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Volumn 36, Issue 3, 1997, Pages 592-604

Hydrogenation of 2,4-Dinitrotoluene Using a Pd/Al2O3 Catalyst in a Slurry Reactor: A Molecular Level Approach to Kinetic Modeling and Nonisothermal Effects

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; DIFFUSION; GRAIN SIZE AND SHAPE; HYDROGENATION; LEAD COMPOUNDS; MATHEMATICAL MODELS; MOLECULAR DYNAMICS; MOLECULES; NUCLEAR REACTORS; REACTION KINETICS; TEMPERATURE;

EID: 0031094486     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie960365l     Document Type: Article
Times cited : (38)

References (37)
  • 1
    • 0004193010 scopus 로고
    • Kosak, J. R., Ed.; Chemical Industries Series; Dekker: New York
    • Alcorn, W. K. Catalysis of Organic Reactions; Kosak, J. R., Ed.; Chemical Industries Series; Dekker: New York, 1984.
    • (1984) Catalysis of Organic Reactions
    • Alcorn, W.K.1
  • 3
    • 0019632496 scopus 로고
    • Homogeneous reduction of aromatic nitrocompounds by a Triphenylphosphine complex of Palladium
    • Banerjee, T. Kr.; Sen, D. Homogeneous reduction of aromatic nitrocompounds by a Triphenylphosphine complex of Palladium. J. Chem. Technol. Biotechnol. 1981, 31, 676.
    • (1981) J. Chem. Technol. Biotechnol. , vol.31 , pp. 676
    • Banerjee, T.Kr.1    Sen, D.2
  • 5
    • 51249189382 scopus 로고
    • Kinetics of the hydrogenation of rapeseed oil. Rate equations of Chemical reactions
    • Bern, L.; Hell, M.; Schoon, N. H. Kinetics of the hydrogenation of rapeseed oil. Rate equations of Chemical reactions. J. Am. Oil Chem. Soc. 1975, 52, 391.
    • (1975) J. Am. Oil Chem. Soc. , vol.52 , pp. 391
    • Bern, L.1    Hell, M.2    Schoon, N.H.3
  • 6
    • 0003013312 scopus 로고
    • Noble Metal Catalysis in Industrial Hydrogenations, Part I: Palladium solubility and hydrogen availability
    • seventh conference; Jones, W. H., Ed.; Academic Press: New York
    • Bird, A. J.; Thompson, D. T. Noble Metal Catalysis in Industrial Hydrogenations, Part I: palladium solubility and hydrogen availability. In Catalysis in Organic Synthesis; seventh conference; Jones, W. H., Ed.; Academic Press: New York, 1980; p 61.
    • (1980) Catalysis in Organic Synthesis , pp. 61
    • Bird, A.J.1    Thompson, D.T.2
  • 7
    • 84910858815 scopus 로고
    • Effectiveness factors for general reaction rate forms
    • Bischoff, K. B. Effectiveness factors for general reaction rate forms. AIChE J. 1965, 11, 351.
    • (1965) AIChE J. , vol.11 , pp. 351
    • Bischoff, K.B.1
  • 9
    • 0000903169 scopus 로고
    • Physical rate processes in industrial fermentation. Part I. The interfacial area in gas-liquid contacting with mechanical agitation
    • Calderbank, P. H. Physical rate processes in industrial fermentation. Part I. The interfacial area in gas-liquid contacting with mechanical agitation. Trans. Inst. Chem. Eng. 1958, 36, 443.
    • (1958) Trans. Inst. Chem. Eng. , vol.36 , pp. 443
    • Calderbank, P.H.1
  • 11
    • 1542710796 scopus 로고
    • Hydrogen sorption on pure metal surfaces
    • Christmann, K. R. Hydrogen sorption on pure metal surfaces. Chem. Ind. (Dekker) 1988, 3.
    • (1988) Chem. Ind. (Dekker) , pp. 3
    • Christmann, K.R.1
  • 14
    • 1542396190 scopus 로고
    • Energetics of hydrogen adsorption on porous and supported metals
    • Geus, J. Energetics of hydrogen adsorption on porous and supported metals. Chem. Ind. (Dekker) 1988, 85.
    • (1988) Chem. Ind. (Dekker) , pp. 85
    • Geus, J.1
  • 15
    • 0025434454 scopus 로고
    • Kinetics of the catalytic hydrogenation of 2,4 Dinitrotoluene (I): Experiments, reaction scheme and catalyst activity
    • Janssen, H. F.; Kruithof, A. J.; Steghuis, G. J.; Westerterp, K. R. Kinetics of the catalytic hydrogenation of 2,4 Dinitrotoluene (I): Experiments, reaction scheme and catalyst activity. Ind. Eng. Chem. Res. 1990a, 29, 754.
    • (1990) Ind. Eng. Chem. Res. , vol.29 , pp. 754
    • Janssen, H.F.1    Kruithof, A.J.2    Steghuis, G.J.3    Westerterp, K.R.4
  • 16
    • 0025483886 scopus 로고
    • Kinetics of catalytic hydrogenation of 2,4 Dinitrotoluene (II): Modelling of reaction rates and catalyst activity
    • Janssen, H. F.; Kruithof, A. J.; Steghuis, G. J.; Westerterp, K. R. Kinetics of catalytic hydrogenation of 2,4 Dinitrotoluene (II): Modelling of reaction rates and catalyst activity. Ind. Eng. Chem. Res. 1990b, 29, 1822.
    • (1990) Ind. Eng. Chem. Res. , vol.29 , pp. 1822
