Dinitrogen bridged gold clusters

Science

Volumn 275, Issue 5305, 1997, Pages 1460-1462

  Shan, Hui ^a   Yang, Yi ^a   James, Alan J ^a   Sharp, Paul R ^a  

^a UNIVERSITY OF MISSOURI   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

GOLD; METAL COMPLEX; NITROGEN;

ARTICLE; CHEMICAL BINDING; CHEMICAL STRUCTURE; COMPLEX FORMATION; MOLECULAR INTERACTION; PRIORITY JOURNAL;

EID: 0031040079     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.275.5305.1460     Document Type: Article

References (31)

1. For a recent review, see M. Hidai and Y. Mizobe, Chem. Rev. 95, 1115 (1995).
2. V. Ramamoorthy, Z. Wu, Y. Yi, P. R. Sharp, J. Am. Chem. Soc. 114, 1526 (1992).
3. A. V. Nesmeyanov et al., J. Organomet. Chem. 201, 343 (1980); Y. Yang and P. R. Sharp, Inorg. Chem. 32, 1946 (1993); A. Kolb, P. Bissinger, H. Schmidbaur, Z. Anorg. Allg. Chem. 619, 1580 (1993).
4. A. V. Nesmeyanov et al., J. Organomet. Chem. 201, 343 (1980); Y. Yang and P. R. Sharp, Inorg. Chem. 32, 1946 (1993); A. Kolb, P. Bissinger, H. Schmidbaur, Z. Anorg. Allg. Chem. 619, 1580 (1993).
5. A. V. Nesmeyanov et al., J. Organomet. Chem. 201, 343 (1980); Y. Yang and P. R. Sharp, Inorg. Chem. 32, 1946 (1993); A. Kolb, P. Bissinger, H. Schmidbaur, Z. Anorg. Allg. Chem. 619, 1580 (1993).
6. Spectroscopic and analytical information is available from the corresponding author or to Science Online subscribers at http://www.sciencemag.org/
7. 2) = 0.1260. Crystallographic details may be obtained from the corresponding author or from the Cambridge Crystallographic Data Centre, by quoting the full literature citation.
8. E. W. Schmidt, Hydrazine and its Derivatives (Wiley, New York, 1984).
9. H. Schmidbaur, Gold Bull. 23, 11 (1990).
10. P. Pyykkö and J. P. Desclaux, Acc. Chem. Res. 12, 276 (1979).
11. H. Schmidbaur, W. Graf, G. Müller, Angew. Chem. Int. Ed. Engl. 27, 417 (1988); M. Jansen, ibid. 26, 1098 (1987); D. E. Harwell, M. D. Mortimer, C. B. Knobler, F. A. L. Anet, M. F. Hawthorne, J. Am. Chem. Soc. 118, 2679 (1996).
12. H. Schmidbaur, W. Graf, G. Müller, Angew. Chem. Int. Ed. Engl. 27, 417 (1988); M. Jansen, ibid. 26, 1098 (1987); D. E. Harwell, M. D. Mortimer, C. B. Knobler, F. A. L. Anet, M. F. Hawthorne, J. Am. Chem. Soc. 118, 2679 (1996).
13. H. Schmidbaur, W. Graf, G. Müller, Angew. Chem. Int. Ed. Engl. 27, 417 (1988); M. Jansen, ibid. 26, 1098 (1987); D. E. Harwell, M. D. Mortimer, C. B. Knobler, F. A. L. Anet, M. F. Hawthorne, J. Am. Chem. Soc. 118, 2679 (1996).
14. P. G. Jones, Gold Bull. 14, 102 (1981); ibid., p. 159; ibid. 16, 114 (1983); ibid. 19, 46 (1986).
15. P. G. Jones, Gold Bull. 14, 102 (1981); ibid., p. 159; ibid. 16, 114 (1983); ibid. 19, 46 (1986).
16. P. G. Jones, Gold Bull. 14, 102 (1981); ibid., p. 159; ibid. 16, 114 (1983); ibid. 19, 46 (1986).
17. P. G. Jones, Gold Bull. 14, 102 (1981); ibid., p. 159; ibid. 16, 114 (1983); ibid. 19, 46 (1986).
18. H. Schmidbaur, S. Hofreiter, M. Paul, Nature 377, 503 (1995).
19. 2Co and 2,6-lutidinium chloride have been used for catalytic reductions of hydrazine [K. D. Demadis, S. M. Malinak, D. Coucouvanis, Inorg. Chem. 35, 4038 (1996)].
20. A. L. Chaney, Clin. Chem. 8, 130 (1962).
21. R. R. Schrock, T. E. Glassman, M. G. Vale, M. Kol, J. Am. Chem. Soc. 115, 1760 (1993).
22. G. W. Watt and J. D. Chrisp, Anal. Chem. 24, 2006 (1952).
23. Md. Matiur Rahman, H.-Y. Liu, K. Eriks, A. Prock, W. Giering, Organometallics 8, 1 (1989).
24. C. E. Briant, K. P. Hall, D. M. P. Mingos, J. Organomet. Chem. 229, C5 (1982).
25. D. C. Rees, M. K. Chan, J. Kim, Adv. Inorg. Chem. 40, 89 (1993); J. Kim and D. C. Rees, Science 257, 1677 (1992); Nature 350, 553 (1992); M. K. Chan, J. Kim, D. C. Rees, Science 260, 792 (1993).
26. D. C. Rees, M. K. Chan, J. Kim, Adv. Inorg. Chem. 40, 89 (1993); J. Kim and D. C. Rees, Science 257, 1677 (1992); Nature 350, 553 (1992); M. K. Chan, J. Kim, D. C. Rees, Science 260, 792 (1993).
27. D. C. Rees, M. K. Chan, J. Kim, Adv. Inorg. Chem. 40, 89 (1993); J. Kim and D. C. Rees, Science 257, 1677 (1992); Nature 350, 553 (1992); M. K. Chan, J. Kim, D. C. Rees, Science 260, 792 (1993).
28. D. C. Rees, M. K. Chan, J. Kim, Adv. Inorg. Chem. 40, 89 (1993); J. Kim and D. C. Rees, Science 257, 1677 (1992); Nature 350, 553 (1992); M. K. Chan, J. Kim, D. C. Rees, Science 260, 792 (1993).
29. Early calculations disfavored internal bonding [H. Deng and R. Hoffmann, Angew. Chem. Int. Ed. Engl. 32, 1062 (1993)]; however, more recent calculations are favorable [K. K. Stavrev and M. C. Zerner, Chem. Eur. J. 2, 83 (1996)].
30. Early calculations disfavored internal bonding [H. Deng and R. Hoffmann, Angew. Chem. Int. Ed. Engl. 32, 1062 (1993)]; however, more recent calculations are favorable [K. K. Stavrev and M. C. Zerner, Chem. Eur. J. 2, 83 (1996)].
31. We thank J. Bercaw for pointing out the structural analogy of 1 to the nitrogenase cluster. This work was supported by the Division of Chemical Sciences, Office of Basic Energy Sciences, Office of Energy Research, U.S. Department of Energy.