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Examples of studies focussed on the unimolecular dissociation of polypeptide cations are as follows: (a) Smith, R. D.; Barinaga, C. J.; Udseth, H. R. J. Phys. Chem. 1989, 93, 5019. (b) Beu, S. C.; Senko, M. W.; Quinn, J. P.; Wampler, F. M., III; McLafferty, F. W. J. Am. Soc. Mass Spectrom. 1993, 4, 557. Smith, R. D.; Barinaga, C. J. Rapid Commun. Mass Spectrom. 1990, 4, 54. Barinaga, C. J.; Edmonds, C. G.; Udseth, H. R.; Smith, R. D. Rapid Commun. Mass Spectrom. 1989, 3, 160. (e) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Science 1990, 248, 201. (f) Feng, R.; Konishi, Y. Anal. Chem. 1993, 65, 645. (g) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1993, 65, 425. (h) Hunt, D. F.; Zhu, N.-Z.; Shabanowitz, J. Rapid Commun. Mass Spectrom. 1989, 3, 122. Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1991, 63, 2488. (j) Edmonds, C. G.; Loo, J. A.; Fields, S. M.; Barinaga, C. J.; Udseth, H. R.; Smith, R. D. In Biological Mass Spectrometry; Burlingame, A. L., McCloskey, J. A., Eds.; Elsevier: Amsterdam, 1990; pp 77-100. (k) Alexander, A. J.; Thibault, P.; Boyd, R. K.; Curtis, J. M.; Rinehart, K. L. Int. J. Mass Spectrom. Ion Processes 1990, 98, 107. Senko, M. W.; Beu, S. C.; McLafferty, F. W. Anal. Chem. 1994, 66, 415.
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Examples of studies focussed on the unimolecular dissociation of polypeptide cations are as follows: (a) Smith, R. D.; Barinaga, C. J.; Udseth, H. R. J. Phys. Chem. 1989, 93, 5019. (b) Beu, S. C.; Senko, M. W.; Quinn, J. P.; Wampler, F. M., III; McLafferty, F. W. J. Am. Soc. Mass Spectrom. 1993, 4, 557. Smith, R. D.; Barinaga, C. J. Rapid Commun. Mass Spectrom. 1990, 4, 54. Barinaga, C. J.; Edmonds, C. G.; Udseth, H. R.; Smith, R. D. Rapid Commun. Mass Spectrom. 1989, 3, 160. (e) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Science 1990, 248, 201. (f) Feng, R.; Konishi, Y. Anal. Chem. 1993, 65, 645. (g) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1993, 65, 425. (h) Hunt, D. F.; Zhu, N.-Z.; Shabanowitz, J. Rapid Commun. Mass Spectrom. 1989, 3, 122. Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1991, 63, 2488. (j) Edmonds, C. G.; Loo, J. A.; Fields, S. M.; Barinaga, C. J.; Udseth, H. R.; Smith, R. D. In Biological Mass Spectrometry; Burlingame, A. L., McCloskey, J. A., Eds.; Elsevier: Amsterdam, 1990; pp 77-100. (k) Alexander, A. J.; Thibault, P.; Boyd, R. K.; Curtis, J. M.; Rinehart, K. L. Int. J. Mass Spectrom. Ion Processes 1990, 98, 107. Senko, M. W.; Beu, S. C.; McLafferty, F. W. Anal. Chem. 1994, 66, 415.
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Examples of studies focussed on the unimolecular dissociation of polypeptide cations are as follows: (a) Smith, R. D.; Barinaga, C. J.; Udseth, H. R. J. Phys. Chem. 1989, 93, 5019. (b) Beu, S. C.; Senko, M. W.; Quinn, J. P.; Wampler, F. M., III; McLafferty, F. W. J. Am. Soc. Mass Spectrom. 1993, 4, 557. Smith, R. D.; Barinaga, C. J. Rapid Commun. Mass Spectrom. 1990, 4, 54. Barinaga, C. J.; Edmonds, C. G.; Udseth, H. R.; Smith, R. D. Rapid Commun. Mass Spectrom. 1989, 3, 160. (e) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Science 1990, 248, 201. (f) Feng, R.; Konishi, Y. Anal. Chem. 1993, 65, 645. (g) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1993, 65, 425. (h) Hunt, D. F.; Zhu, N.-Z.; Shabanowitz, J. Rapid Commun. Mass Spectrom. 1989, 3, 122. Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1991, 63, 2488. (j) Edmonds, C. G.; Loo, J. A.; Fields, S. M.; Barinaga, C. J.; Udseth, H. R.; Smith, R. D. In Biological Mass Spectrometry; Burlingame, A. L., McCloskey, J. A., Eds.; Elsevier: Amsterdam, 1990; pp 77-100. (k) Alexander, A. J.; Thibault, P.; Boyd, R. K.; Curtis, J. M.; Rinehart, K. L. Int. J. Mass Spectrom. Ion Processes 1990, 98, 107. Senko, M. W.; Beu, S. C.; McLafferty, F. W. Anal. Chem. 1994, 66, 415.
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Examples of studies focussed on the unimolecular dissociation of polypeptide cations are as follows: (a) Smith, R. D.; Barinaga, C. J.; Udseth, H. R. J. Phys. Chem. 1989, 93, 5019. (b) Beu, S. C.; Senko, M. W.; Quinn, J. P.; Wampler, F. M., III; McLafferty, F. W. J. Am. Soc. Mass Spectrom. 1993, 4, 557. Smith, R. D.; Barinaga, C. J. Rapid Commun. Mass Spectrom. 1990, 4, 54. Barinaga, C. J.; Edmonds, C. G.; Udseth, H. R.; Smith, R. D. Rapid Commun. Mass Spectrom. 1989, 3, 160. (e) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Science 1990, 248, 201. (f) Feng, R.; Konishi, Y. Anal. Chem. 1993, 65, 645. (g) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1993, 65, 425. (h) Hunt, D. F.; Zhu, N.-Z.; Shabanowitz, J. Rapid Commun. Mass Spectrom. 1989, 3, 122. Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1991, 63, 2488. (j) Edmonds, C. G.; Loo, J. A.; Fields, S. M.; Barinaga, C. J.; Udseth, H. R.; Smith, R. D. In Biological Mass Spectrometry; Burlingame, A. L., McCloskey, J. A., Eds.; Elsevier: Amsterdam, 1990; pp 77-100. (k) Alexander, A. J.; Thibault, P.; Boyd, R. K.; Curtis, J. M.; Rinehart, K. L. Int. J. Mass Spectrom. Ion Processes 1990, 98, 107. Senko, M. W.; Beu, S. C.; McLafferty, F. W. Anal. Chem. 1994, 66, 415.
