Dynamic mechanical and solid-state NMR determination of molecular-scale heterogeneity in a raw elastomer, a microcrystalline polymer, and their blend

Journal of Polymer Science, Part B: Polymer Physics

Volumn 35, Issue 4, 1997, Pages 709-716

  Kwak, Seung Yeop ^a   Kim, Sang Yong ^b   Nakajima, Nobuyuki ^c  

^a Korea Institute of Science and Technology   (South Korea)

^b Seoul National University   (South Korea)

^c The University of Akron   (United States)

Author keywords

CP MAS 13C nuclear magnetic resonance relaxation; Dynamic viscoelastic behavior; Molecular scale heterogeneity; Proton spin lattice relaxation time in the rotating frame; T1

Indexed keywords

ELASTOMERS; MAGNETIC RELAXATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMER BLENDS; POLYVINYL CHLORIDES; SOLUBILITY; THERMAL EFFECTS; VISCOELASTICITY;

BUTADIENE ACRYLONITRILE; CROSS POLARIZATION; MAGIC ANGLE SPINNING; MICROCRYSTALLINE POLYMER; MOLECULAR SCALE HETEROGENEITY; RAW ELASTOMER;

ORGANIC POLYMERS;

EID: 0031103268     PISSN: 08876266     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0488(199703)35:4<709::AID-POLB17>3.0.CO;2-K     Document Type: Article

References (28)

1. P. J. Flory, Principles of Polymer Chemistry, Cornell University Press, New York, 1953.
2. W. Hoffmann, Rubber Chem. Technol., Rubber Rev., 37, 61 (1963).
3. D. Mackey and A. H. Jorgensen, in Kirk-Othmer, Encyclopedia of Chemical Technology, 4th ed., John Wiley & Sons, New York, 1991, Vol. 8, p. 1005.
4. P. H. Geil, J. Macromol. Sci.-Phys., B14, 171 (1977).
5. J. A. Davidson and K. L. Gardner, in Kirk-Othmer, Encyclopedia of Chemical Technology, 3rd ed., John Wiley & Sons, New York, 1991, Vol. 23, p. 886.
6. E. A. Collins, J. Macromol. Sci.-Phys., B14, 185 (1977).
7. G. A. Zakrzewski, Polymer, 14, 347 (1973).
8. H. F. Schwarz and J. W. F. Bley, in Advances in Polymer Blends and Alloys Technology, M. A. Kohudic and K. Finlayson, eds., Technomic Publishing, Lancaster, 1989, Vol. 2.
9. J. W. Horvath, W. A. Wilson, H. S. Lundstrom, and J. R. Purdon, Appl. Polym. Symp., 7, 95 (1968).
10. Y. J. Shur and B. Ranby, J. Appl. Polym. Sci., 19, 2143 (1975).
11. B. Ranby, J. Polym. Sci.: Symp., 51, 89 (1975).
12. C. B. Wang and S. L. Cooper, J. Polym. Sci.: Part B: Polym. Phys., 21, 11 (1983).
13. M. Matsuo, C. Nozaki, and Y. Jyo, Polym. Eng. Sci., 9, 197 (1969).
14. K. Fukumori, N. Sato, and T. Kurauchi, Rubber Chem. Technol., 64, 522 (1991).
15. D. S. Kaplan, J. Appl. Polym. Sci., 20, 2615 (1980).
16. D. C. Douglass and G. P. Jones, J. Chem. Phys., 45, 956 (1966).
17. J. Schaefer, E. O. Stejskal, M. D. Sefeik, and R. A. McKay, Phil. Trans. Soc. Lond. A, 299, 593 (1981).
18. L. A. Chandler and E. A. Collins, Rubber Chem. Technol., 43, 1465 (1970).
19. C. A. Daniels and E. A. Collins, J. Macromol. Sci.-Phys., B10, 287 (1974).
20. E. R. Harrell and N. Nakajima, J. Appl. Polym. Sci., 29, 995 (1984).
21. N. Nakajima and E. R. Harrell, in Current Topics in Polymer Science, R. M. Ottenbrite, L. A. Utracki, and S. Inoue, eds., Hanser, New York, 1987, Vol. II, p. 149.
22. D. E. Witenhafer, J. Macromol. Sci.-Phys., B4, 915 (1970).
23. V. J. McBrierty, Polymer, 15, 503 (1974).
24. D. W. McCall, D. C. Douglass, and D. R. Falcone, J. Phys. Chem., 71, 998 (1967).
25. C. A. Fyee, Solid State NMR for Chemists, C.F.C. Press, Ontario, 1983.
26. T. M. Connor, NMR Basic Principles and Progress, Springer-Verlag, Berlin, 1971, Vol. 4.
27. V. J. McBrierty and D. C. Douglass, Phys. Rep., 63, 61 (1980).
28. V. J. McBrierty and D. C. Douglass, J. Polym. Sci., Macromol. Rev., 16, 295 (1981).