Phosphinidine-Bridged Silver Clusters

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 3, 1997, Pages 230-233

  Fenske, Dieter ^a   Simon, Falk ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

Bridging ligands; Clusters; P ligands; Silver

Indexed keywords

EID: 0031001987     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199702301     Document Type: Article

References (31)

1. D. Fenske, J. Ohmer, J. Hachgenei, K. Merzweiler, Angew. Chem. 1988, 100, 1300-1320; Angew. Chem. Int. Ed. Engl. 1988, 27, 1277-1296; H. Krautscheid, D. Fenske, G. Baum, M. Semmelmann, ibid. 1993, 105, 1364-1367 and 1993, 32, 1303-1305; D. Fenske, J.-C. Steck, ibid. 1993, 105, 254-257 and 1993, 32, 238-242.
2. D. Fenske, J. Ohmer, J. Hachgenei, K. Merzweiler, Angew. Chem. 1988, 100, 1300-1320; Angew. Chem. Int. Ed. Engl. 1988, 27, 1277-1296; H. Krautscheid, D. Fenske, G. Baum, M. Semmelmann, ibid. 1993, 105, 1364-1367 and 1993, 32, 1303-1305; D. Fenske, J.-C. Steck, ibid. 1993, 105, 254-257 and 1993, 32, 238-242.
3. D. Fenske, J. Ohmer, J. Hachgenei, K. Merzweiler, Angew. Chem. 1988, 100, 1300-1320; Angew. Chem. Int. Ed. Engl. 1988, 27, 1277-1296; H. Krautscheid, D. Fenske, G. Baum, M. Semmelmann, ibid. 1993, 105, 1364-1367 and 1993, 32, 1303-1305; D. Fenske, J.-C. Steck, ibid. 1993, 105, 254-257 and 1993, 32, 238-242.
4. D. Fenske, J. Ohmer, J. Hachgenei, K. Merzweiler, Angew. Chem. 1988, 100, 1300-1320; Angew. Chem. Int. Ed. Engl. 1988, 27, 1277-1296; H. Krautscheid, D. Fenske, G. Baum, M. Semmelmann, ibid. 1993, 105, 1364-1367 and 1993, 32, 1303-1305; D. Fenske, J.-C. Steck, ibid. 1993, 105, 254-257 and 1993, 32, 238-242.
5. D. Fenske, J. Ohmer, J. Hachgenei, K. Merzweiler, Angew. Chem. 1988, 100, 1300-1320; Angew. Chem. Int. Ed. Engl. 1988, 27, 1277-1296; H. Krautscheid, D. Fenske, G. Baum, M. Semmelmann, ibid. 1993, 105, 1364-1367 and 1993, 32, 1303-1305; D. Fenske, J.-C. Steck, ibid. 1993, 105, 254-257 and 1993, 32, 238-242.
6. D. Fenske, J. Ohmer, J. Hachgenei, K. Merzweiler, Angew. Chem. 1988, 100, 1300-1320; Angew. Chem. Int. Ed. Engl. 1988, 27, 1277-1296; H. Krautscheid, D. Fenske, G. Baum, M. Semmelmann, ibid. 1993, 105, 1364-1367 and 1993, 32, 1303-1305; D. Fenske, J.-C. Steck, ibid. 1993, 105, 254-257 and 1993, 32, 238-242.