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Examples of studies focussed on the unimolecular dissociation of polypeptide cations are as follows: (a) Smith, R. D.; Barinaga, C. J.; Udseth, H. R. J. Phys. Chem. 1989, 93, 5019. (b) Beu, S. C.; Senko, M. W.; Quinn, J. P.; Wampler, F. M., III; McLafferty, F. W. J. Am. Soc. Mass Spectrom. 1993, 4, 557. Smith, R. D.; Barinaga, C. J. Rapid Commun. Mass Spectrom. 1990, 4, 54. Barinaga, C. J.; Edmonds, C. G.; Udseth, H. R.; Smith, R. D. Rapid Commun. Mass Spectrom. 1989, 3, 160. (e) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Science 1990, 248, 201. (f) Feng, R.; Konishi, Y. Anal. Chem. 1993, 65, 645. (g) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1993, 65, 425. (h) Hunt, D. F.; Zhu, N.-Z.; Shabanowitz, J. Rapid Commun. Mass Spectrom. 1989, 3, 122. Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1991, 63, 2488. (j) Edmonds, C. G.; Loo, J. A.; Fields, S. M.; Barinaga, C. J.; Udseth, H. R.; Smith, R. D. In Biological Mass Spectrometry; Burlingame, A. L., McCloskey, J. A., Eds.; Elsevier: Amsterdam, 1990; pp 77-100. (k) Alexander, A. J.; Thibault, P.; Boyd, R. K.; Curtis, J. M.; Rinehart, K. L. Int. J. Mass Spectrom. Ion Processes 1990, 98, 107. Senko, M. W.; Beu, S. C.; McLafferty, F. W. Anal. Chem. 1994, 66, 415.
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Examples of studies focussed on the unimolecular dissociation of polypeptide cations are as follows: (a) Smith, R. D.; Barinaga, C. J.; Udseth, H. R. J. Phys. Chem. 1989, 93, 5019. (b) Beu, S. C.; Senko, M. W.; Quinn, J. P.; Wampler, F. M., III; McLafferty, F. W. J. Am. Soc. Mass Spectrom. 1993, 4, 557. Smith, R. D.; Barinaga, C. J. Rapid Commun. Mass Spectrom. 1990, 4, 54. Barinaga, C. J.; Edmonds, C. G.; Udseth, H. R.; Smith, R. D. Rapid Commun. Mass Spectrom. 1989, 3, 160. (e) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Science 1990, 248, 201. (f) Feng, R.; Konishi, Y. Anal. Chem. 1993, 65, 645. (g) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1993, 65, 425. (h) Hunt, D. F.; Zhu, N.-Z.; Shabanowitz, J. Rapid Commun. Mass Spectrom. 1989, 3, 122. Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1991, 63, 2488. (j) Edmonds, C. G.; Loo, J. A.; Fields, S. M.; Barinaga, C. J.; Udseth, H. R.; Smith, R. D. In Biological Mass Spectrometry; Burlingame, A. L., McCloskey, J. A., Eds.; Elsevier: Amsterdam, 1990; pp 77-100. (k) Alexander, A. J.; Thibault, P.; Boyd, R. K.; Curtis, J. M.; Rinehart, K. L. Int. J. Mass Spectrom. Ion Processes 1990, 98, 107. Senko, M. W.; Beu, S. C.; McLafferty, F. W. Anal. Chem. 1994, 66, 415.
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Examples of studies focussed on the unimolecular dissociation of polypeptide cations are as follows: (a) Smith, R. D.; Barinaga, C. J.; Udseth, H. R. J. Phys. Chem. 1989, 93, 5019. (b) Beu, S. C.; Senko, M. W.; Quinn, J. P.; Wampler, F. M., III; McLafferty, F. W. J. Am. Soc. Mass Spectrom. 1993, 4, 557. Smith, R. D.; Barinaga, C. J. Rapid Commun. Mass Spectrom. 1990, 4, 54. Barinaga, C. J.; Edmonds, C. G.; Udseth, H. R.; Smith, R. D. Rapid Commun. Mass Spectrom. 1989, 3, 160. (e) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Science 1990, 248, 201. (f) Feng, R.; Konishi, Y. Anal. Chem. 1993, 65, 645. (g) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1993, 65, 425. (h) Hunt, D. F.; Zhu, N.-Z.; Shabanowitz, J. Rapid Commun. Mass Spectrom. 1989, 3, 122. Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1991, 63, 2488. (j) Edmonds, C. G.; Loo, J. A.; Fields, S. M.; Barinaga, C. J.; Udseth, H. R.; Smith, R. D. In Biological Mass Spectrometry; Burlingame, A. L., McCloskey, J. A., Eds.; Elsevier: Amsterdam, 1990; pp 77-100. (k) Alexander, A. J.; Thibault, P.; Boyd, R. K.; Curtis, J. M.; Rinehart, K. L. Int. J. Mass Spectrom. Ion Processes 1990, 98, 107. Senko, M. W.; Beu, S. C.; McLafferty, F. W. Anal. Chem. 1994, 66, 415.
