Aggregation kinetics and precipitation phenomena in poly(phenylisocyanide)

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 35, Issue 3, 1997, Pages 439-446

  Huang, Jiun Tang ^a   Sun, Jingxian ^a   Euler, William B ^a   Rosen, William ^a  

^a University of Rhode Island   (United States)

Author keywords

GPC; Light scattering techniques; NMR; Poly(phenylisocyanide)

Indexed keywords

AGGLOMERATION; AMORPHOUS MATERIALS; CATALYSIS; GAS CHROMATOGRAPHY; LIGHT SCATTERING; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERS; PRECIPITATION (CHEMICAL); REACTION KINETICS; ULTRAVIOLET SPECTROSCOPY; X RAY DIFFRACTION ANALYSIS;

POLY(PHENYLISOCYANIDE);

CYANIDES;

EID: 0031076517     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0518(199702)35:3<439::AID-POLA6>3.0.CO;2-N     Document Type: Article

References (19)

1. (a) F. Millich and R. G. Sinclair, Polym. Prep. Div. Polym Chem. (ACS), 6, 786 (1965).
2. (b) Y. Yamamoto, T. Takizawa, and N. Hagihara, Nippon Kagagu Zasshi, 87, 1355 (1966).
3. (a) F. Millich, Adv. Polym. Chem., 19, 117 (1975);
4. (b) W. Drenth and R. J. M. Nolte, Acct. Chem. Res., 12, 30 (1979);
5. (c) C. Kollmar and R. Hoffmann, J. Am. Chem. Soc., 112, 8230 (1990);
6. (d) R. J. M. Nolte and W. Drenth, in New Methods of Polymer Synthesis, W. J. Mijs, Ed., Plenum Press, New York, 1992, p. 273.
7. (a) P. C. J. Kamer, R. J. M. Nolte, and W. Drenth, W.; J. Am. Chem. Soc., 110, 6818 (1988);
8. (b) M. M. Green, R. A. Gross, F. C. Schilling, K. Zero, and C. Crosby, Macromolecules, 21, 1839 (1988).
9. T. J. Deming and B. M. Novak, J. Am. Chem. Soc., 115, 9101 (1993).
10. R. B. King and M. J. Greene, J. Polym. Sci., Part A: Polym. Chem., 25, 907 (1987).
11. J. Sun, J.-T. Huang, W. B. Euler, and W. Rosen, in Proceedings of the Second International Conference on Intelligent Materials, C. A. Rogers and G. C. Wallace, Eds. Technomic Publ., Lancaster, PA, 1994, p. 1223.
12. Polyimines can have two molecular structures: carbon-carbon backbones with substitution at the N sites or carbon-nitrogen backbones with substitution at C sites. The polymers studied here are in the former category.
13. R. J. M. Nolte, R. W. Stephany, and W. Drenth, Rec. Trav. Chim. Pays-Bas, 92, 83 (1973).
14. B. Hong and M. A. Fox, Macromolecules, 27, 5311 (1994).
15. G. Skorana and I. Ugi, Angew. Chem. Int. Ed. Eng., 16, 259 (1977).
16. The structure of this low molecular weight component (MW < 600) is under intense scrutiny in our laboratory.
17. P. A. Grutsch and R. B. King, Makromol. Chem., Rapid Commun., 9, 323 (1988).
18. D. L. Gin, V. P. Conticello, and R. H. Grubbs, J. Am. Chem. Soc., 116, 10507 (1994).
19. n about twice that of the polymers discussed in this article.