo, Y.; Teramoto, M. Kinetics and Mechanism of Metal Extraction with Acidic Organophosphorus Extractants (II): Extraction Mechanism of Fe(III) with Di(2-ethylhexyl)phosphoric Acid. Hydrometallurgy 1990, 24, 37-51.
29. Miyake, Y.; Matsuyama, H.; Nishida, M.; Nakai, M.; Nagase, N.; Teramoto, M. Kinetics and Mechanism of Metal Extraction with Acidic Organophosphorus Extractants (I): Extraction Rate Limited by Diffusion Process. Hydrometallurgy 1990, 23, 19-35.
30. Pavlatou, A.; Polyzopoulos, N. A. The Role of Diffusion in the Kinetics of Phosphate Desorption: The Relevance of the Elovich Equation. J. Soil Sci. 1988, 39, 425-436.
31. Smith, D. M.; Welch, W. F.; Jassim, J. A.; Chughtai, A. R.; Stedman, D. M. Soot-Ozone Reaction Kinetics: Spectroscopic and Gravimetric Studies. Appl. Spectrosc. 1988, 42, 1473-1482.
32. Strikovsky, A. G.; Jerabek, K.; Cortina, J. L.; Sastre, A. M.; Warshawsky, A. Solvent Impregnated Resins Containing Di-alkyldithiophosphoric Acid on Amberlite XAD-2: Extraction of Copper and Comparison to the Liquid-Liquid Extraction. React. Funct. Polym. 1996, 28, 149-158.
33. Swami, N.; Dreisinger, D. B. Kinetics of Zinc Removal from Cobalt Electrolytes by Ion Exchange. Solvent Extr. Ion Exch. 1995, 13, 1037-1062.
34. Tavlaride, L. L.; Bae, J. H.; Lee, C. K. Solvent Extraction, Membranes, and Ion Exchange in Hydrometallurgical Dilute Metals Separation. Sep. Sci. Technol. 1987, 22, 581-617.
35. Taylor, H. A.; Thon, N. Kinetics of Chemisorption. J. Am. Chem. Soc. 1952, 74, 4169-4173.
36. Torrent, J. Rapid and Slow Phosphate Sorption by Mediterranean Soils: Effect of Iron Oxides. Soil Sci. Soc. Am. J. 1987, 51, 78-82.
37. Warshawsky, A. Extraction with Solvent-Impregnated Resins. In Ion Exchange and Solvent Extraction; Marinsky, J. A., Marcus, Y., Eds.; Marcel Dekker: New York, 1981; Vol. 8, pp 229-310.
38. Warshawsky, A.; Patchornik, A. Recent Developments in Metal Extraction by Solvent Impregnated Resins. In The Theory and Practice of Ion Exchange; Streat, M., Ed.; SCI: London, 1976; Paper 38.
39. Warshawsky, A.; Bercovitz, H. Hydroxyoxime Solvent-Impregnated Resins for Selective Copper Separation. Trans. Inst. Min. Metall., Sect. C 1979, 88, 36-43.