Model systems in electrocatalysis: Electronic and structural characterization of vapor deposited platinum on the basal plane of highly oriented pyrolytic graphite

Solid State Ionics

Volumn 94, Issue 1-4, 1997, Pages 115-121

  Howells, Annette ^a   Harris, Todd ^a,b   Sashikata, Kenji ^a,c   Chottiner, Gary S ^a   Schersona, Daniel A ^a  

^a CASE WESTERN RESERVE UNIVERSITY   (United States)

^b MONTANA STATE UNIVERSITY   (United States)

^c TOHOKU UNIVERSITY   (Japan)

Author keywords

Electrocatalysis; Platinum; Pyrolytic graphite; Ultrahigh vacuum; Vapor deposition

Indexed keywords

BINDING ENERGY; CATALYSIS; DENSITY (SPECIFIC GRAVITY); GRAPHITE; IMAGE ANALYSIS; SCANNING TUNNELING MICROSCOPY; SPECTRUM ANALYSIS; VACUUM; VAPOR DEPOSITION; X RAY PHOTOELECTRON SPECTROSCOPY;

ELECTROCATALYSIS; HIGHLY ORIENTED PYROLYTIC GRAPHITE (HOPG); ULTRAHIGH VACUUM (UHV);

PLATINUM;

EID: 0031072141     PISSN: 01672738     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0167-2738(96)00609-1     Document Type: Article

References (26)

1. G.C. Bond, in: Heterogeneous Catalysis (Clarendon Press, Oxford, 1987).
2. Comprehensive Treatise of Electrochemistry, eds. J. O'M. Bockris, B.E. Conway, E. Yeager and R.E. White, Vol. 3 (Plenum Press, New York, 1981).
3. (a) For a recent monograph in the area of particle size effects on the catalytic properties of supported metals see: M. Che and C.O. Bennett in: Advances in Catalysis, eds. D.D. Eley, H. Pines and P.B. Weisz, Vol. 36 (Academic Press, San Diego, 1989), p. 55.
4. (b) For a recent monograph in the area of metal-support interactions see: G.L. Haller and D.E. Resasco in: Advances in Catalysis, eds. D.D. Eley, H. Pines and P.B. Weisz, Vol. 36 (Academic Press, San Diego, 1989) p. 173.
5. The general area of particle size effects in electrocatalysis has been reviewed by: (a) K. Kinoshita in: Modern Aspects of Electrochemistry, eds. J. O'M. Bockris, B.E. Conway and R.E. White, Vol. 14 (Plenum Press, New York, 1982).
6. (b) B.S. Mukerjee, J. Appl. Electrochem. 20 (1990) 537 and references therein.
7. V.S. Bagotsky and A.M. Skundin, Electrochim. Acta 29 (1984) 757.
8. (a) K. Kinoshita, J. Electrochem. Soc. 137 (1990) 845.
9. (b) L.J. Bregoli, Electrochim. Acta 23 (1978) 489.
10. M. Watanabe, H. Sei and P. Stonehart, J. Electroanal. Chem. 261 (1989) 375.
11. (a) V.S. Bagotsky, L.S. Kanevsky and V. Sh. Palanker, Electrochim. Acta 18 473 (1973).
12. (b) B.D. McNicol, J. Electroanal. Chem. 118 (1981) 71.
13. For photoelectrocatalytic effects induced by metal particles attached to massive semiconductor surfaces see: (a) D.E. Aspnes and A. Heller, J. Phys. Chem. 87 (1983) 4919 and references therein
14. (b) P. Allomgue, E. Souteyrand and L. Allemand, J. Electrochem. Soc. 136 (1989) 1027.
15. K. Kalyanasundaram in: Energy Resources through Photochemistry and Catalysis, ed. M. Graetzel (Academic Press, New York, 1983).
16. O.S. Chottiner, W.D. Jennings and K.I. Pandya, J. Vac. Sci. Technol. A 5 (1987) 2970.
17. (a) S. Eppell, O.S. Chottiner, D.A. Scherson and G. Pruett, Langmuir 6 (1990) 1316.
18. (b) C.W. Clark and L.L. Kesmodel, J. Vac. Sci. Technol. B 11 (1993) 131.
19. J. Moulder, W. Stickle, P. Sobol and K. Bomben, Handbook of X-ray Photo-electron Spectroscopy (Perkin-Elmer Corporation, Eden Prairie, 1992).
20. The binding energy of individual Pt atoms on the basal plane of graphite has been estimated to be on the order of 0.15 eV. K.-Y. Chan (private communication). See also: S. Liem and K.-Y. Chan Surf. Sci. 328 (1995) 119; 365 (1996) 38.
21. The binding energy of individual Pt atoms on the basal plane of graphite has been estimated to be on the order of 0.15 eV. K.-Y. Chan (private communication). See also: S. Liem and K.-Y. Chan Surf. Sci. 328 (1995) 119; 365 (1996) 38.
22. A.T. Hubbard, J.L. Stickney, S.D. Rosasco, M.P. Soriaga and D. Song, J. Electroanal. Chem. 150 (1983) 165 and references therein.
23. F.T. Wagner and P.N. Ross, Jr., J. Electroanal. Chem. 150 (1983) 141 and references therein.
24. A.S. Homa, E. Yeager and B.D. Cahan, J. Electroanal. Chem. 150 (1983) 181 and references therein.
25. K. Wang, S. Eppell, G.S. Chottiner and D.A. Scherson, Rev. Sci. Instrum. 64 (1993) 1066.
26. M.P. Soriaga, Prog. Surf. Sci. 39 (1992) 325 and references therein.