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0842341771
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Semichem Inc., 7128 Summit
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AMPAC version 5.0, Semichem Inc., 7128 Summit. The parameters of the AMI method belong to Dewar, M. J. S.; Zoebisch, E. F.; Healy, E. F.; Stewart, J. J. P. J. Am. Chem. Soc. 1985, 107, 3902-3909.
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AMPAC Version 5.0
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8
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0842341771
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AMPAC version 5.0, Semichem Inc., 7128 Summit. The parameters of the AMI method belong to Dewar, M. J. S.; Zoebisch, E. F.; Healy, E. F.; Stewart, J. J. P. J. Am. Chem. Soc. 1985, 107, 3902-3909.
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Dewar, M.J.S.1
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Stewart, J.J.P.4
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9
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0343672264
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0343672262
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11
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0343236580
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Pyridinium chloride (0.75 eq.) in refluxing ethanol was found to be a mild method of detritylation, yielding quantitatively the deprotected product. These neutral conditions may be useful for detritylation of carbohydrate derivatives having acid-sensitive protecting groups and have been successfully tested in our lab on mono- and ditrityl derivatives
-
Pyridinium chloride (0.75 eq.) in refluxing ethanol was found to be a mild method of detritylation, yielding quantitatively the deprotected product. These neutral conditions may be useful for detritylation of carbohydrate derivatives having acid-sensitive protecting groups and have been successfully tested in our lab on mono- and ditrityl derivatives.
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13
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0342367086
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note
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14: C 72.53, H 7.27. Found C 72.20, H 7.04.
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14
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0343672260
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note
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3).
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