Two-dimensional photoelectron spectroscopy of acetylene: Rydberg-valence interaction between the (3σg)-1(3pσu)1and (3σg)-1(3σu)1 states

Journal of Chemical Physics

Volumn 106, Issue 12, 1997, Pages 4902-4911

  Hattori, Hideo ^a   Hikosaka, Yasumasa ^b   Hikida, Takumi ^b   Mitsuke, Koichiro ^a  

^a INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE; CHEMICAL BONDS; ELECTRON ENERGY ANALYZERS; ELECTRON ENERGY LEVELS; IONIZATION; IONS; LEAST SQUARES APPROXIMATIONS; MOLECULAR VIBRATIONS;

CONSTANT IONIC STATE SPECTRA; FRANCK-CONDON GAP; PHOTON ENERGY; POTENTIAL ENERGY; RYDBERG VALENCE INTERACTION;

PHOTOELECTRON SPECTROSCOPY;

EID: 0031102323     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.473991     Document Type: Article

References (19)

1. P. H. Metzger and G. R. Cook, J. Chem. Phys. 41, 642 (1964).
2. R. Botter, V. H. Dibeler, J. A. Walker, and H. M. Rosenstock, J. Chem. Phys. 44, 1271 (1966).
3. T. Hayaishi, S. Iwata, M. Sasanuma, E. Ishiguro, Y. Morioka, Y. Iida, and M. Nakamura, J. Phys. B 15, 79 (1982).
4. M. Ukai, K. Kameta, R. Chiba, K. Nagano, N. Kouchi, K. Shinsaka, Y. Hatano, H. Umemoto, Y. Ito, and K. Tanaka, J. Chem. Phys. 95, 4142 (1991).
5. K. Mitsuke and H. Hattori, J. Chem. Phys. 102, 5288 (1995).
6. H. Hattori and K. Mitsuke, J. Electron Spectrosc. Relat. Phenom. 80, 1 (1996).
7. P. W. Langhoff, B. V. McKoy, R. Unwin, and A. M. Bradshaw, Chem. Phys. Lett. 83 270 (1981).
8. L. E. Machado, E. P. Leal, G. Csanak, B. V. McKoy, and P. W. Langhoff, J. Electron Spectrosc. Relat. Phenom. 25, 1 (1982).
9. D. M. P. Holland, A. C. Parr, D. L. Ederer, J. L. Dehmer, and J. B. West, Nucl. Instrum. Methods Phys. Res. 195, 331 (1982).
10. G. V. Marr and J. B. West, At. Data Nucl. Data Tables 18, 497 (1976).
11. Ch. Cha, R. Weinkauf, and U. Boesl, J. Chem. Phys. 103, 5224 (1995).
12. J. E. Reutt, L. S. Wang, J. E. Pollard, D. J. Trevor, Y. T. Lee, and D. A. Shirley, J. Chem. Phys. 84, 3022 (1986).
13. W. P. Kraemer, V. Spirko, and B. O. Roos, J. Mol. Spectrosc. 141, 43 (1990).
14. L. Avaldi, G. Dawber, R. I. Hall, G. C. King, A. G. McConkey, M. A. MacDonald, and G. Stefani, J. Electron Spectrosc. Relat. Phenom. 71, 93 (1995).
15. + = 1 level.
16. G. Chambaud, R. Van den Boom, and P. Rosmus, Chem. Phys. Lett. 247, 79 (1995).
17. R. S. Freund, in Rydberg States of Atoms and Molecules, edited by R. F. Stebbings and F. B. Dunning (Cambridge University Press, Cambridge, 1983), Chap. 10.
18. S. T. Pratt, P. M. Dehmer, and J. L. Dehmer, J. Chem. Phys. 99, 6233 (1993).
19. 2, an isoelectronic molecule with acetylene. See, for example, D. Stahel, M. Leoni, and K. Dressler, J. Chem. Phys. 79, 2541 (1983).