Anisotropic dissolution at the CaCO3(101̄4)-water interface

Surface Science

Volumn 373, Issue 2-3, 1997, Pages 275-287

  Liang, Y ^a   Baer, D R ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

Atomic force microscopy; Calcium carbonate; Dissolution; Interface; Kinetics; Surface

Indexed keywords

ACTIVATION ENERGY; ANISOTROPY; ATOMIC FORCE MICROSCOPY; CALCITE; INTERFACES (MATERIALS); MORPHOLOGY; REACTION KINETICS; THERMAL EFFECTS; VELOCITY; WATER;

CALCIUM CARBONATE; KINK SITES; TERRACE LEDGE KINK MODEL;

DISSOLUTION;

EID: 0031103093     PISSN: 00396028     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0039-6028(96)01155-7     Document Type: Article

References (35)

1. W.K. Burton, N. Cabrera and C.F. Frank, Philos. Trans. R. Soc. A 243 (1951) 299.
2. J.P. Hirth and G.M. Pound, J. Chem. Phys. 26 (1957) 1216.
3. J.D. Weeks and G.H. Gilmer, Advances in Chemical Physics, Vol. 40, Eds. I. Prigogine and S.A. Rice (Wiley, New York, 1979) p. 157.
4. A.E. Blum and A.C. Lasaga, in: Aquatic Surface Chemistry, Ed. W. Stumm (Wiley, New York, 1987) p. 255.
5. R. Kunkel, B. Poelsema, L.K. Verheij and G. Comsa, Phys. Rev. Lett. 65 (1990) 733.
6. J.H. Neave, P.J. Dobson, B.A. Joyce and J. Zhang, Appl. Phys. Lett. 47 (1985) 100.
7. E. Vlieg, A.W. Denier van der Gon, J.F. van der Veen, J.E. Macdonald and C. Norris, Phys. Rev. Lett. 61 (1988) 2241.
8. A.J. Gratz, S. Manne and P.K. Hansma, Science 251 (1991) 1343.
9. S.R. Higgins and R.J. Hamers, Surf. Sci. 324 (1995) 263.
10. Y. Liang, D.R. Baer and A.S. Lea, Mater. Res. Soc. Symp. 355 (1995) 409.
11. Y. Liang, D.R. Baer, J.M. McCoy and J.P. LaFemina, J. Vac. Sci. Technol. A 14 (1996) 1368.
12. Y.-W. Mo, B.S. Swartzentruber, R. Kariotis, M.B. Webb and M.G. Lagally, Phys. Rev. Lett. 63 (1989) 2393.
13. P.M. Dove and M.F. Hochella, Jr., Geochim. Cosmochim. Acta 57 (1993) 705.
14. W.B. White, D.C. Culver, J.S. Herman, T.C. Kane and J.E. Mylroie, Am. Sci. 83 (1995) 450.
15. For a review, see, for example, J.W. Morse, in: Carbonates: Mineralogy and Chemistry, Vol. 11, Ed. R.J. Reeder, Reviews in Mineralogy (Washington, DC, 1983) p. 227.
16. P.E. Hilner, A.J. Gratz, S. Manne and P.K. Hansma, Geology 20 (1992) 359.
17. P.E. Hilner, S. Manne, A.J. Gratz and P.K. Hansma, Ultramicroscopy 42-44 (1992) 1387.
18. I.N. MacInnis and S.L. Brantley, Geochim. Cosmochim. Acta 56 (1992) 1113.
19. J. Schott, S. Brantley, D. Crerar, C. Guy, M. Borcsik and C. Willaime, Geochim. Cosmochim. Acta 53 (1989) 373.
20. E.L. Sjoberg and D.T. Rickard, Geochim. Cosmochim. Acta 48 (1984) 485.
21. S.L. Stipp, C.M. Eggleston and B.S. Nielsen, Geochim. Cosmochim. Acta 58 (1994) 3023.
22. J.M. McCoy and J.P. LaFemina, Surf. Sci. 373 (1997) 288.
23. L. Chou, R.M. Garrels and R. Wollast, Chem. Geol. 78 (1989) 269.
24. Y. Liang, A.S. Lea, D.R. Baer and M.H. Engelhard, Surf. Sci. 351 (1996) 172.
25. W.A. Tiller, The Science of Crystallization: Macroscopic Phenomena and Defect Generation (Cambridge University Press, Cambridge, 1991) p. 25.
26. It is useful to note that these "deep" pits are often 20-100 atomic layers deep, but with slopes of sides of only 1-3°. Thus, they are deep compared to single-layer pits, but shallow or gradual on a general scale.
27. When pits become very deep, the diffusion field near the bottom of the pits is likely to be different from that near the surface. As a result, although the overall dissolution is in the surface-reaction controlled regime, near the bottom of the deep pits, dissolution is likely to be affected by diffusion. Consequently, the ratio of the terrace widths near the bottom of the deep pits would differ from that at the surface.
28. J.P. Hirth and J. Lothe, Theory of Dislocations (McGraw-Hill, New York, 1982) p. 182.
29. J.P. Hirth and J. Lothe, Theory of Dislocations (McGraw-Hill, New York, 1982) p. 496.
30. G.G. Hammes, Principles of Chemical Kinetics (Academic, New York, 1978) p. 51.
31. G.H. Gilmer and P. Bennema, J. Appl. Phys. 43 (1972) 1347.
32. B.S. Swartzentruber, Y.-W. Mo, R. Kariotis, M.G. Lagally and M.B. Webb, Phys. Rev. Lett. 65 (1990) 1913.
33. R.G. Compton and P.J. Daly, J. Colloid Interface Sci. 115 (1987) 493.
34. Y. Liang and D.R. Baer, unpublished.
35. A.J. Gratz, P.E. Hillner and P.K. Hansma, Geochim. Cosmochim. Acta 57 (1993) 491.