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note
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This bifunctional initiator was synthesized by the reaction of 1,1-diphenylethylene and lithium naphthalenide in THF at -78 °C just prior the polymerization. The corresponding potassium salt was similarly prepared from 1,1-diphenylethylene and potassium naphthalenide.
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85033177988
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note
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1H NMR analysis. However, since the signal of trimethylsilyl protons were almost overlapped with that of α-methyl proton of the poly(1), no attempt was carried out to use this method.
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