A photoemission study of the coadsorption of CO2 and Na on TiO2(110)-(1 × 1) and -(1 × 2) surfaces: Adsorption geometry and reactivity

Surface Science

Volumn 371, Issue 2-3, 1997, Pages 321-336

  Nerlov, Jesper ^a   Christensen, Søren V ^b   Weichel, Steen ^a   Pedersen, Eddie H ^a   Møller, Preben J ^a  

^a UNIVERSITY OF COPENHAGEN   (Denmark)

^b AARHUS UNIVERSITY   (Denmark)

Author keywords

Alkali metals; Carbon dioxide; Low index single crystal surfaces; Soft X ray photoelectron spectroscopy; Titanium oxide

Indexed keywords

BAND STRUCTURE; BINDING ENERGY; CARBON DIOXIDE; GAS ADSORPTION; PHOTOEMISSION; REACTION KINETICS; SATURATION (MATERIALS COMPOSITION); SINGLE CRYSTALS; SODIUM; SYNCHROTRON RADIATION; TITANIUM DIOXIDE; X RAY PHOTOELECTRON SPECTROSCOPY;

ADSORPTION GEOMETRY; CORE LEVEL EMISSION; VALENCE BAND PHOTOEMISSION;

SURFACE PHENOMENA;

EID: 0031078799     PISSN: 00396028     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0039-6028(96)00988-0     Document Type: Article

References (30)

1. For a review as well as references, see: V.E. Henrich and P.A. Cox, The Surface Science of Metal Oxides (Cambridge University Press, Cambridge, 1994).
2. H. Onishi, T. Aruga, C. Egawa and Y. Iwasawa, Surf. Sci. 199 (1988) 54.
3. H. Onishi, T. Aruga, C. Egawa and Y. Iwasawa, J. Chem. Soc., Faraday Trans. 85 (1989) 2597.
4. K. Prabhakaran, D. Purdie, R. Casanova, C.A. Muryn and G. Thornton, Phys. Rev. B 45 (1992) 6969.
5. P.W. Murray, N.G. Condon and G. Thornton, Surf. Sei. 323 (1995) L281.
6. A.G. Thomas, P.J. Hardman, C.A. Muryn, H.S. Dhariwal, A.F. Prime, G. Thornton, E. Román and J.L. de Segovia, J. Chem. Soc., Faraday Trans. 91 (1995) 3569.
7. R. Heise and R. Courths, Surf. Sci. 331-333 (1995) 1460.
8. P.J. Møller and M.-C. Wu, Surf. Sci. 224 (1989) 265.
9. P.W. Murray, N.G. Condon and G. Thornton, Phys. Rev. B 51 (1995) 10989.
10. M. Sander and T. Engel, Surf. Sci. 302 (1994) L263.
11. H. Onishi and Y. Iwasawa, Surf. Sci. 313 (1994) L783.
12. A. Szabo and T. Engel, Surf. Sci. 329 (1995) 241.
13. J. Nerlov, Q. Ge and P.J. Møller, Surf. Sci. 348 (1996) 28.
14. M. Scrocco, Chem. Phys. Lett. 61 (1979) 453.
15. P.J. Hardman, N.S. Prakash, C.A. Muryn, G.N. Raikar, A.G. Thomas, A.F. Prime, G. Thornton and R.J. Blake, Phys. Rev. B 47 (1993) 16056.
16. M. Ramamoorthy, R.D. King-Smith and D. Vanderbilt, Phys. Rev. B 49 (1994) 7709.
17. J.N. Andersen, E. Lundgren, R. Nyholm and M. Qvarford, Surf. Sci. 289 (1993) 307.
18. Z. Zhang, S.-P. Jeng and V.E. Henrich, Phys. Rev. B 43 (1991) 12004.
19. D. Vogtenhuber, R. Podloucky, A. Neckel, S.G. Steinemann and A.J. Freeman, Phys. Rev. B 49 (1994) 2099.
20. P. Reinhardt and B.A. Hess, Phys. Rev. B 50 (1994) 12015.
21. J. Nerlov, S.V. Christensen, M. Shimomoura and P.J. Møller, in preparation.
22. CRC Handbook of Chemistry and Physics, 64th ed., (CRC Press, Boca Raton, FL).
23. P.I. Sorantin and K. Schwarz, Inorg. Chem. 31 (1992) 567.
24. S.L. Qiu, C.L. Lin, J. Chen and M. Strongin, Phys. Rev. B 41 (1990) 7467.
25. C.T. Au and W. Hirschwald, Surf. Sci. 199 (1988) 507.
26. H.-J. Freund and R.P. Messmer, Surf. Sci. 172 (1986) 1.
27. J. Onsgaard, P.J. Godowski, J. Nerlov and S.V. Christensen, in preparation.
28. J.A. Conner, M. Considine and I.H. Hillier, J. Chem. Soc. Faraday Trans. 2 (1978) 1285.
29. B. Bartos, H.-J. Freund, H. Kuhlenbeck, M. Neumann, H. Lindner and K. Müller, Surf. Sci. 179 (1987) 59.
30. J. Onsgaard, J. Storm, S.V. Christensen, J. Nerlov, P.J. Godowski, P. Morgen and D. Batchelor, Surf. Sci. 336 (1995) 101.