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Examples of studies focussed on the unimolecular dissociation of polypeptide cations are as follows: (a) Smith, R. D.; Barinaga, C. J.; Udseth, H. R. J. Phys. Chem. 1989, 93, 5019. (b) Beu, S. C.; Senko, M. W.; Quinn, J. P.; Wampler, F. M., III; McLafferty, F. W. J. Am. Soc. Mass Spectrom. 1993, 4, 557. Smith, R. D.; Barinaga, C. J. Rapid Commun. Mass Spectrom. 1990, 4, 54. Barinaga, C. J.; Edmonds, C. G.; Udseth, H. R.; Smith, R. D. Rapid Commun. Mass Spectrom. 1989, 3, 160. (e) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Science 1990, 248, 201. (f) Feng, R.; Konishi, Y. Anal. Chem. 1993, 65, 645. (g) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1993, 65, 425. (h) Hunt, D. F.; Zhu, N.-Z.; Shabanowitz, J. Rapid Commun. Mass Spectrom. 1989, 3, 122. Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1991, 63, 2488. (j) Edmonds, C. G.; Loo, J. A.; Fields, S. M.; Barinaga, C. J.; Udseth, H. R.; Smith, R. D. In Biological Mass Spectrometry; Burlingame, A. L., McCloskey, J. A., Eds.; Elsevier: Amsterdam, 1990; pp 77-100. (k) Alexander, A. J.; Thibault, P.; Boyd, R. K.; Curtis, J. M.; Rinehart, K. L. Int. J. Mass Spectrom. Ion Processes 1990, 98, 107. Senko, M. W.; Beu, S. C.; McLafferty, F. W. Anal. Chem. 1994, 66, 415.
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Examples of studies focussed on the unimolecular dissociation of polypeptide cations are as follows: (a) Smith, R. D.; Barinaga, C. J.; Udseth, H. R. J. Phys. Chem. 1989, 93, 5019. (b) Beu, S. C.; Senko, M. W.; Quinn, J. P.; Wampler, F. M., III; McLafferty, F. W. J. Am. Soc. Mass Spectrom. 1993, 4, 557. Smith, R. D.; Barinaga, C. J. Rapid Commun. Mass Spectrom. 1990, 4, 54. Barinaga, C. J.; Edmonds, C. G.; Udseth, H. R.; Smith, R. D. Rapid Commun. Mass Spectrom. 1989, 3, 160. (e) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Science 1990, 248, 201. (f) Feng, R.; Konishi, Y. Anal. Chem. 1993, 65, 645. (g) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1993, 65, 425. (h) Hunt, D. F.; Zhu, N.-Z.; Shabanowitz, J. Rapid Commun. Mass Spectrom. 1989, 3, 122. Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1991, 63, 2488. (j) Edmonds, C. G.; Loo, J. A.; Fields, S. M.; Barinaga, C. J.; Udseth, H. R.; Smith, R. D. In Biological Mass Spectrometry; Burlingame, A. L., McCloskey, J. A., Eds.; Elsevier: Amsterdam, 1990; pp 77-100. (k) Alexander, A. J.; Thibault, P.; Boyd, R. K.; Curtis, J. M.; Rinehart, K. L. Int. J. Mass Spectrom. Ion Processes 1990, 98, 107. Senko, M. W.; Beu, S. C.; McLafferty, F. W. Anal. Chem. 1994, 66, 415.
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Examples of studies focussed on the unimolecular dissociation of polypeptide cations are as follows: (a) Smith, R. D.; Barinaga, C. J.; Udseth, H. R. J. Phys. Chem. 1989, 93, 5019. (b) Beu, S. C.; Senko, M. W.; Quinn, J. P.; Wampler, F. M., III; McLafferty, F. W. J. Am. Soc. Mass Spectrom. 1993, 4, 557. Smith, R. D.; Barinaga, C. J. Rapid Commun. Mass Spectrom. 1990, 4, 54. Barinaga, C. J.; Edmonds, C. G.; Udseth, H. R.; Smith, R. D. Rapid Commun. Mass Spectrom. 1989, 3, 160. (e) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Science 1990, 248, 201. (f) Feng, R.; Konishi, Y. Anal. Chem. 1993, 65, 645. (g) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1993, 65, 425. (h) Hunt, D. F.; Zhu, N.-Z.; Shabanowitz, J. Rapid Commun. Mass Spectrom. 1989, 3, 122. Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1991, 63, 2488. (j) Edmonds, C. G.; Loo, J. A.; Fields, S. M.; Barinaga, C. J.; Udseth, H. R.; Smith, R. D. In Biological Mass Spectrometry; Burlingame, A. L., McCloskey, J. A., Eds.; Elsevier: Amsterdam, 1990; pp 77-100. (k) Alexander, A. J.; Thibault, P.; Boyd, R. K.; Curtis, J. M.; Rinehart, K. L. Int. J. Mass Spectrom. Ion Processes 1990, 98, 107. Senko, M. W.; Beu, S. C.; McLafferty, F. W. Anal. Chem. 1994, 66, 415.
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Examples of studies focussed on the unimolecular dissociation of polypeptide cations are as follows: (a) Smith, R. D.; Barinaga, C. J.; Udseth, H. R. J. Phys. Chem. 1989, 93, 5019. (b) Beu, S. C.; Senko, M. W.; Quinn, J. P.; Wampler, F. M., III; McLafferty, F. W. J. Am. Soc. Mass Spectrom. 1993, 4, 557. Smith, R. D.; Barinaga, C. J. Rapid Commun. Mass Spectrom. 1990, 4, 54. Barinaga, C. J.; Edmonds, C. G.; Udseth, H. R.; Smith, R. D. Rapid Commun. Mass Spectrom. 1989, 3, 160. (e) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Science 1990, 248, 201. (f) Feng, R.; Konishi, Y. Anal. Chem. 1993, 65, 645. (g) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1993, 65, 425. (h) Hunt, D. F.; Zhu, N.-Z.; Shabanowitz, J. Rapid Commun. Mass Spectrom. 1989, 3, 122. Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1991, 63, 2488. (j) Edmonds, C. G.; Loo, J. A.; Fields, S. M.; Barinaga, C. J.; Udseth, H. R.; Smith, R. D. In Biological Mass Spectrometry; Burlingame, A. L., McCloskey, J. A., Eds.; Elsevier: Amsterdam, 1990; pp 77-100. (k) Alexander, A. J.; Thibault, P.; Boyd, R. K.; Curtis, J. M.; Rinehart, K. L. Int. J. Mass Spectrom. Ion Processes 1990, 98, 107. Senko, M. W.; Beu, S. C.; McLafferty, F. W. Anal. Chem. 1994, 66, 415.
