Polymer melts under uniaxial elongational flow: Stress-optical behavior from experiments and nonequilibrium molecular dynamics computer simulations

Macromolecules

Volumn 30, Issue 3, 1997, Pages 526-539

  Kroger M ^a   Luap, C ^b   Muller, R ^b  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^b INSTITUT CHARLES SADRON   (France)

Author keywords

[No Author keywords available]

Indexed keywords

BIREFRINGENCE; COMPUTER SIMULATION; FLOW OF FLUIDS; MATHEMATICAL MODELS; MOLECULAR DYNAMICS; STRESS RELAXATION; STRESSES; VISCOELASTICITY;

NONEQUILIBRIUM MOLECULAR DYNAMICS; POLYMER MELTS; UNIAXIAL ELONGATION FLOW;

POLYMERS;

EID: 0031077626     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma960317c     Document Type: Article

References (55)

1. Kremer, K.; Grest, G. S. J. Chem. Phys. 1990, 92, 5057.
2. Lopez Cascales, J. J.; Navarro, S.; Delatorre, J. G. Macromolecules 1992, 25, 3574.
3. Kröger, M.; Loose, W.; Hess, S. J. Rheol. 1993, 37, 1057.
4. Gao, J.; Weiner, J. H. J. Chem. Phys. 1992, 97, 8698; Macromolecules 1994, 27, 1201; 1996, 29, 6048.
5. Gao, J.; Weiner, J. H. J. Chem. Phys. 1992, 97, 8698; Macromolecules 1994, 27, 1201; 1996, 29, 6048.
6. Gao, J.; Weiner, J. H. J. Chem. Phys. 1992, 97, 8698; Macromolecules 1994, 27, 1201; 1996, 29, 6048.
7. Kröger, M. Rheologie und Struktur von Polymerschmelzen; Wissenschaft & Technik Verlag: Berlin, 1995.
8. Hounkonnou, M. N.; Pierleoni, C.; Ryckaert, J.-P. J. Chem. Phys. 1992, 97, 9335.
9. Fetsko, S. W.; Cummings, P. T. J. Rheol. 1995, 39, 285.
10. Kobe, J. M.; Wiest, J. M. J. Rheol. 1993, 37, 947.
11. Kröger, M.; Makhloufi, R. Phys. Rev. E 1996, 53, 2531.
12. Kröger, M. Rheology 1995, 5, 66.
13. Kröger, M.; Voigt, H. Macromol. Theory Simul. 1994, 3, 639.
14. Laun, H. M.; Bung, R.; Hess, S.; Loose, W.; Hess, O.; Hahn, K.; Hädicke, E., Hingmann, R.; Schmidt, F.; Lindner, P. J. Rheology 1992, 36, 743.
15. Loose, W.; Hess, S. Rheol. Acta 1989, 28, 91.
16. Kalus, J.; Hoffmann, H. J. Chem. Phys. 1987, 87, 714.
17. Muller, R.; Picot, C. Makromol. Chem.-Makromol. Symp. 1992, 56, 107. Muller, R.; Pesce, J. J.; Picot, C. Macromolecules 1993, 26, 4356.
18. Muller, R.; Picot, C. Makromol. Chem.-Makromol. Symp. 1992, 56, 107. Muller, R.; Pesce, J. J.; Picot, C. Macromolecules 1993, 26, 4356.
19. g to be independent of both temperature and elongation rate, even in the nonlinear part at high stresses.
20. Pick, M.; Lovell, R. Polymer 1979, 20, 1448.
21. Janeschitz-Kriegl, H. J. Polymer melt rheology and flow birefringence; Springer: Berlin, 1983.
22. Priss, L. S.; Vishnyakoov, I. I.; Pavlova, I. P. Int. J. Polym. Mater 1980, 8, 85.
23. Read, B. E. Polym. Eng. Sci. 1983, 23, 835
24. Osaki, K.; Okamoto, H.; Inoue, T.; Hwang, E.-J. Macromolecules 1995, 28, 3625, and refs 4 and 6 herein.
25. Gao, J; Weiner, J. H. J. Chem. Phys. 1989, 90, 6749.
26. Doi, M.; Edwards, S. F. The theory of polymer dynamics; Clarendon: Oxford, 1986.
27. Mead, D. W.; Leal, L. G. Rheol. Acta 1995, 34 339. Mead, D. W.; Yavich, D.; Leal, L. G. Rheol. Acta 1995, 34, 360.
