Estolide production with modified clay catalysts and process conditions

JAOCS, Journal of the American Oil Chemists' Society

Volumn 74, Issue 3, 1997, Pages 249-254

  Erhan, Selim M ^a   Isbell, Terry A ^a  

^a NATIONAL CENTER FOR AGRICULTURAL UTILIZATION RESEARCH   (United States)

Author keywords

Cation exchanged clays; Estolide; Meadowfoam oil fatty acids; Montmorillonite clays; Nitrogen sparging; Oleic acid; Oleic homopolymer; Surface active agents

Indexed keywords

ADSORPTION; AMMONIUM COMPOUNDS; CATALYST ACTIVITY; CHEMICAL MODIFICATION; CLAY; ION EXCHANGERS; IRON; NITROGEN; OLIGOMERS; REACTION KINETICS; SURFACE ACTIVE AGENTS;

CETYLTRIMETHYLAMMONIUM CHLORIDE; ESTOLIDE; MEADOWFOAM OIL FATTY ACIDS; MONTMORILLONITE CLAY; NITROGEN SPARGING; OLEIC ACID;

FATTY ACIDS;

EID: 0031100703     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-997-0131-z     Document Type: Article

References (21)

1. Plattner, R.D., K. Payne-Wahl, L. Tjarks, and R. Kleiman, Hydroxy Acids and Estolide Triglycerides of Heliophilia amplexicaulis L.f. Seed Oil, Lipids 14:516-519 (1979).
2. Modak, S.N., and J.G. Kane, Kinetics of Estolide Formation and Decomposition, J. Am. Chem. Soc. 42:428-432 (1965).
3. Neissner, V.R., and E.W. Schluter, DC-Trennung von Ricinusolfettsaure-estoliden, Fette Seifen Anstrichm. 82:183-186 (1980).
4. Raynor, M.W., K.D. Bartle, and A.A. Clifford, Analysis of Aliphatic and Phenolic Carboxylic Acids by Capillary Supercritical Fluid Chromatography-Fourier Transform Infrared Microspectrometry, J. Chromatogr. 505:179-190 (1990).
5. Delafield, F.P., M. Doudoroff, N.J. Palleroni, C.J. Lusty, and R. Contopoulos, Decomposition of Poly-hydroxybutyrate by Pseudomonads, J. Bacteriol. 90:1455-1466 (1965).
6. Burg, D. A., R. Kleiman, and S.M. Erhan, Production of Fatty Acids and Estolide Intermediates, U.S. Patent 5 380 984 (1995).
7. Erhan, S.M., R. Kleiman, and T.A. Isbell, Estolides from Meadowfoam Oil Fatty Acids and Other Monounsaturated Fatty Acids, J. Am. Oil Chem. Soc. 70:461-465 (1993).
8. Isbell, T.A., and R. Kleiman, Characterization of Estolides Produced from Acid Catalyzed Condensation of Oleic Acid, Ibid. 71:379-383 (1994).
9. Erhan, S.M., and R. Kleiman, Biodegradation of Monounsaturated Fatty Acid Estolides, INFORM 6:524 (1995).
10. Erhan, S.M., R. Kleiman, and T.A. Isbell, Methods for Increasing Estolide Yields in a Batch Reactor, J. Am. Oil Chem. Soc. 72:671-674 (1995).
11. Adams, J.M., J.A. Ballantine, S.H. Graham, R.J. Laub, J.H. Purnell, P.I. Reid, Y.M. Shaman, and J.M. Thomas, Organic Syntheses Using Sheet Silicata Intercalates: Low-Temperature Conversion of Olefins to Secondary Ethers, Angew. Chem. Int. Ed. Engl. 17:282-283 (1978).
12. Adams, J.M., J.A. Ballantine, S.H. Graham, R.T. Laub, H.J. Purnell, P.I. Reid, Y.M. Shaman, and J.M. Thomas, Selective Chemical Conversions Using Sheet Silicata Intercalates: Low-Temperature Addition of Water to 1-Alkenes, J. Catal. 58:238-252 (1979).
13. Ballantine, A.J., M. Davies, H.J. Purnel, M. Rayanakorn, J.M. Thomas, and K.J. Williams, Chemical Conversions Using Sheet Silicates: Facile Ester Synthesis by Direct Addition of Acids to Alkenes, J. Chem. Soc. Chem. Comm. 9:8-9 (1981).
14. Ballantine, A.J., M. Davies, H.J. Purnell, M. Rayanakorn, J.M. Thomas, and K.J. Williams, Chemical Conversions Using Sheet Silicates: Novel Intermolecular Dehydrations of Alcohols to Ethers and Polymers, Ibid. 9:427-428 (1981).
15. Ballantine, A.J., M. Davies, H.J. Purnell, M. Rayanakorn, J.M. Thomas, and K.J. Williams, Organic Reactions Catalyzed by Sheet Silicates: Ether Formation by the Intermolecular Dehydration of Alcohols and by Addition of Alcohols to Alkenes, J. Mol. Catal. 26:37-56 (1984).
16. Schwuger, M.J., and H. Heitmann, Kinetics of Competitive Surfactant/Pollutant Adsorption on Clay Minerals, INFORM 3:503 (1992).
17. Klump, E., H. Heitmann, H. Lewandowski, and M.J. Schwuger, Enhancing Effects During the Interaction of Cationic Surfactants and Organic Pollutants with Clay Minerals, Prog. Colloid Polym. Sci. 89:181-185 (1992).
18. Robinson, J.L., M. Tsimidou, and R. Macrae, Evaluation of the Mass Detector for Quantitative Detection of Triglycerides and Fatty Acid Methyl Esters, J. Chromatogr. 324:35-51 (1985).
19. Stolyhwo, A., H. Colin, M. Martin, and G. Guiochon, Studies of Qualitative and Quantitative Properties of the Light-Scattering Detector, Ibid. 288:253-275 (1984).
20. Taylor, D.R., and D.B. Jenkins, Acid Activated Clays, Trans. Soc. Min. Eng. AIME 282:1901-1910 (1988).
21. Pinnavaia, T.J., Intercalated Clay Catalysts, Science 220:365-371 (1983).