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Examples of studies focussed on the unimolecular dissociation of polypeptide cations are as follows: (a) Smith, R. D.; Barinaga, C. J.; Udseth, H. R. J. Phys. Chem. 1989, 93, 5019. (b) Beu, S. C.; Senko, M. W.; Quinn, J. P.; Wampler, F. M., III; McLafferty, F. W. J. Am. Soc. Mass Spectrom. 1993, 4, 557. Smith, R. D.; Barinaga, C. J. Rapid Commun. Mass Spectrom. 1990, 4, 54. Barinaga, C. J.; Edmonds, C. G.; Udseth, H. R.; Smith, R. D. Rapid Commun. Mass Spectrom. 1989, 3, 160. (e) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Science 1990, 248, 201. (f) Feng, R.; Konishi, Y. Anal. Chem. 1993, 65, 645. (g) Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1993, 65, 425. (h) Hunt, D. F.; Zhu, N.-Z.; Shabanowitz, J. Rapid Commun. Mass Spectrom. 1989, 3, 122. Loo, J. A.; Edmonds, C. G.; Smith, R. D. Anal. Chem. 1991, 63, 2488. (j) Edmonds, C. G.; Loo, J. A.; Fields, S. M.; Barinaga, C. J.; Udseth, H. R.; Smith, R. D. In Biological Mass Spectrometry; Burlingame, A. L., McCloskey, J. A., Eds.; Elsevier: Amsterdam, 1990; pp 77-100. (k) Alexander, A. J.; Thibault, P.; Boyd, R. K.; Curtis, J. M.; Rinehart, K. L. Int. J. Mass Spectrom. Ion Processes 1990, 98, 107. Senko, M. W.; Beu, S. C.; McLafferty, F. W. Anal. Chem. 1994, 66, 415.
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(1994)
Anal. Chem.
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, pp. 415
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Senko, M.W.1
Beu, S.C.2
McLafferty, F.W.3
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27
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Examples of studies focussed on the unimolecular dissociation of oligonucleotide anions are as follows: (a) McLuckey, S. A.; Van Berkel, G. J.; Glish, G. L. J. Am. Soc. Mass Spectrom. 1992, 3, 60. (b) McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Chem. Soc. 1993, 115, 12085. Little, D. P.; McLafferty, F. W. J. Am. Chem. Soc. 1995, 117, 6783. McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Soc. Mass Spectrom. 1994, 5, 740. (e) Little, D. P.; Chorush, R. A.; Speir, J. P.; Senko, M. W.; Kelleher, N. L.; McLafferty, F. W. J. Am. Chem. Soc. 1994, 116, 4893. (f) McLuckey, S. A.; Vaidyanathan, G.; Habibi-Goudarzi, S. J. Mass Spectrom. 1995, 30, 1222. (g) Barry, J. P.; Vouros, P.; Schepdael, A. V.; Law, S.-Y. J. Mass Spectrom. 1995, 30, 993. (h) Grain, P. F.; Gregson, J. M.; McCloskey, J. A.; Nelson, C. C.; Peltier, J. M.; Philips, D. R.; Pomerantz, S. C.; Reddy, D. M. In Mass Spectrometry in the Biological Sciences, Burlingame, A. L., Carr, S. A., Eds.; Humana Press: Totowa, NJ, 1996; p 497. (i) Boschenok, J.; Sheil, M. M. Rapid Commun. Mass Spectrom. 1996, 10 144. (j) Gentil, E.; Banoub, J. J. Mass Spectrom. 1996, 31, 83. (k) Ni, J.; Pomerantz, S. C.; Rozenski, J.; Zhang, Y.; McCloskey, J. A. Anal. Chem. 1996, 68, 1989. Wolter, M. A.; Engels, J. W. Eur. Mass Spectrom. 1995, 1, 507. McLuckey, S. A.; Vaidyanathan, G. Int. J. Mass Spectrom. Ion Processes. In Press.
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(1992)
J. Am. Soc. Mass Spectrom.
, vol.3
, pp. 60
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Van Berkel, G.J.2
Glish, G.L.3
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Examples of studies focussed on the unimolecular dissociation of oligonucleotide anions are as follows: (a) McLuckey, S. A.; Van Berkel, G. J.; Glish, G. L. J. Am. Soc. Mass Spectrom. 1992, 3, 60. (b) McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Chem. Soc. 1993, 115, 12085. Little, D. P.; McLafferty, F. W. J. Am. Chem. Soc. 1995, 117, 6783. McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Soc. Mass Spectrom. 1994, 5, 740. (e) Little, D. P.; Chorush, R. A.; Speir, J. P.; Senko, M. W.; Kelleher, N. L.; McLafferty, F. W. J. Am. Chem. Soc. 1994, 116, 4893. (f) McLuckey, S. A.; Vaidyanathan, G.; Habibi-Goudarzi, S. J. Mass Spectrom. 1995, 30, 1222. (g) Barry, J. P.; Vouros, P.; Schepdael, A. V.; Law, S.-Y. J. Mass Spectrom. 1995, 30, 993. (h) Grain, P. F.; Gregson, J. M.; McCloskey, J. A.; Nelson, C. C.; Peltier, J. M.; Philips, D. R.; Pomerantz, S. C.; Reddy, D. M. In Mass Spectrometry in the Biological Sciences, Burlingame, A. L., Carr, S. A., Eds.; Humana Press: Totowa, NJ, 1996; p 497. (i) Boschenok, J.; Sheil, M. M. Rapid Commun. Mass Spectrom. 1996, 10 144. (j) Gentil, E.; Banoub, J. J. Mass Spectrom. 1996, 31, 83. (k) Ni, J.; Pomerantz, S. C.; Rozenski, J.; Zhang, Y.; McCloskey, J. A. Anal. Chem. 1996, 68, 1989. Wolter, M. A.; Engels, J. W. Eur. Mass Spectrom. 1995, 1, 507. McLuckey, S. A.; Vaidyanathan, G. Int. J. Mass Spectrom. Ion Processes. In Press.