    • Janssen, H.F.1    Kruithof, A.J.2    Steghuis, G.J.3    Westerterp, K.R.4
  • 19
    • 0030147757 scopus 로고    scopus 로고
    • Chemical Reaction Engineering: A multiscale approach to a multiobjective task
    • Lerou, J. J.; Ng, K. M. Chemical Reaction Engineering: a multiscale approach to a multiobjective task. Chem. Eng. Sci. 1996, 51, 1595.
    • (1996) Chem. Eng. Sci. , vol.51 , pp. 1595
    • Lerou, J.J.1    Ng, K.M.2
  • 21
    • 0015145370 scopus 로고
    • Tests for transport limitations in experimental catalytic reactors
    • Mears, D. E. Tests for transport limitations in experimental catalytic reactors. Ind. Eng. Chem. Process. Des. Dev. 1971, 10, 541.
    • (1971) Ind. Eng. Chem. Process. Des. Dev. , vol.10 , pp. 541
    • Mears, D.E.1
  • 22
    • 0026865554 scopus 로고
    • Kinetics of hydrogenation of 2,4-Dinitrotolune using 5% Pd on alumina catalyst
    • Molga, E. J.; Westerterp, K. R. Kinetics of hydrogenation of 2,4-Dinitrotolune using 5% Pd on alumina catalyst. Chem. Eng. Sci. 1992, 47, 1733.
    • (1992) Chem. Eng. Sci. , vol.47 , pp. 1733
    • Molga, E.J.1    Westerterp, K.R.2
  • 23
    • 0001432073 scopus 로고
    • Hornning, E. C., Ed.; John Wiley: London, Collect.
    • Mozingo, R. In Organic Syntheses, Hornning, E. C., Ed.; John Wiley: London, 1956; Collect. Vol. III, p 685.
    • (1956) Organic Syntheses , vol.3 , pp. 685
    • Mozingo, R.1
  • 24
    • 0029341829 scopus 로고
    • Kinetic modelling of 2,4-Dinitrotoluene hydrogenation over Pd/C
    • Neri, G.; Musolino, M. G.; Milone, C.; Galvagno, S. Kinetic modelling of 2,4-Dinitrotoluene hydrogenation over Pd/C. Ind. Eng. Chem. Res. 1995, 34, 2226.
    • (1995) Ind. Eng. Chem. Res. , vol.34 , pp. 2226
    • Neri, G.1    Musolino, M.G.2    Milone, C.3    Galvagno, S.4
  • 25
    • 0020632788 scopus 로고
    • Hydrogen effects in metal catalysts
    • Paal, Z.; Menon, P. G. Hydrogen effects in metal catalysts. Catal. Rev. Sci. Eng. 1983, 25, 299.
    • (1983) Catal. Rev. Sci. Eng. , vol.25 , pp. 299
    • Paal, Z.1    Menon, P.G.2
  • 26
    • 0018530892 scopus 로고
    • Theoretical analysis of reaction of two gases in a catalytic slurry reactor
    • Ramachandran, P. A.; Chaudhari, R. V. Theoretical analysis of reaction of two gases in a catalytic slurry reactor. Ind. Eng. Chem. Procd. Res. Dev. 1979, 18, 703.
    • (1979) Ind. Eng. Chem. Procd. Res. Dev. , vol.18 , pp. 703
    • Ramachandran, P.A.1    Chaudhari, R.V.2
  • 27
    • 84985736852 scopus 로고
    • Overall effectiveness factor of a slurry reactor for non-linear kinetics
    • Ramachandran, P. A.; Chaudhari, R. V. Overall effectiveness factor of a slurry reactor for non-linear kinetics. Can. J. Chem. Eng. 1980, 58, 412.
    • (1980) Can. J. Chem. Eng. , vol.58 , pp. 412
    • Ramachandran, P.A.1    Chaudhari, R.V.2
  • 29
    • 0028460371 scopus 로고
    • Hydrogenation of m-nitrochlorobenzene to m-chloroaniline: Reaction kinetics and modelling of a non-isothermal slurry reactor
    • Rode, C. V.; Chaudhari, R. V. Hydrogenation of m-nitrochlorobenzene to m-chloroaniline: Reaction kinetics and modelling of a non-isothermal slurry reactor. Ind. Eng. Chem. Res. 1994, 33, 1645.
    • (1994) Ind. Eng. Chem. Res. , vol.33 , pp. 1645
    • Rode, C.V.1    Chaudhari, R.V.2
  • 30
    • 85007994925 scopus 로고
    • Mass transfer coefficients for suspended particles in agitated vessels and bubble columns
    • Sano, Y.; Yamaguchi, N.; Adachi, T. Mass transfer coefficients for suspended particles in agitated vessels and bubble columns. J. Chem. Eng. Jpn. 1974, 7, 255.
    • (1974) J. Chem. Eng. Jpn. , vol.7 , pp. 255
    • Sano, Y.1    Yamaguchi, N.2    Adachi, T.3
  • 34
    • 0030144492 scopus 로고    scopus 로고
    • Kinetic modeling of industrial catalytic processes based upon fundamental elementary kinetics under ultra high vacuum
    • Waugh, K. C. Kinetic modeling of industrial catalytic processes based upon fundamental elementary kinetics under ultra high vacuum. Chem. Eng. Sci. 1996, 57, 1533.
    • (1996) Chem. Eng. Sci. , vol.57 , pp. 1533
    • Waugh, K.C.1
  • 36
    • 84984085862 scopus 로고
    • Correlations of diffusion co-efficients in dilute solutions
    • Wilke, C. R.; Chang, P. Correlations of diffusion co-efficients in dilute solutions. AIChE J. 1955, 1, 264.
    • (1955) AIChE J. , vol.1 , pp. 264
    • Wilke, C.R.1    Chang, P.2


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