7. A. Eichhöfer, D. Fenske, W. Holstein, Angew. Chem. 1993, 105, 257-261; Angew. Chem. Int. Ed. Engl. 1993, 32, 242-245.
8. A. Eichhöfer, D. Fenske, W. Holstein, Angew. Chem. 1993, 105, 257-261; Angew. Chem. Int. Ed. Engl. 1993, 32, 242-245.
9. D. Fenske, W. Holstein, Angew. Chem. 1994, 106, 1311-1312; Angew. Chem. Int. Ed. Engl. 1994, 33, 1290-1292.
10. D. Fenske, W. Holstein, Angew. Chem. 1994, 106, 1311-1312; Angew. Chem. Int. Ed. Engl. 1994, 33, 1290-1292.
11. A. Eichhöfer, J. Eisenmann, D. Fenske, F. Simon, Z. Anorg. Allg. Chem. 1993, 619, 1360-1368.
12. J. Eisenmann, D. Fenske, F. Simon, Z. Anorg. Allg. Chem. 1995, 621, 1681.
13. V. G. Albano, L. Grossi, G. Longoni, M. Monari, S. Mulley, A. Sironi, J. Am. Chem. Soc. 1992, 114, 5708-5713.
14. C. E. Briant, R. G. Smith, D. M. P. Mingos, J. Chem. Soc. Chem. Commun. 1984, 586-588.
15. F. Calderazzo, G. Pampaloni, U. Englert, J. Strähle, J. Organomet. Chem. 1990, 383, 45-57.
16. B. K. Teo, K. Keating, J. Am. Chem. Soc. 1984, 106, 2224-2226; B. K. Teo, M. C. Hong, H. Zhang, D. B. Huang, Angew. Chem. 1987, 99, 943-945; Angew. Chem. Int. Ed. Engl. 1987, 26, 897-900; B. K. Teo, M. Hong, H. Zhang, D. Huang, X. Shi, J. Chem. Soc. Chem. Commun. 1988, 204-206; B. K. Teo, H. Zhang, X. Shi, Inorg. Chem. 1990, 29, 2083-2091; B. K. Teo, X. Shi, H. Zhang, J. Am. Chem. Soc. 1991, 113, 4329-4331; R. C. B. Copley, D. M. P. Mingos, J. Chem. Soc. Dalton Trans. 1992, 1755; B. K. Teo, H. Zhang, Angew. Chem. 1992, 104, 447-449; Angew. Chem. Int. Ed. Engl. 1992, 31, 445-447.
17. B. K. Teo, K. Keating, J. Am. Chem. Soc. 1984, 106, 2224-2226; B. K. Teo, M. C. Hong, H. Zhang, D. B. Huang, Angew. Chem. 1987, 99, 943-945; Angew. Chem. Int. Ed. Engl. 1987, 26, 897-900; B. K. Teo, M. Hong, H. Zhang, D. Huang, X. Shi, J. Chem. Soc. Chem. Commun. 1988, 204-206; B. K. Teo, H. Zhang, X. Shi, Inorg. Chem. 1990, 29, 2083-2091; B. K. Teo, X. Shi, H. Zhang, J. Am. Chem. Soc. 1991, 113, 4329-4331; R. C. B. Copley, D. M. P. Mingos, J. Chem. Soc. Dalton Trans. 1992, 1755; B. K. Teo, H. Zhang, Angew. Chem. 1992, 104, 447-449; Angew. Chem. Int. Ed. Engl. 1992, 31, 445-447.
18. B. K. Teo, K. Keating, J. Am. Chem. Soc. 1984, 106, 2224-2226; B. K. Teo, M. C. Hong, H. Zhang, D. B. Huang, Angew. Chem. 1987, 99, 943-945; Angew. Chem. Int. Ed. Engl. 1987, 26, 897-900; B. K. Teo, M. Hong, H. Zhang, D. Huang, X. Shi, J. Chem. Soc. Chem. Commun. 1988, 204-206; B. K. Teo, H. Zhang, X. Shi, Inorg. Chem. 1990, 29, 2083-2091; B. K. Teo, X. Shi, H. Zhang, J. Am. Chem. Soc. 1991, 113, 4329-4331; R. C. B. Copley, D. M. P. Mingos, J. Chem. Soc. Dalton Trans. 1992, 1755; B. K. Teo, H. Zhang, Angew. Chem. 1992, 104, 447-449; Angew. Chem. Int. Ed. Engl. 1992, 31, 445-447.