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Examples of studies focussed on the unimolecular dissociation of oligonucleotide anions are as follows: (a) McLuckey, S. A.; Van Berkel, G. J.; Glish, G. L. J. Am. Soc. Mass Spectrom. 1992, 3, 60. (b) McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Chem. Soc. 1993, 115, 12085. Little, D. P.; McLafferty, F. W. J. Am. Chem. Soc. 1995, 117, 6783. McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Soc. Mass Spectrom. 1994, 5, 740. (e) Little, D. P.; Chorush, R. A.; Speir, J. P.; Senko, M. W.; Kelleher, N. L.; McLafferty, F. W. J. Am. Chem. Soc. 1994, 116, 4893. (f) McLuckey, S. A.; Vaidyanathan, G.; Habibi-Goudarzi, S. J. Mass Spectrom. 1995, 30, 1222. (g) Barry, J. P.; Vouros, P.; Schepdael, A. V.; Law, S.-Y. J. Mass Spectrom. 1995, 30, 993. (h) Grain, P. F.; Gregson, J. M.; McCloskey, J. A.; Nelson, C. C.; Peltier, J. M.; Philips, D. R.; Pomerantz, S. C.; Reddy, D. M. In Mass Spectrometry in the Biological Sciences, Burlingame, A. L., Carr, S. A., Eds.; Humana Press: Totowa, NJ, 1996; p 497. (i) Boschenok, J.; Sheil, M. M. Rapid Commun. Mass Spectrom. 1996, 10 144. (j) Gentil, E.; Banoub, J. J. Mass Spectrom. 1996, 31, 83. (k) Ni, J.; Pomerantz, S. C.; Rozenski, J.; Zhang, Y.; McCloskey, J. A. Anal. Chem. 1996, 68, 1989. Wolter, M. A.; Engels, J. W. Eur. Mass Spectrom. 1995, 1, 507. McLuckey, S. A.; Vaidyanathan, G. Int. J. Mass Spectrom. Ion Processes. In Press.
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(1995)
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0001678484
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Examples of studies focussed on the unimolecular dissociation of oligonucleotide anions are as follows: (a) McLuckey, S. A.; Van Berkel, G. J.; Glish, G. L. J. Am. Soc. Mass Spectrom. 1992, 3, 60. (b) McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Chem. Soc. 1993, 115, 12085. Little, D. P.; McLafferty, F. W. J. Am. Chem. Soc. 1995, 117, 6783. McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Soc. Mass Spectrom. 1994, 5, 740. (e) Little, D. P.; Chorush, R. A.; Speir, J. P.; Senko, M. W.; Kelleher, N. L.; McLafferty, F. W. J. Am. Chem. Soc. 1994, 116, 4893. (f) McLuckey, S. A.; Vaidyanathan, G.; Habibi-Goudarzi, S. J. Mass Spectrom. 1995, 30, 1222. (g) Barry, J. P.; Vouros, P.; Schepdael, A. V.; Law, S.-Y. J. Mass Spectrom. 1995, 30, 993. (h) Grain, P. F.; Gregson, J. M.; McCloskey, J. A.; Nelson, C. C.; Peltier, J. M.; Philips, D. R.; Pomerantz, S. C.; Reddy, D. M. In Mass Spectrometry in the Biological Sciences, Burlingame, A. L., Carr, S. A., Eds.; Humana Press: Totowa, NJ, 1996; p 497. (i) Boschenok, J.; Sheil, M. M. Rapid Commun. Mass Spectrom. 1996, 10 144. (j) Gentil, E.; Banoub, J. J. Mass Spectrom. 1996, 31, 83. (k) Ni, J.; Pomerantz, S. C.; Rozenski, J.; Zhang, Y.; McCloskey, J. A. Anal. Chem. 1996, 68, 1989. Wolter, M. A.; Engels, J. W. Eur. Mass Spectrom. 1995, 1, 507. McLuckey, S. A.; Vaidyanathan, G. Int. J. Mass Spectrom. Ion Processes. In Press.
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Examples of studies focussed on the unimolecular dissociation of oligonucleotide anions are as follows: (a) McLuckey, S. A.; Van Berkel, G. J.; Glish, G. L. J. Am. Soc. Mass Spectrom. 1992, 3, 60. (b) McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Chem. Soc. 1993, 115, 12085. Little, D. P.; McLafferty, F. W. J. Am. Chem. Soc. 1995, 117, 6783. McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Soc. Mass Spectrom. 1994, 5, 740. (e) Little, D. P.; Chorush, R. A.; Speir, J. P.; Senko, M. W.; Kelleher, N. L.; McLafferty, F. W. J. Am. Chem. Soc. 1994, 116, 4893. (f) McLuckey, S. A.; Vaidyanathan, G.; Habibi-Goudarzi, S. J. Mass Spectrom. 1995, 30, 1222. (g) Barry, J. P.; Vouros, P.; Schepdael, A. V.; Law, S.-Y. J. Mass Spectrom. 1995, 30, 993. (h) Grain, P. F.; Gregson, J. M.; McCloskey, J. A.; Nelson, C. C.; Peltier, J. M.; Philips, D. R.; Pomerantz, S. C.; Reddy, D. M. In Mass Spectrometry in the Biological Sciences, Burlingame, A. L., Carr, S. A., Eds.; Humana Press: Totowa, NJ, 1996; p 497. (i) Boschenok, J.; Sheil, M. M. Rapid Commun. Mass Spectrom. 1996, 10 144. (j) Gentil, E.; Banoub, J. J. Mass Spectrom. 1996, 31, 83. (k) Ni, J.; Pomerantz, S. C.; Rozenski, J.; Zhang, Y.; McCloskey, J. A. Anal. Chem. 1996, 68, 1989. Wolter, M. A.; Engels, J. W. Eur. Mass Spectrom. 1995, 1, 507. McLuckey, S. A.; Vaidyanathan, G. Int. J. Mass Spectrom. Ion Processes. In Press.
