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Volumn 119, Issue 4, 1997, Pages 744-755

Stabilities and structures of metal ion complexes of adenosine 5'-O-thiomonophosphate (AMPS 2-) in comparison with those of its parent nucleotide (AMP 2-) in aqueous solution

Author keywords

[No Author keywords available]

Indexed keywords

ADENOSINE DERIVATIVE; METAL COMPLEX;

EID: 0031048121     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja962970l     Document Type: Article
Times cited : (130)

References (119)
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    • (1996) Metal Ions in Biological Systems , vol.32 , pp. 1-814
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    • (a) Sigel, A., Sigel, H., Eds. Probing of Nucleic Acids by Metal Ion Complexes of Small Molecules; Vol. 33 of Metal Ions in Biological Systems; M. Dekker, Inc.: New York, Basel, and Hong Kong, 1996; pp 1-678.
    • (1996) Metal Ions in Biological Systems , vol.33 , pp. 1-678
    • Sigel, A.1    Sigel, H.2
  • 5
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    • Interrelations among Metal Ions, Enzymes, and Gene Expression
    • M. Dekker, Inc.: New York and Basel
    • (b) Sigel, H., Sigel, A., Eds. Interrelations among Metal Ions, Enzymes, and Gene Expression; Vol. 25 of Metal Ions in Biological Systems; M. Dekker, Inc.: New York and Basel, 1989; pp 1-557.
    • (1989) Metal Ions in Biological Systems , vol.25 , pp. 1-557
    • Sigel, H.1    Sigel, A.2
  • 14
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    • 6-ethenoadenine derivatives, see: Sigel, H. Chimia 1987, 41, 11-26.
    • (1987) Chimia , vol.41 , pp. 11-26
    • Sigel, H.1
  • 23
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    • (e) Regarding metal ion coordination of such antiviral nucleotide analogues, see: Sigel, H. Coord. Chem. Rev. 1995, 144, 287-319.
    • (1995) Coord. Chem. Rev. , vol.144 , pp. 287-319
    • Sigel, H.1
  • 61
    • 1842289510 scopus 로고    scopus 로고
    • note
    • -, tetrahydrothiophene-2-carboxylate; Tris, tris(hydroxymethyl)aminomethane = 2-amino-2-(hydroxymethyl)-1,3-propanediol. Further abbreviations are defined in the legend of Figure 2. Species which are given in the text without a charge either do not carry one or represent the species in general (i.e., independent from their protonation degree); which of the two versions applies is always clear from the context.
  • 67
  • 68
    • 0028473674 scopus 로고
    • (b) One may mention here also that chloro(diethylenetriamine)platinum(II) chloride yields with AMPS exclusively a (phosphothiorato)platinum(II) complex: Slavin, L. L.; Cox, E. H.; Bose, R. N. Bioconjugate Chem. 1994, 5, 316-320.
    • (1994) Bioconjugate Chem. , vol.5 , pp. 316-320
    • Slavin, L.L.1    Cox, E.H.2    Bose, R.N.3
  • 75
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    • Sigel, H. Chimia 1967, 21, 489-500.
    • (1967) Chimia , vol.21 , pp. 489-500
    • Sigel, H.1
  • 89
    • 1842296018 scopus 로고    scopus 로고
    • note
    • 2+ binding, and therefore, an increase in stability is expected. The result indicates that the two mentioned opposite effects evidently cancel each other.
  • 97
    • 0003998388 scopus 로고
    • CRC Press: Boca Raton, FL, Ann Arbor, MI, London, and Tokyo
    • Lide, D. R., Ed. Handbook of Chemistry and Physics. 74th ed.; CRC Press: Boca Raton, FL, Ann Arbor, MI, London, and Tokyo, 1993; pp 8-49.
    • (1993) Handbook of Chemistry and Physics. 74th Ed. , pp. 8-49
    • Lide, D.R.1
  • 98
    • 1842407521 scopus 로고    scopus 로고
    • note
    • CoS values (22.51, 21.3, 22.10, 20.4), which refer to 25°C and which are listed in ref 42a.
  • 99
    • 1842298454 scopus 로고    scopus 로고
    • note
    • MnS = 21.21 (20°C) is listed in ref 42a; it is based on refs 45c,d.
  • 104
    • 1842337153 scopus 로고    scopus 로고
    • note
    • PbS values (27.47, 28.3, 29.04, 29.15, 29.37, 28.17, 28.15, 27.10, 26.6, 27.9, 27.15) determined close to 25°C and as listed in ref 42a.
  • 105
    • 1842300769 scopus 로고    scopus 로고
    • note
    • CuS values, i.e., for cupric sulfide (37.46, 37.49, 36.10, 35.10, 35.2, 35.40), which refer to 25°C and are listed in ref 42a.
  • 115
    • 1842376580 scopus 로고    scopus 로고
    • note
    • M(AMPS)op* (Table 3, column 5; this latter stability constant quantifies only the oxygen-binding capacity of a phosphate group) results for the six metal ion systems in a poor fit regarding a straight line (correlation coefficient R = 0.85).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.