Resolving component overlap in multiwavelength kinetic spectroscopy: Application to Raman scattering from intermediates in triplet-state photoreactions

Photochemistry and Photobiology

Volumn 65, Issue 1, 1997, Pages 47-56

  Fister, Julius C ^a   Harris, Joel M ^a  

^a UNIVERSITY OF UTAH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0031045104     PISSN: 00318655     EISSN: None     Source Type: Journal    
DOI: 10.1111/j.1751-1097.1997.tb01876.x     Document Type: Conference Paper

References (46)

1. James, D. R. and W. R. Ware (1985) A fallacy in the interpretation of fluorescence decay parameters. Chem. Phys. Lett. 120, 455-459.
2. Marshall, D. B. (1989) Statistical considerations in the analysis of dispersive kinetics data as discrete or continuous distributions of rate constants. Anal. Chem. 61, 660-665.
3. Kaiser, H. (1970) Quantitation in elemental analysis. Anal. Chem. 42, 24A-41A.
4. Wilson, R. M. and T. L. Miller (1975) Computerized kinetic luminescence spectrometry: time-resolved and component-resolved phosphorescence spectrometry. Anal. Chem. 47, 256-266.
5. Knorr, F. J. and J. M. Harris (1981) Resolution of multicomponent fluorescence spectra by an emission wavelength-decay time data matrix. Anal. Chem. 53, 272-276.
6. Frans, S. D. and J. M. Harris (1984) Reiterative least squares spectral resolution of organic acid/base mixtures. Anal. Chem. 56, 466-470.
7. Sternberg, J. S., H. S. Stillo and R. H. Schwendeman (1960) Spectrophotometric analysis of multicomponent systems using the least squares method in matrix form. Anal. Chem. 32, 84-90.
8. Beechem, J. M., M. Ameloot and L. Brand (1985) Global analysis of fluorescence decay surfaces: excited state reactions. Chem. Phys. Lett. 120, 466-472.
9. Beechem, J. M., E. Gratton, M. Ameloot, J. R. Knutson and L. Brand (1991) Global analysis of fluorescence intensity and anisotropy decay data: second-generation theory and programs. In Topics in Fluorescence Spectroscopy, Vol. 2, Principles (Edited by J. R. Lakowicz), Chapter 5. Plenum, New York.
10. Lawton, W. H. and E. A. Sylvestre (1971) Self modeling curve resolution. Technometrics 13, 617-633.
11. Aartsma, T. J., M. Gouterman, C. Jochum, A. L. Kwiram, B. V. Pepich and L. D. Williams (1982) Porphyrins 43. Triplet sublevel emission of platinum tetrabenzoporphyrin by spectrothermal principal component decomposition. J. Am. Chem. Soc. 104, 6278-6283.
12. Sun Y. P., D. F. Sears and J. Saltiel (1989) Resolution of benzophenone delayed fluorescence and phosphorescence spectra. Evidence of vibrationally unrelaxed prompt benzophenone fluorescence. J. Am. Chem. Soc. 111, 706-711.
13. Saltiel, J., D. F. Sears, Y.-O. Choi, Y. P. Sun and D. W. Eaker (1994) Fluorescence, fluorescence excitation, and ultraviolet absorption spectra of trans-1-(2-naphthyl)-2-phenylethene conformers. J. Phys. Chem. 98, 35-46.
14. Saltiel, J., Y.-O. Choi, D. F. Sears, D. W. Eaker, F. B. Mallory and C. W. Mallory (1994) Effect of spectral shifts on the resolution of trans-1-(2-naphthyl)-2-phenylethene conformer UV spectra based on principal component analysis with self-modeling. J. Phys. Chem. 98, 13162-13170.
15. Fister, J. C. and J. M. Harris (1995) Multidimensional least-squares resolution of excited-state Raman spectra. Anal. Chem. 67, 701-709.
16. Fister, J. C. and J. M. Harris (1995) Multidimensional least-squares resolution of Raman spectra from intermediates in sensitized photochemical reactions. Anal. Chem. 67, 1361-1370.
17. Asher, S. A. (1993) UV resonance Raman spectroscopy for analytical, physical, and biophysical chemistry. Anal. Chem. 65, 59A-66A.
18. Poston, P. E. and J. M. Harris (1990) Excited-state calorimetry studies of triplet benzophenone using time-resolved photothermal beam deflection spectroscopy. J. Am. Chem. Soc. 112, 644-650.
19. Takatori, Y., K. Yoshizumi, S. Kazuhiko and K. Obi (1994) Dissociation of highly excited triplet benzophenone into phenyl radicals and carbon monoxide: determination of the reaction quantum yield and the heat of reaction by time-resolved thermal lensing technique. Chem. Phys. 180, 99-107.
20. Malinowski, E. R. (1977) Determination of the number of factors and the experimental error in a data matrix. Anal. Chem. 49, 612-617.