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0029164899
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Examples of studies focussed on the unimolecular dissociation of oligonucleotide anions are as follows: (a) McLuckey, S. A.; Van Berkel, G. J.; Glish, G. L. J. Am. Soc. Mass Spectrom. 1992, 3, 60. (b) McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Chem. Soc. 1993, 115, 12085. Little, D. P.; McLafferty, F. W. J. Am. Chem. Soc. 1995, 117, 6783. McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Soc. Mass Spectrom. 1994, 5, 740. (e) Little, D. P.; Chorush, R. A.; Speir, J. P.; Senko, M. W.; Kelleher, N. L.; McLafferty, F. W. J. Am. Chem. Soc. 1994, 116, 4893. (f) McLuckey, S. A.; Vaidyanathan, G.; Habibi-Goudarzi, S. J. Mass Spectrom. 1995, 30, 1222. (g) Barry, J. P.; Vouros, P.; Schepdael, A. V.; Law, S.-Y. J. Mass Spectrom. 1995, 30, 993. (h) Grain, P. F.; Gregson, J. M.; McCloskey, J. A.; Nelson, C. C.; Peltier, J. M.; Philips, D. R.; Pomerantz, S. C.; Reddy, D. M. In Mass Spectrometry in the Biological Sciences, Burlingame, A. L., Carr, S. A., Eds.; Humana Press: Totowa, NJ, 1996; p 497. (i) Boschenok, J.; Sheil, M. M. Rapid Commun. Mass Spectrom. 1996, 10 144. (j) Gentil, E.; Banoub, J. J. Mass Spectrom. 1996, 31, 83. (k) Ni, J.; Pomerantz, S. C.; Rozenski, J.; Zhang, Y.; McCloskey, J. A. Anal. Chem. 1996, 68, 1989. Wolter, M. A.; Engels, J. W. Eur. Mass Spectrom. 1995, 1, 507. McLuckey, S. A.; Vaidyanathan, G. Int. J. Mass Spectrom. Ion Processes. In Press.
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Examples of studies focussed on the unimolecular dissociation of oligonucleotide anions are as follows: (a) McLuckey, S. A.; Van Berkel, G. J.; Glish, G. L. J. Am. Soc. Mass Spectrom. 1992, 3, 60. (b) McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Chem. Soc. 1993, 115, 12085. Little, D. P.; McLafferty, F. W. J. Am. Chem. Soc. 1995, 117, 6783. McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Soc. Mass Spectrom. 1994, 5, 740. (e) Little, D. P.; Chorush, R. A.; Speir, J. P.; Senko, M. W.; Kelleher, N. L.; McLafferty, F. W. J. Am. Chem. Soc. 1994, 116, 4893. (f) McLuckey, S. A.; Vaidyanathan, G.; Habibi-Goudarzi, S. J. Mass Spectrom. 1995, 30, 1222. (g) Barry, J. P.; Vouros, P.; Schepdael, A. V.; Law, S.-Y. J. Mass Spectrom. 1995, 30, 993. (h) Grain, P. F.; Gregson, J. M.; McCloskey, J. A.; Nelson, C. C.; Peltier, J. M.; Philips, D. R.; Pomerantz, S. C.; Reddy, D. M. In Mass Spectrometry in the Biological Sciences, Burlingame, A. L., Carr, S. A., Eds.; Humana Press: Totowa, NJ, 1996; p 497. (i) Boschenok, J.; Sheil, M. M. Rapid Commun. Mass Spectrom. 1996, 10 144. (j) Gentil, E.; Banoub, J. J. Mass Spectrom. 1996, 31, 83. (k) Ni, J.; Pomerantz, S. C.; Rozenski, J.; Zhang, Y.; McCloskey, J. A. Anal. Chem. 1996, 68, 1989. Wolter, M. A.; Engels, J. W. Eur. Mass Spectrom. 1995, 1, 507. McLuckey, S. A.; Vaidyanathan, G. Int. J. Mass Spectrom. Ion Processes. In Press.
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Law, S.-Y.4
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Examples of studies focussed on the unimolecular dissociation of oligonucleotide anions are as follows: (a) McLuckey, S. A.; Van Berkel, G. J.; Glish, G. L. J. Am. Soc. Mass Spectrom. 1992, 3, 60. (b) McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Chem. Soc. 1993, 115, 12085. Little, D. P.; McLafferty, F. W. J. Am. Chem. Soc. 1995, 117, 6783. McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Soc. Mass Spectrom. 1994, 5, 740. (e) Little, D. P.; Chorush, R. A.; Speir, J. P.; Senko, M. W.; Kelleher, N. L.; McLafferty, F. W. J. Am. Chem. Soc. 1994, 116, 4893. (f) McLuckey, S. A.; Vaidyanathan, G.; Habibi-Goudarzi, S. J. Mass Spectrom. 1995, 30, 1222. (g) Barry, J. P.; Vouros, P.; Schepdael, A. V.; Law, S.-Y. J. Mass Spectrom. 1995, 30, 993. (h) Grain, P. F.; Gregson, J. M.; McCloskey, J. A.; Nelson, C. C.; Peltier, J. M.; Philips, D. R.; Pomerantz, S. C.; Reddy, D. M. In Mass Spectrometry in the Biological Sciences, Burlingame, A. L., Carr, S. A., Eds.; Humana Press: Totowa, NJ, 1996; p 497. (i) Boschenok, J.; Sheil, M. M. Rapid Commun. Mass Spectrom. 1996, 10 144. (j) Gentil, E.; Banoub, J. J. Mass Spectrom. 1996, 31, 83. (k) Ni, J.; Pomerantz, S. C.; Rozenski, J.; Zhang, Y.; McCloskey, J. A. Anal. Chem. 1996, 68, 1989. Wolter, M. A.; Engels, J. W. Eur. Mass Spectrom. 1995, 1, 507. McLuckey, S. A.; Vaidyanathan, G. Int. J. Mass Spectrom. Ion Processes. In Press.
