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Volumn 101, Issue 13, 1997, Pages 2267-2276

Inner-shell excitation spectroscopy of polymer and monomer isomers of dimethyl phthalate

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; ELECTRON ENERGY LOSS SPECTROSCOPY; ELECTRON SCATTERING; MONOMERS; SUBSTITUTION REACTIONS; TRANSMISSION ELECTRON MICROSCOPY; X RAY SPECTROSCOPY;

EID: 0031098338     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp963419d     Document Type: Article
Times cited : (58)

References (38)
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    • Ade, H.1    Zhang, X.2    Cameron, S.3    Costello, C.4    Williams, S.5
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    • Ade, H.; Zhang, X.; Cameron, S.; Costello, C.; Williams, S. Science 1992, 258, 972. Ade, H.; Smith, A.; Cameron, S.; Cielinski, R.; Mitchell, G. E.; Hsiao, B.; Rightor, E. G. Polymer 1995, 36, 1843. Leapman, R. D. In Transmission Electron Energy Loss Spectroscopy in Materials Science; Disko, M. M., Ahn, C. C., Fultz, B., Eds.; Materials Research Society: Pittsburgh, PA, 1992; p 47.
    • (1995) Polymer , vol.36 , pp. 1843
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  • 7
    • 0003020971 scopus 로고
    • Disko, M. M., Ahn, C. C., Fultz, B., Eds.; Materials Research Society: Pittsburgh, PA
    • Ade, H.; Zhang, X.; Cameron, S.; Costello, C.; Williams, S. Science 1992, 258, 972. Ade, H.; Smith, A.; Cameron, S.; Cielinski, R.; Mitchell, G. E.; Hsiao, B.; Rightor, E. G. Polymer 1995, 36, 1843. Leapman, R. D. In Transmission Electron Energy Loss Spectroscopy in Materials Science; Disko, M. M., Ahn, C. C., Fultz, B., Eds.; Materials Research Society: Pittsburgh, PA, 1992; p 47.
    • (1992) Transmission Electron Energy Loss Spectroscopy in Materials Science , pp. 47
    • Leapman, R.D.1
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    • (1997) X-ray Microscopy and Spectromicroscopy
    • Smith, A.P.1    Coffey, T.2    Ade, H.3
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    • Soft X-ray Microscopy; Jacobsen, C., Trebes, J., Eds.
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    • Spartan Version 4.0
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    • Wiley: New York
    • Beamson, G.; Briggs, D. High Resolution XPS of Organic Polymers: The Scienta ESCA300 Database; Wiley: New York, 1992. The narrowest line in their XPS spectrum of PET is 0.85 eV fwhm (C 1s(C=O)), whereas the C 1s(ring) peak is 1.0 eV wide. Two Gaussian peaks in a 2:1 intensity ratio, each with 0.85 eV width, that are separated by 0.5 eV give a near symmetric peak 1.0 eV in width. From this we conclude that the C 1s(C-R) IP is ∼0.5 eV above the C 1s(C-H) IP. The present calculated IPs, which predict a C 1s(C-H)/C 1s(C-R) shift of 0.37 eV in 1,4-PET, are in agreement with this observation. A lower resolution XPS spectrum of PET, along with a discussion of the dependence of the XPS on conformation, is given in the following: Boulanger, P.; Pireaux, J. J.; Berbist, J. J.; Delhalle, J. J. Electron Spectrosc. 1993, 63, 53.
    • (1992) High Resolution XPS of Organic Polymers: The Scienta ESCA300 Database
    • Beamson, G.1    Briggs, D.2
  • 37
    • 0012639553 scopus 로고
    • Beamson, G.; Briggs, D. High Resolution XPS of Organic Polymers: The Scienta ESCA300 Database; Wiley: New York, 1992. The narrowest line in their XPS spectrum of PET is 0.85 eV fwhm (C 1s(C=O)), whereas the C 1s(ring) peak is 1.0 eV wide. Two Gaussian peaks in a 2:1 intensity ratio, each with 0.85 eV width, that are separated by 0.5 eV give a near symmetric peak 1.0 eV in width. From this we conclude that the C 1s(C-R) IP is ∼0.5 eV above the C 1s(C-H) IP. The present calculated IPs, which predict a C 1s(C-H)/C 1s(C-R) shift of 0.37 eV in 1,4-PET, are in agreement with this observation. A lower resolution XPS spectrum of PET, along with a discussion of the dependence of the XPS on conformation, is given in the following: Boulanger, P.; Pireaux, J. J.; Berbist, J. J.; Delhalle, J. J. Electron Spectrosc. 1993, 63, 53.
    • (1993) J. Electron Spectrosc. , vol.63 , pp. 53
    • Boulanger, P.1    Pireaux, J.J.2    Berbist, J.J.3    Delhalle, J.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.