Kinetics of the Peracetic Acid Decomposition Part II: PH Effect and Alkaline Hydrolysis

Canadian Journal of Chemical Engineering

Volumn 75, Issue 1, 1997, Pages 42-47

  Yuan, Z ^a   Ni, Y ^a   Van Heiningen, A R P ^a  

^a UNIVERSITY OF NEW BRUNSWICK   (Canada)

Author keywords

Decomposition; Hydrogen peroxide; Hydrolysis; Kinetics; Peracetic acid; Transition metal ions

Indexed keywords

ACETIC ACID; HYDROGEN PEROXIDE; HYDROLYSIS; IONS; PH EFFECTS; REACTION KINETICS; SOLUTIONS; TRANSITION METALS;

ALKALINE HYDROLYSIS; PERACETIC ACID; SPONTANEOUS DECOMPOSITION;

BLEACHING;

EID: 0031071130     PISSN: 00084034     EISSN: None     Source Type: Journal    
DOI: 10.1002/cjce.5450750109     Document Type: Article

References (17)

1. Akiba, K. and O. Simamura, "Decomposition of Sodium Peroxybenzoate in Sodium Hydroxide Solution', Tetrahedron 26, 2519-2531 (1970).
2. Allison, R. W., "Peroxide Bleaching of Mechanical Pulp from Pinus Radiata", Appita 6(5), 362-370 (1983).
3. Ball, R. E., J. O. Edwards, J. L. Haggett and P. Jones, "A Kinetic and Isotropic Study of the Decomposition of Monoperoxyphthalic Acid", J. Amer. Chem. Soc. 89, 2331-2333 (1967).
4. Ball, D. L. and J. O. Edwards, "The Kinetics and Mechanism of the Decomposition of Caro's Acid, I", J. Amer. Chem. Soc. 78, 1125-1129 (1956).
5. D'Ans, J. and J. Mattner, "Acetpersäure erleidet in verdünnter Natronlauge Hydrolyse in Wasserstoffperoxyd und Acetat. Durch Nebenreaktionen geht aktiver Sauerstoff verloren; Magnesiumhydroxyd und andere Stoffe verhindern diesen Verlust. Festes Magnesiumhydroxyd beschleunigt die Hydrolyse", Angew. Chem. 63, 368-370 (1951).
6. Evans, D. F. and M. W. Upton, "Studies on Singlet Oxygen in Aqueous Solution, Part 3", J. Chem. Soc., Dalton Trans. 1151-1153 (1985).
7. Francis, R. C., X. Zhang, P. M. Froass and O. Tamer, "Alkali-and Metal-induced Decomposition of Peroxymonosulfate", Tappi J. 77(6), 133-140 (1994).
8. Goodman, J. F. and P. Robson, "Decomposition of Inorganic Peroxyacids in Aqueous Alkali", J. Chem. Soc., 2781-2875 (1963).
9. Greenspan, F. P. and D. G. Mackellar, "Analysis of Aliphatic Per Acids", Anal. Chem. 20, 1061-1063 (1948).
10. Hill, R. T., P. B. Walsh and J. A. Hollie, "Peracetic Acid, An Effective Alternative for Chlorine Compound Free Delignification of Kraft Pulp", in "Proc. 1992 Pulping conf.", Boston, MA, Nov. 1-5 (1992), pp. 1219-1230.
11. Kagan, M. J. and G. D. Lubarsky, "The Intermediate Stages of Aldehyde Oxidation", J. Phys. Chem. 39, 837-847 (1935).
12. Koubek, E., "The Kinetics and the Mechanism of the Decomposition of Aliphatic Peroxyacids in Aqueous Solutions", Ph.D thesis, Brown University, Providence, RI (1964).
13. Liebergott, N., "Di-per Process: Time for a Peracid Delignication and Bleaching", in "Proc. 81st CPPA Annual meeting", Technical section, Montreal, Canada, Jan. 27-31 (1995), pp. B157-B170.
14. McDonough, T. J. M., "Peracetic Acid Decomposition and Oxidation of Lignin Model Phenols in Alkaline Solutions", Ph.D Thesis, University of Toronto, Toronto, ON (1972).
15. Springer, E. L. and J. D. McSweeny, "Treatment of Softwood Kraft Pulps with Peroxymonosulfate Prior to Oxygen Delignification", Tappi J. 76(8), 194-199 (1993).
16. Troughton, N. A., F. Desprez and J. Devenyns, "Peracids: The Pathway to High Brightness TCF Kraft Pulps", in "Proc. 1994 International Non-chlorine Bleahcing Conf.", Pulp & Paper and Engineering Technology Transfer Inc., Amelia Island, FL, March 6-10, Paper 10-1 (1994).
17. Yuan, Z., Y. Ni, and A. R. P. van Heiningen, "Kinetics of Peracetic Acid Decomposition, Part I: Spontaneous Decomposition at Typical Pulp Brightening Conditions", Can. J. Chem. Eng. 75, 37-41 (1997).