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Pomerantz, S.C.7
Reddy, D.M.8
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0029691295
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Examples of studies focussed on the unimolecular dissociation of oligonucleotide anions are as follows: (a) McLuckey, S. A.; Van Berkel, G. J.; Glish, G. L. J. Am. Soc. Mass Spectrom. 1992, 3, 60. (b) McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Chem. Soc. 1993, 115, 12085. Little, D. P.; McLafferty, F. W. J. Am. Chem. Soc. 1995, 117, 6783. McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Soc. Mass Spectrom. 1994, 5, 740. (e) Little, D. P.; Chorush, R. A.; Speir, J. P.; Senko, M. W.; Kelleher, N. L.; McLafferty, F. W. J. Am. Chem. Soc. 1994, 116, 4893. (f) McLuckey, S. A.; Vaidyanathan, G.; Habibi-Goudarzi, S. J. Mass Spectrom. 1995, 30, 1222. (g) Barry, J. P.; Vouros, P.; Schepdael, A. V.; Law, S.-Y. J. Mass Spectrom. 1995, 30, 993. (h) Grain, P. F.; Gregson, J. M.; McCloskey, J. A.; Nelson, C. C.; Peltier, J. M.; Philips, D. R.; Pomerantz, S. C.; Reddy, D. M. In Mass Spectrometry in the Biological Sciences, Burlingame, A. L., Carr, S. A., Eds.; Humana Press: Totowa, NJ, 1996; p 497. (i) Boschenok, J.; Sheil, M. M. Rapid Commun. Mass Spectrom. 1996, 10 144. (j) Gentil, E.; Banoub, J. J. Mass Spectrom. 1996, 31, 83. (k) Ni, J.; Pomerantz, S. C.; Rozenski, J.; Zhang, Y.; McCloskey, J. A. Anal. Chem. 1996, 68, 1989. Wolter, M. A.; Engels, J. W. Eur. Mass Spectrom. 1995, 1, 507. McLuckey, S. A.; Vaidyanathan, G. Int. J. Mass Spectrom. Ion Processes. In Press.
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Examples of studies focussed on the unimolecular dissociation of oligonucleotide anions are as follows: (a) McLuckey, S. A.; Van Berkel, G. J.; Glish, G. L. J. Am. Soc. Mass Spectrom. 1992, 3, 60. (b) McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Chem. Soc. 1993, 115, 12085. Little, D. P.; McLafferty, F. W. J. Am. Chem. Soc. 1995, 117, 6783. McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Soc. Mass Spectrom. 1994, 5, 740. (e) Little, D. P.; Chorush, R. A.; Speir, J. P.; Senko, M. W.; Kelleher, N. L.; McLafferty, F. W. J. Am. Chem. Soc. 1994, 116, 4893. (f) McLuckey, S. A.; Vaidyanathan, G.; Habibi-Goudarzi, S. J. Mass Spectrom. 1995, 30, 1222. (g) Barry, J. P.; Vouros, P.; Schepdael, A. V.; Law, S.-Y. J. Mass Spectrom. 1995, 30, 993. (h) Grain, P. F.; Gregson, J. M.; McCloskey, J. A.; Nelson, C. C.; Peltier, J. M.; Philips, D. R.; Pomerantz, S. C.; Reddy, D. M. In Mass Spectrometry in the Biological Sciences, Burlingame, A. L., Carr, S. A., Eds.; Humana Press: Totowa, NJ, 1996; p 497. (i) Boschenok, J.; Sheil, M. M. Rapid Commun. Mass Spectrom. 1996, 10 144. (j) Gentil, E.; Banoub, J. J. Mass Spectrom. 1996, 31, 83. (k) Ni, J.; Pomerantz, S. C.; Rozenski, J.; Zhang, Y.; McCloskey, J. A. Anal. Chem. 1996, 68, 1989. Wolter, M. A.; Engels, J. W. Eur. Mass Spectrom. 1995, 1, 507. McLuckey, S. A.; Vaidyanathan, G. Int. J. Mass Spectrom. Ion Processes. In Press.
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Examples of studies focussed on the unimolecular dissociation of oligonucleotide anions are as follows: (a) McLuckey, S. A.; Van Berkel, G. J.; Glish, G. L. J. Am. Soc. Mass Spectrom. 1992, 3, 60. (b) McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Chem. Soc. 1993, 115, 12085. Little, D. P.; McLafferty, F. W. J. Am. Chem. Soc. 1995, 117, 6783. McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Soc. Mass Spectrom. 1994, 5, 740. (e) Little, D. P.; Chorush, R. A.; Speir, J. P.; Senko, M. W.; Kelleher, N. L.; McLafferty, F. W. J. Am. Chem. Soc. 1994, 116, 4893. (f) McLuckey, S. A.; Vaidyanathan, G.; Habibi-Goudarzi, S. J. Mass Spectrom. 1995, 30, 1222. (g) Barry, J. P.; Vouros, P.; Schepdael, A. V.; Law, S.-Y. J. Mass Spectrom. 1995, 30, 993. (h) Grain, P. F.; Gregson, J. M.; McCloskey, J. A.; Nelson, C. C.; Peltier, J. M.; Philips, D. R.; Pomerantz, S. C.; Reddy, D. M. In Mass Spectrometry in the Biological Sciences, Burlingame, A. L., Carr, S. A., Eds.; Humana Press: Totowa, NJ, 1996; p 497. (i) Boschenok, J.; Sheil, M. M. Rapid Commun. Mass Spectrom. 1996, 10 144. (j) Gentil, E.; Banoub, J. J. Mass Spectrom. 1996, 31, 83. (k) Ni, J.; Pomerantz, S. C.; Rozenski, J.; Zhang, Y.; McCloskey, J. A. Anal. Chem. 1996, 68, 1989. Wolter, M. A.; Engels, J. W. Eur. Mass Spectrom. 1995, 1, 507. McLuckey, S. A.; Vaidyanathan, G. Int. J. Mass Spectrom. Ion Processes. In Press.