19. B. K. Teo, K. Keating, J. Am. Chem. Soc. 1984, 106, 2224-2226; B. K. Teo, M. C. Hong, H. Zhang, D. B. Huang, Angew. Chem. 1987, 99, 943-945; Angew. Chem. Int. Ed. Engl. 1987, 26, 897-900; B. K. Teo, M. Hong, H. Zhang, D. Huang, X. Shi, J. Chem. Soc. Chem. Commun. 1988, 204-206; B. K. Teo, H. Zhang, X. Shi, Inorg. Chem. 1990, 29, 2083-2091; B. K. Teo, X. Shi, H. Zhang, J. Am. Chem. Soc. 1991, 113, 4329-4331; R. C. B. Copley, D. M. P. Mingos, J. Chem. Soc. Dalton Trans. 1992, 1755; B. K. Teo, H. Zhang, Angew. Chem. 1992, 104, 447-449; Angew. Chem. Int. Ed. Engl. 1992, 31, 445-447.
20. B. K. Teo, K. Keating, J. Am. Chem. Soc. 1984, 106, 2224-2226; B. K. Teo, M. C. Hong, H. Zhang, D. B. Huang, Angew. Chem. 1987, 99, 943-945; Angew. Chem. Int. Ed. Engl. 1987, 26, 897-900; B. K. Teo, M. Hong, H. Zhang, D. Huang, X. Shi, J. Chem. Soc. Chem. Commun. 1988, 204-206; B. K. Teo, H. Zhang, X. Shi, Inorg. Chem. 1990, 29, 2083-2091; B. K. Teo, X. Shi, H. Zhang, J. Am. Chem. Soc. 1991, 113, 4329-4331; R. C. B. Copley, D. M. P. Mingos, J. Chem. Soc. Dalton Trans. 1992, 1755; B. K. Teo, H. Zhang, Angew. Chem. 1992, 104, 447-449; Angew. Chem. Int. Ed. Engl. 1992, 31, 445-447.
21. B. K. Teo, K. Keating, J. Am. Chem. Soc. 1984, 106, 2224-2226; B. K. Teo, M. C. Hong, H. Zhang, D. B. Huang, Angew. Chem. 1987, 99, 943-945; Angew. Chem. Int. Ed. Engl. 1987, 26, 897-900; B. K. Teo, M. Hong, H. Zhang, D. Huang, X. Shi, J. Chem. Soc. Chem. Commun. 1988, 204-206; B. K. Teo, H. Zhang, X. Shi, Inorg. Chem. 1990, 29, 2083-2091; B. K. Teo, X. Shi, H. Zhang, J. Am. Chem. Soc. 1991, 113, 4329-4331; R. C. B. Copley, D. M. P. Mingos, J. Chem. Soc. Dalton Trans. 1992, 1755; B. K. Teo, H. Zhang, Angew. Chem. 1992, 104, 447-449; Angew. Chem. Int. Ed. Engl. 1992, 31, 445-447.
22. B. K. Teo, K. Keating, J. Am. Chem. Soc. 1984, 106, 2224-2226; B. K. Teo, M. C. Hong, H. Zhang, D. B. Huang, Angew. Chem. 1987, 99, 943-945; Angew. Chem. Int. Ed. Engl. 1987, 26, 897-900; B. K. Teo, M. Hong, H. Zhang, D. Huang, X. Shi, J. Chem. Soc. Chem. Commun. 1988, 204-206; B. K. Teo, H. Zhang, X. Shi, Inorg. Chem. 1990, 29, 2083-2091; B. K. Teo, X. Shi, H. Zhang, J. Am. Chem. Soc. 1991, 113, 4329-4331; R. C. B. Copley, D. M. P. Mingos, J. Chem. Soc. Dalton Trans. 1992, 1755; B. K. Teo, H. Zhang, Angew. Chem. 1992, 104, 447-449; Angew. Chem. Int. Ed. Engl. 1992, 31, 445-447.
