Photopolymerization of Di- and tetrafunctional methacrylic monomers in a polymeric medium: Kinetics and evidence of reaction diffusion throughout the photopolymerization reaction

Macromolecules

Volumn 30, Issue 5, 1997, Pages 1285-1288

  Mateo, J L ^a   Serrano, J ^a   Bosch, P ^a  

^a INSTITUTO DE CIENCIA Y TECNOLOGÍA DE POLÍMEROS   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ACRYLIC MONOMERS; BLOCK COPOLYMERS; DIFFUSION IN LIQUIDS; ESTERS; POLYBUTADIENES; POLYSTYRENES; REACTION KINETICS;

DIFFUSION-CONTROLLED TERMINATION; KINETIC CONSTANTS; POLYMERIC MEDIUM;

PHOTOCHEMICAL REACTIONS;

EID: 0031094830     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma961028r     Document Type: Article

References (13)

1. Kloosteboer, J. G. Adv. Polym. Sci. 1988, 84, 1.
2. Baumann, H.; Timpe, H. J. Kunstoffe 1989, 79, 696.
3. Monroe, B. M. Photopolymers: Radiation Curable Imaging Systems In Radiation Curing; Pappas, S. P., Ed.; Plenum Press: New York, 1992; Chapter 10.
4. Mita, I.; Horie, K. J. Macromol, Sci., Macromol. Chem. Phys. 1987, C27, 91.
5. Schultz, G. V. Z. Phys. Chem. (Frankfurt am Main) 1956, 8, 290.
6. Ballard, M. J.; Napper, D. H.; Gilbert, R G. J. Polym. Sci. Part A: Polym. Chem. 1986, 24, 1027.
7. Garret, R. W,; Hill, D. J. T.; O'Donell, J. H.; Pomery, P. J.; Winzor, C. L. Polym. Bull. 1989, 22, 611.
8. Ameth, K. S.; Wang, C. M.; Bowman, C. N. Macromolecules 1994, 27, 650.
9. (a) Sastre, R.; Conde, M.; Mateo, J. L. J. Photochem. Photobiol. A: Chem. 1988, 44, 111
10. (b) Mateo, J. L.; Bosch, P.; Lazano, A. E. Macromolecules 1994, 27, 7794.
11. Odian, G. Principles of Polymerization; McGraw-Hill: New York, 1982.
12. Bass, J.; Dugdale, J. S.; Foiles, C. L.; Myers, A. In Numerical Data and Functional Relationships in Science and Technology; Hellwege, K. H., Madelung, O., Eds.; Springer-Verlag: New York, 1985; p 222.
13. Berger, K. C.; Meyerhoff, G. Propagation and Termination Constants in Free Radical Polymerization. In Polymer Handbook; Brandrup, J., Immergut, E. H., Eds.; John Wiley and Sons: New York, 1989.