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Examples of studies focussed on the unimolecular dissociation of oligonucleotide anions are as follows: (a) McLuckey, S. A.; Van Berkel, G. J.; Glish, G. L. J. Am. Soc. Mass Spectrom. 1992, 3, 60. (b) McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Chem. Soc. 1993, 115, 12085. Little, D. P.; McLafferty, F. W. J. Am. Chem. Soc. 1995, 117, 6783. McLuckey, S. A.; Habibi-Goudarzi, S. J. Am. Soc. Mass Spectrom. 1994, 5, 740. (e) Little, D. P.; Chorush, R. A.; Speir, J. P.; Senko, M. W.; Kelleher, N. L.; McLafferty, F. W. J. Am. Chem. Soc. 1994, 116, 4893. (f) McLuckey, S. A.; Vaidyanathan, G.; Habibi-Goudarzi, S. J. Mass Spectrom. 1995, 30, 1222. (g) Barry, J. P.; Vouros, P.; Schepdael, A. V.; Law, S.-Y. J. Mass Spectrom. 1995, 30, 993. (h) Grain, P. F.; Gregson, J. M.; McCloskey, J. A.; Nelson, C. C.; Peltier, J. M.; Philips, D. R.; Pomerantz, S. C.; Reddy, D. M. In Mass Spectrometry in the Biological Sciences, Burlingame, A. L., Carr, S. A., Eds.; Humana Press: Totowa, NJ, 1996; p 497. (i) Boschenok, J.; Sheil, M. M. Rapid Commun. Mass Spectrom. 1996, 10 144. (j) Gentil, E.; Banoub, J. J. Mass Spectrom. 1996, 31, 83. (k) Ni, J.; Pomerantz, S. C.; Rozenski, J.; Zhang, Y.; McCloskey, J. A. Anal. Chem. 1996, 68, 1989. Wolter, M. A.; Engels, J. W. Eur. Mass Spectrom. 1995, 1, 507. McLuckey, S. A.; Vaidyanathan, G. Int. J. Mass Spectrom. Ion Processes. In Press.
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Under the conditions used here, in which a helium bath gas pressure of 1 mtorr is employed, modeling studies have suggested that large bioions can be internally thermalized in on the order of a few hundred microseconds. See ref 8d.
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There is evidence that suggests that the solvent molecules in ES can strip protons from multiply-protonated molecules in the desolvation process. See, for example, (a) Chait, B. T.; Chowdhury, S. K.; Katta, V. Proceedings of the 39th Conference on Mass Spectrometry and Allied Topics Nashville, TN, 1991; p 447. (b) Schnier, P. D.; Gross, D. S.; Williams, E. R. J. Am. Soc. Mass Spectrom. 1995, 6, 1086. Winger, B. E.; Light-Wahl, K. J.; Smith, R. D. J. Am. Soc. Mass Spectrom. 1992, 3, 624. Chillier, X. F. D.; Monnier, A.; Bill, H.; Gulacar, F. O.; Buchs, A.; McLuckey, S. A.; Van Berkel, G. J. Rapid Commun. Mass Spectrom. 1996, 10, 299. However, protein ions that have survived the drying process do not undergo proton transfer or clustering with either water or methanol under the conditions in which HI has been observed to attach to ubiquitin cations.
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There is evidence that suggests that the solvent molecules in ES can strip protons from multiply-protonated molecules in the desolvation process. See, for example, (a) Chait, B. T.; Chowdhury, S. K.; Katta, V. Proceedings of the 39th Conference on Mass Spectrometry and Allied Topics Nashville, TN, 1991; p 447. (b) Schnier, P. D.; Gross, D. S.; Williams, E. R. J. Am. Soc. Mass Spectrom. 1995, 6, 1086. Winger, B. E.; Light-Wahl, K. J.; Smith, R. D. J. Am. Soc. Mass Spectrom. 1992, 3, 624. Chillier, X. F. D.; Monnier, A.; Bill, H.; Gulacar, F. O.; Buchs, A.; McLuckey, S. A.; Van Berkel, G. J. Rapid Commun. Mass Spectrom. 1996, 10, 299. However, protein ions that have survived the drying process do not undergo proton transfer or clustering with either water or methanol under the conditions in which HI has been observed to attach to ubiquitin cations.
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There is evidence that suggests that the solvent molecules in ES can strip protons from multiply-protonated molecules in the desolvation process. See, for example, (a) Chait, B. T.; Chowdhury, S. K.; Katta, V. Proceedings of the 39th Conference on Mass Spectrometry and Allied Topics Nashville, TN, 1991; p 447. (b) Schnier, P. D.; Gross, D. S.; Williams, E. R. J. Am. Soc. Mass Spectrom. 1995, 6, 1086. Winger, B. E.; Light-Wahl, K. J.; Smith, R. D. J. Am. Soc. Mass Spectrom. 1992, 3, 624. Chillier, X. F. D.; Monnier, A.; Bill, H.; Gulacar, F. O.; Buchs, A.; McLuckey, S. A.; Van Berkel, G. J. Rapid Commun. Mass Spectrom. 1996, 10, 299. However, protein ions that have survived the drying process do not undergo proton transfer or clustering with either water or methanol under the conditions in which HI has been observed to attach to ubiquitin cations.
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There is evidence that suggests that the solvent molecules in ES can strip protons from multiply-protonated molecules in the desolvation process. See, for example, (a) Chait, B. T.; Chowdhury, S. K.; Katta, V. Proceedings of the 39th Conference on Mass Spectrometry and Allied Topics Nashville, TN, 1991; p 447. (b) Schnier, P. D.; Gross, D. S.; Williams, E. R. J. Am. Soc. Mass Spectrom. 1995, 6, 1086. Winger, B. E.; Light-Wahl, K. J.; Smith, R. D. J. Am. Soc. Mass Spectrom. 1992, 3, 624. Chillier, X. F. D.; Monnier, A.; Bill, H.; Gulacar, F. O.; Buchs, A.; McLuckey, S. A.; Van Berkel, G. J. Rapid Commun. Mass Spectrom. 1996, 10, 299. However, protein ions that have survived the drying process do not undergo proton transfer or clustering with either water or methanol under the conditions in which HI has been observed to attach to ubiquitin cations.
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It is not possible to create equivalent reaction conditions in solution and in the ion trap. Furthermore, the cluster ions formed in solution are highly dependent upon the electric fields present in the atmosphere/vacuum interface.
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Molecular polarizabilities were calculated according to the method of Miller and Savchik (Miller, K. J.; Savchik, J. A. J. Am. Chem. Soc. 1979, 101, 7206).
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(1979)
J. Am. Chem. Soc.
, vol.101
, pp. 7206
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Miller, K.J.1
Savchik, J.A.2
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101
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8244238861
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note
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13) are greater than that of HI.
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