28. Mead, D. W.; Leal, L. G. Rheol. Acta 1995, 34 339. Mead, D. W.; Yavich, D.; Leal, L. G. Rheol. Acta 1995, 34, 360.
29. Muller, R.; Froelich, D. Polymer 1985, 26, 1477.
30. Inoue, T.; Okamoto, H.; Osaki, K. Macromolecules 1991, 24, 5670. Okamoto, H.; Inoue, T.; Osaki, K. Macromolecules 1992, 25, 3413.
31. Inoue, T.; Okamoto, H.; Osaki, K. Macromolecules 1991, 24, 5670. Okamoto, H.; Inoue, T.; Osaki, K. Macromolecules 1992, 25, 3413.
32. Tassin, J. F.; Monnerie, L. Macromolecules 1988, 21, 1846.
33. Siesler, H. W.; Pfeifer, F.; Luap, C., unpublished results.
34. Hess, S. J. Non-Newt. Fluid Mech. 1987, 23, 305.
35. Feigl, K.; Öttinger, H. C. J. Rheol. 1994, 38, 847.
36. de Gennes, P. G. Scaling concepts in polymer physics; Cornell Univ. Press: Ithaca, NY, 1979.
37. Warner, H. R. Ind. Eng. Chem. Fund. 1972, 11, 379.
38. Weeks, J. D.; Chandler, D.; Andersen, H. C. J. Chem. Phys. 1971, 54, 5237.
39. Verlet, L. Phys. Rev. 1957, 159, 98.
40. Rapaport, D. C. Comput. Phys. Rep. 1988, 9, 1; Comput. Phys. Commun. 1991, 62, 198.
41. Rapaport, D. C. Comput. Phys. Rep. 1988, 9, 1; Comput. Phys. Commun. 1991, 62, 198.
42. Allen, M. P.; Tildesley, D. J. Computer simulation of liquids; Clarendon: Oxford, 1987.
43. Evans, D. J. Mol. Phys. 1979, 37, 1745. Evans, D. J.; Hoover, W. G.; Failor, B. H.; Moran, B.; Ladd, A. J. C. Phys. Rev. A 1983, 28, 1016.
44. Evans, D. J. Mol. Phys. 1979, 37, 1745. Evans, D. J.; Hoover, W. G.; Failor, B. H.; Moran, B.; Ladd, A. J. C. Phys. Rev. A 1983, 28, 1016.
45. Bird, R. B.; Hassager, O.; Armstrong, R. C.; Curtiss, C. F. Dynamics of polymeric liquids; Wiley & Sons: NY, 1987; Vols. 1 and 2.
46. Bowden, P. B. The physics of glassy polymers; Haward, R. N., Ed.; Wiley: New York, 1973.
47. Cicerone, M. T.; Blackburn, F. R.; Ediger, M. D. J. Chem. Phys. 1995, 102, 471.
48. Achibat, T.; Boukenter, A.; Duval, E.; Mermet, A.; Aboulfaraj, M.; Etienne, S.; G'Sell, C. Polymer 1995, 36, 251.
49. Voigt, H. Struktur und Dynamik in Polymerschmelzen und -gläsern. Thesis; TU Berlin, 1996.
50. Öttinger, H. C. J. Non-Newtonian Fluid Mech. 1987, 26, 207.
51. Wedgewood, L. E.; Öttinger, H. C. J. Non-Newtonian Fluid Mech. 1988, 27, 245.
52. Kim, J. J.; Jeong, S. H. J. Phys. A 1987, 20, 3631. Evans, D. J. Physica A 1983, 778, 51. Heyes, D. M. J. Chem. Soc. Faraday Trans. 2 1983, 79, 1741, and refs therein. Ryckaert, J.-P.; Bellemans, A. Phys. Rev. Lett. 1988, 60, 128.
53. Kim, J. J.; Jeong, S. H. J. Phys. A 1987, 20, 3631. Evans, D. J. Physica A 1983, 778, 51. Heyes, D. M. J. Chem. Soc. Faraday Trans. 2 1983, 79, 1741, and refs therein. Ryckaert, J.-P.; Bellemans, A. Phys. Rev. Lett. 1988, 60, 128.
54. Kim, J. J.; Jeong, S. H. J. Phys. A 1987, 20, 3631. Evans, D. J. Physica A 1983, 778, 51. Heyes, D. M. J. Chem. Soc. Faraday Trans. 2 1983, 79, 1741, and refs therein. Ryckaert, J.-P.; Bellemans, A. Phys. Rev. Lett. 1988, 60, 128.
55. Kim, J. J.; Jeong, S. H. J. Phys. A 1987, 20, 3631. Evans, D. J. Physica A 1983, 778, 51. Heyes, D. M. J. Chem. Soc. Faraday Trans. 2 1983, 79, 1741, and refs therein. Ryckaert, J.-P.; Bellemans, A. Phys. Rev. Lett. 1988, 60, 128.