23. B. K. Teo, K. Keating, J. Am. Chem. Soc. 1984, 106, 2224-2226; B. K. Teo, M. C. Hong, H. Zhang, D. B. Huang, Angew. Chem. 1987, 99, 943-945; Angew. Chem. Int. Ed. Engl. 1987, 26, 897-900; B. K. Teo, M. Hong, H. Zhang, D. Huang, X. Shi, J. Chem. Soc. Chem. Commun. 1988, 204-206; B. K. Teo, H. Zhang, X. Shi, Inorg. Chem. 1990, 29, 2083-2091; B. K. Teo, X. Shi, H. Zhang, J. Am. Chem. Soc. 1991, 113, 4329-4331; R. C. B. Copley, D. M. P. Mingos, J. Chem. Soc. Dalton Trans. 1992, 1755; B. K. Teo, H. Zhang, Angew. Chem. 1992, 104, 447-449; Angew. Chem. Int. Ed. Engl. 1992, 31, 445-447.
24. B. K. Teo, K. Keating, J. Am. Chem. Soc. 1984, 106, 2224-2226; B. K. Teo, M. C. Hong, H. Zhang, D. B. Huang, Angew. Chem. 1987, 99, 943-945; Angew. Chem. Int. Ed. Engl. 1987, 26, 897-900; B. K. Teo, M. Hong, H. Zhang, D. Huang, X. Shi, J. Chem. Soc. Chem. Commun. 1988, 204-206; B. K. Teo, H. Zhang, X. Shi, Inorg. Chem. 1990, 29, 2083-2091; B. K. Teo, X. Shi, H. Zhang, J. Am. Chem. Soc. 1991, 113, 4329-4331; R. C. B. Copley, D. M. P. Mingos, J. Chem. Soc. Dalton Trans. 1992, 1755; B. K. Teo, H. Zhang, Angew. Chem. 1992, 104, 447-449; Angew. Chem. Int. Ed. Engl. 1992, 31, 445-447.
25. 1 = 0.124. Further details of the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen (Germany), on quoting the depository numbers CSD-405276, CSD-405277, and CSD-405778.
26. H. Schmidbaur, J. Adlkofer, K. Schwirten, Chem. Ber. 1972, 105, 3382-3388, B. K. Teo, J. C. Calabrese, Inorg. Chem. 1976, 15, 2467-2474; M. R. Churchill, J. D. Donahue, F. J. Rotella, Inorg. Chem. 1976, 15, 2752-2758.
27. H. Schmidbaur, J. Adlkofer, K. Schwirten, Chem. Ber. 1972, 105, 3382-3388, B. K. Teo, J. C. Calabrese, Inorg. Chem. 1976, 15, 2467-2474; M. R. Churchill, J. D. Donahue, F. J. Rotella, Inorg. Chem. 1976, 15, 2752-2758.
28. H. Schmidbaur, J. Adlkofer, K. Schwirten, Chem. Ber. 1972, 105, 3382-3388, B. K. Teo, J. C. Calabrese, Inorg. Chem. 1976, 15, 2467-2474; M. R. Churchill, J. D. Donahue, F. J. Rotella, Inorg. Chem. 1976, 15, 2752-2758.
29. D. Fenske, F. Simon, Z. Anorg. Allg. Chem. 1996, 622, 45.
30. Important Ag-Ag distances in 2 [pm] (±1.4pm): Ag1-Ag2 279.5, Ag1-Ag7 299.4, Ag1-Ag8 311.6, Ag2-Ag3 288.9, Ag2-Ag4 323.1, Ag2-Ag5 289.7, Ag3-Ag4 289.5, Ag3-Ag9 279.5, Ag3-Ag10 290.1. Ag4-Ag5 283.2, Ag4-Ag12 285.5, Ag5-Ag6 275.8, Ag5-Ag14 299.0, Ag6-Ag7 288.7, Ag6-Ag14 287.8, Ag6-Ag15 275.8, Ag7-Ag8 319.4, Ag8-Ag9 279.2, Ag8-Ag17 310.1, Ag10-Ag11 287.7, Ag10-Ag19 292.7, Ag11-Ag12 291.4, Ag11-Ag19 296.9, Ag11-Ag20 297.0, Ag12-Ag13 294.2, Ag13-Ag20 298.4, Ag13-Ag14 299.1, Ag13-Ag21 281.8, Ag13-Ag23 321.4, Ag14-Ag21 296.4, Ag15-Ag16 296.6, Ag15-Ag22 281.7, Ag15-Ag23 316.9, Ag16-Ag18 288.7, Ag16-Ag17 290.3, Ag16-Ag20′ 287.4, Ag17-Ag18 308.7, Ag18-Ag19 293.3, Ag18-Ag21′ 292.1, Ag19-Ag22′ 326.7, Ag20-Ag16′ 287.9, Ag20-Ag22′ 323.4, Ag20-Ag23 318.4, Ag21-Ag22 289.8.