21. Fister, J. C. and J. M. Harris (1996) Factor analysis of transient Raman scattering data to resolve spectra of ground- and excited-state species. In Computer Assisted Analytical Spectroscopy (Edited by S. D. Brown), pp. 81-106. John Wiley, New York.
22. Warner, I. M., E. R. Davidson and G. D. Christian (1977) Quantitative analysis of multicomponent fluorescence data by the methods of least squares and non-negative least sum of errors. Anal. Chem. 49, 2155-2159.
23. Sandros, K. (1964) Transfer of triplet state energy in fluid solutions. Acta Chem. Scand. 18, 2355-2374.
24. Dexter, D. L. (1953) Theory of sensitized luminescence in solids. J. Chem. Phys. 21, 836-850.
25. Bensasson, R. and E. J. Land (1971) Triplet-triplet extinction coefficients via energy transfer. Trans. Faraday Soc. 67, 1904-1915.
26. Singh, A., A. R. Scott and F. Sopchyshyn (1969) Flash photolysis of champhorquinone and biacetyl. J. Phys. Chem. 73, 2633-2643.
27. Bensasson, R. V. and J. Gramain (1980) Benzophenone triplet properties in acetonitrile and water. J. Chem. Soc. Faraday Trans. I 76, 1801-1810.
28. Alcock, N. W., D. J. Benton and P. Moore (1970) Kinetics of series first-order reactions. Trans. Faraday Soc. 66, 2210-2213.
29. Cohen, S. G., A. Parola and G. H. Parsons, Jr. (1973) Photoreduction by amines. Chem. Rev. 73, 141-161.
30. Devadoss, C. and R. W. Fessenden (1991) Picosecond and nanosecond studies of the photoreduction of benzophenone by N,N-diethylaniline and triethylamine. J. Phys. Chem. 95, 7253-7260.
31. Beck, S. M. and L. E. Brus (1982) Photooxidation of water by p-benzoquinone. J. Am. Chem. Soc. 104, 1103-1104.
32. Noda, I. (1993) Generalized two-dimensional correlation method applicable to infrared, Raman, and other types of spectroscopy. Appl. Spectrosc. 47, 1329-1336.
33. Fister, J. C. and J. M. Harris (1996) Time- and wavelength-resolved delayed-fluorescence emission from acridine yellow in an inhomogeneous saccharide glass. Anal. Chem. 68, 639-646.
34. Murray, S. B. and S. B. Dierker (1986) The use of an unintensified charge-coupled device detector for low-light-level Raman spectroscopy. J. Opt. Soc. Am. A 3, 2151-2159.
35. Dierker, S. B., S. B. Murray, J. D. Legrange and N. E. Schlotter (1987) Characterization of order in Langmuir-Blodgett monolayers by unenhanced Raman spectroscopy. Chem. Phys. Lett. 137, 453-457.
36. Bilhorn, R. B., P. M. Epperson, J. V. Sweedler and M. B. Denton (1987) Charge transfer device detectors for analytical optical spectroscopy - operation and characteristics. Appl. Spectrosc. 41, 1114-1125.
37. Wiessner, A. and H. Staerk (1993) Optical design considerations and performance of a spectro-streak apparatus for time-resolved fluorescence spectroscopy. Rev. Sci. Instrum. 64, 3430-3439.
38. Ishikawa, M., M. Watanabe and T. Hayakawa (1995) Simultaneous measurement of the fluorescence spectrum and lifetime of rhodamine B in solution to the subpicomole per liter level. Anal. Chem. 67, 511-518.
39. Manning, C., R. A. Palmer and J. L. Chai (1991) Step-scan Fourier-transform infrared spectrometer. Rev. Sci. Instrum. 62, 1219-1229.
40. Weidlich, O. and F. Siebert (1993) Time-resolved step-scan FTIR investigations of the transition from KL to L in the bacteriorhodopsin photocycle: identification of chromophore twists by assigning hoop bending vibrations. Appl. Spectrosc. 47, 1394-1400.
41. Plunkett, S. E., J. L. Chai, T. J. Tague and R. A. Palmer (1995) Time-resolved step-scan FTIR spectroscopy of the photodynamics of carbonmonoxymyoglobin. Appl. Spectrosc. 49, 702-708.
42. Schoonover, J. R., G. F. Strouse, R. B. Dyer, W. D. Bates, P. Chen and T. J. Meyer (1996) Application of time-resolved step-scan Fourier transform infrared spectroscopy to excited state electronic structure in polypyridyl complexes of rhenium(I). Inorg. Chem. 35, 273-274.
43. Fee, R. S., J. A. Milsom and M. Maroncelli (1991) Inhomogeneous decay kinetics and apparent solvent relaxation at low temperatures. J. Phys. Chem. 95, 5170-5181.
44. Maeder, M. (1987) Evolving factor analysis for the resolution of overlapping chromatographic peaks. Anal. Chem. 59, 527-530.
45. Keller, H. R., D. L. Massart and J. O. DeBeer (1993) Window evolving factor analysis for assessment of peak homogeneity in liquid chromatography. Anal. Chem. 65, 471-475.
46. Bracewell, R. N. (1978) The Fourier Transform and Its Applications, 2nd ed. McGraw-Hill, New York.