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Volumn 36, Issue 4, 1997, Pages 401-404

Tracking Down Chlorophyll Breakdown in Plants: Elucidation of the Constitution of a "Fluorescent" Chlorophyll Catabolite

Author keywords

Chlorophyll degradation; Porphyrinoids; Structure elucidation

Indexed keywords


EID: 0030989742     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199704011     Document Type: Article
Times cited : (115)

References (27)
  • 5
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    • a) B. Kräutler, B. Jaun, K. Bortlik, M. Schellenberg, P. Matile, Angew. Chem. 1991, 103, 1354-1357; Angew. Chem. Int. Ed. Engl. 1991, 30, 1315-1318;
    • (1991) Angew. Chem. Int. Ed. Engl. , vol.30 , pp. 1315-1318
  • 14
    • 0642352545 scopus 로고    scopus 로고
    • note
    • max/min (rel. Δε) = 360 (sh, 0.60), 328 (1.00), 282 (-0.50), 238 (-0.67), 205 nm(-1.65).
  • 17
    • 84990113699 scopus 로고
    • a) H. Kessler, M. Gehrke, C. Griesinger, Angew. Chem. 1988, 100, 507-554; Angew. Chem. Int. Ed. Engl. 1988, 27, 490-537;
    • (1988) Angew. Chem. Int. Ed. Engl. , vol.27 , pp. 490-537
  • 20
    • 0642352544 scopus 로고    scopus 로고
    • note
    • 2O (9/1, v/v). Bn-FCC-2 from rape cotyledons was compared to 3 by means of analytical HPLC (see ref. [9a]), UV/Vis-spectroscopy, and luminescence properties.
  • 21
    • 0002532549 scopus 로고
    • Experiments by Eschenmoser and co-workers provided evidence of favorable thermodynamics for the formation of pyrrole units in tautomerization reactions of (metal-free) hydroporphyrins: A. Eschenmoser, Angew. Chem. 1988, 100, 5-40; Angew. Chem. Int. Ed. Engl. 1988, 27, 5-40. The feasibility of the tautomerization of a mixture of 4,5-seco-4,5-dioxooctahydrophytoporphyrinates related to 3 to linear tetrapyrroles structurally similar to 1 has recently been reported: N. Engel, C. Curty, A. Gossauer, Plant Physiol. Biochem. 1996, 34, 77-83.
    • (1988) Angew. Chem. , vol.100 , pp. 5-40
    • Eschenmoser, A.1
  • 22
    • 0011026647 scopus 로고
    • Experiments by Eschenmoser and co-workers provided evidence of favorable thermodynamics for the formation of pyrrole units in tautomerization reactions of (metal-free) hydroporphyrins: A. Eschenmoser, Angew. Chem. 1988, 100, 5-40; Angew. Chem. Int. Ed. Engl. 1988, 27, 5-40. The feasibility of the tautomerization of a mixture of 4,5-seco-4,5-dioxooctahydrophytoporphyrinates related to 3 to linear tetrapyrroles structurally similar to 1 has recently been reported: N. Engel, C. Curty, A. Gossauer, Plant Physiol. Biochem. 1996, 34, 77-83.
    • (1988) Angew. Chem. Int. Ed. Engl. , vol.27 , pp. 5-40
  • 23
    • 0002371956 scopus 로고    scopus 로고
    • Experiments by Eschenmoser and co-workers provided evidence of favorable thermodynamics for the formation of pyrrole units in tautomerization reactions of (metal-free) hydroporphyrins: A. Eschenmoser, Angew. Chem. 1988, 100, 5-40; Angew. Chem. Int. Ed. Engl. 1988, 27, 5-40. The feasibility of the tautomerization of a mixture of 4,5-seco-4,5-dioxooctahydrophytoporphyrinates related to 3 to linear tetrapyrroles structurally similar to 1 has recently been reported: N. Engel, C. Curty, A. Gossauer, Plant Physiol. Biochem. 1996, 34, 77-83.
    • (1996) Plant Physiol. Biochem. , vol.34 , pp. 77-83
    • Engel, N.1    Curty, C.2    Gossauer, A.3
  • 24
    • 0642321691 scopus 로고    scopus 로고
    • note
    • 2 position (as in Bn-FCC-2, 3). Accordingly, in contrast to a recent proposal by Gossauer & Engel [17 b], there is no indication of an "early" hydrolysis of this ester function occurring during the chlorphyll breakdown in plants.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.