31. Important Ag-Ag distances in 3 [pm] (±0.4 pm): Ag1-Ag2 320.0, Ag1-Ag3 294.3, Ag1-Ag10 294.3, Ag2-Ag3 280.0, Ag2-Ag7 280.6, Ag2-Ag8 311.2, Ag3-Ag4 287.4, Ag3-Ag12 291.5, Ag4-Ag5 287.1, Ag4-Ag12 298.3, Ag4-Ag15 293.5, Ag5-Ag6 287.7, Ag5-Ag7 276.9, Ag5-Ag15 273.6, Ag6-Ag7 312.3, Ag6-Ag17 286.9, Ag7-Ag8 287.7, Ag8-Ag9 297.1, Ag8-Ag18 291.0, Ag9-Ag10 280.0, Ag9-Ag18 282.1, Ag9-Ag22 298.5, Ag10-Ag11 281.3, Ag10-Ag22 290.6, Ag11-Ag12 305.8, Ag11-Ag24 290.9, Ag12-Ag13 293.5, Ag13-Ag14 280.4, Ag13-Ag20 307.8, Ag13-Ag24 292.8, Ag13-Ag27 330.1, Ag14-Ag15 278.8, Ag14-Ag16 312.7, Ag14-Ag20 293.0, Ag14-Ag27 289.4, Ag14-Ag28 309.0, Ag15-Ag16 289.9, Ag15-Ag20 324.9, Ag16-Ag17 306.5, Ag16-Ag20 300.3, Ag16-Ag30 293.9, Ag16-Ag33 301.1, Ag10-Ag35 303.3, Ag17-Ag18 283.1, Ag17-Ag19 302.9, Ag17-Ag33 287.7, Ag18-Ag19 285.9, Ag19-Ag20 288.3, Ag19-Ag21 280.1, Ag19-Ag36 287.5, Ag20-Ag21 329.1, Ag21-Ag22 295.4, Ag21-Ag23 281.5, Ag21-Ag37 288.2, Ag22-Ag23 290.0, Ag23-Ag24 289.4, Ag23-Ag25 283.9, Ag24-Ag25 307.4, Ag25-Ag26 328.5, Ag26-Ag27 288.4, Ag26-Ag37 293.7, Ag26-Ag38 304.9, Ag27-Ag28 285.6, Ag27-Ag37 318.7, Ag28-Ag29 283.9, Ag28-Ag35 321.7, Ag28-Ag39 301.8, Ag29-Ag30 282.4, Ag29-Ag31 283.9, Ag30-Ag31 305.2, Ag30-Ag35 319.2, A231-Ag32 298.6, Ag31-Ag42 282.3, Ag32-Ag34 285.5, Ag32-Ag43 393.4, Ag33-Ag34 280.6, Ag34-Ag36 283.2, Ag34-Ag45 289.6, Ag35-Ag36 317.0, Ag36-Ag37 287.9, Ag36-Ag45 293.4, Ag37-Ag38 288.3, Ag38-Ag39 298.3, Ag39-Ag40 295.2, Ag39-Ag47 297.5, Ag40-Ag41 282.3, Ag41-Ag42 284.5, Ag41-Ag48 279.5, Ag42-Ag43 291.1, Ag42-Ag48 298.2, Ag43-Ag44 278.6, Ag44-Ag45 291.9, Ag44-Ag46 280.8, Ag44-Ag49 292.3, Ag45-Ag46 288.7, Ag46-Ag47 282.8, Ag47-Ag48 292.3, Ag47-Ag50 290.4, Ag48-Ag49 305.6, Ag45-Ag50 299.0, A49-Ag50 297.8.