Synthesis of 5-Alkyl-1-aryl-4,4-dimethyl-2,6,7-trioxa as a chemiluminescent substrate with remarkable thermal stability

Tetrahedron Letters

Volumn 38, Issue 16, 1997, Pages 2863-2866

  Matsumoto, Masakatsu ^a   Watanabe, Nobuko ^a   Kasuga, Noriko C ^a   Hamada, Fumiaki ^a   Tadokoro, Koji ^a  

^a KANAGAWA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

OXETANE DERIVATIVE;

ARTICLE; CHEMOLUMINESCENCE; DRUG SYNTHESIS; IN VITRO STUDY; STRUCTURE ACTIVITY RELATION; THERMOSTABILITY;

EID: 0031005928     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)00483-8     Document Type: Article

References (29)

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23. Olefins 4 were synthesized by the use of McMurry reaction of the corresponding ketoesters 6.
24. +, 7), 246 (8), 231 (14), 222 (32), 152 (38), 135 (100).
25. 7) that the "ene" reaction and 1,2-addition of singlet oxygen occur concurrently for 4,5-dimethyl-2,3-dihydrofuran, the results for 4c suggest that an aryl at the 1-position of dihydrofuran affects most likely the side selectivity of singlet oxygen.
26. 5d was decomposed gradually while the isolation process.
27. 2b)
28. --triggerable dioxetanes 8 and 9, TBAF induced luminescence occurred by a pseudo-first order process under the conditions described here, and the chemiluminescence spectra from 9 were identical to the fluorescence emission spectra of the corresponding spent reaction mixture.
29. 3.