The chemistry of peroxovanadium species in aqueous solutions. Structure and reactivity of a neutral diperoxovanadium complex as provided by 51V-NMR data, ab initio calculations and kinetic results

Journal of Molecular Catalysis A: Chemical

Volumn 120, Issue 1-3, 1997, Pages 93-99

  Conte, Valeria ^a   Di Furia, Fulvio ^a   Moro, Stefano ^a  

^a UNIVERSITY OF PADOVA   (Italy)

Author keywords

51V NMR spectroscopy; Ab initio calculations; Oxidations; Peroxovanadium complexes

Indexed keywords

EID: 0030973353     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1381-1169(96)00435-9     Document Type: Article

References (32)

1. N.D. Chasteen (Ed.), Vanadium in Biological Systems (Kluwer Academic Publishers, Dordrecht, 1990); H. Sigel and A. Sigel (Eds.), Metal Ions in Biological Systems, Vanadium and Its Role in Life, Vol. 31 (Marcel Dekker, New York, 1995).
2. N.D. Chasteen (Ed.), Vanadium in Biological Systems (Kluwer Academic Publishers, Dordrecht, 1990); H. Sigel and A. Sigel (Eds.), Metal Ions in Biological Systems, Vanadium and Its Role in Life, Vol. 31 (Marcel Dekker, New York, 1995).
3. N.D. Chasteen, Struct. Bonding 53 (1983) 104; B.R. Nechay, Ann. Rev. Toxicol. 24 (1984) 501; H. Michibata, H. Sakurai and N.D. Chasteen, in: N.D. Chasteen (Ed.), Vanadium in Biological Systems (Kluwer Academic Publishers, Dordrecht, 1990) ch. IX, p. 153.
4. N.D. Chasteen, Struct. Bonding 53 (1983) 104; B.R. Nechay, Ann. Rev. Toxicol. 24 (1984) 501; H. Michibata, H. Sakurai and N.D. Chasteen, in: N.D. Chasteen (Ed.), Vanadium in Biological Systems (Kluwer Academic Publishers, Dordrecht, 1990) ch. IX, p. 153.
5. N.D. Chasteen, Struct. Bonding 53 (1983) 104; B.R. Nechay, Ann. Rev. Toxicol. 24 (1984) 501; H. Michibata, H. Sakurai and N.D. Chasteen, in: N.D. Chasteen (Ed.), Vanadium in Biological Systems (Kluwer Academic Publishers, Dordrecht, 1990) ch. IX, p. 153.
6. V. Conte, F. Di Furia and S. Moro, J. Mol. Catal. 94 (1994) 323.
7. V. Conte, F. Di Furia and S. Moro, J. Mol. Catal. 104 (1995) 159.
8. O.W. Howarth and J.R. Hunt, J. Chem. Soc. Dalton Trans. (1979) 1388; N.J. Campbell, A.C. Dengel and W.P. Griffith, Polyhedron 8 (1989) 1379; A.S. Tracey and J.S. Jaswal, J. Am. Chem. Soc. 114 (1992) 3835.
9. O.W. Howarth and J.R. Hunt, J. Chem. Soc. Dalton Trans. (1979) 1388; N.J. Campbell, A.C. Dengel and W.P. Griffith, Polyhedron 8 (1989) 1379; A.S. Tracey and J.S. Jaswal, J. Am. Chem. Soc. 114 (1992) 3835.
10. O.W. Howarth and J.R. Hunt, J. Chem. Soc. Dalton Trans. (1979) 1388; N.J. Campbell, A.C. Dengel and W.P. Griffith, Polyhedron 8 (1989) 1379; A.S. Tracey and J.S. Jaswal, J. Am. Chem. Soc. 114 (1992) 3835.
11. F. Di Furia and G. Modena, Pure Appl. Chem. 54 (1982) 1853; F. Di Furia and G. Modena, Rev. Chem. Interm. 6 (1985) 51; R.I. De La Rosa, M.J. Claugue and A. Butler, J. Am. Chem. Soc. 114 (1992) 760; R.C. Thompson, Inorg. Chem. 22 (1983) 584; V. Conte, F. Di Furia and G. Modena, in: W. Ando (Ed.), Organic peroxides (1992) ch. 11.2, p. 559.
12. F. Di Furia and G. Modena, Pure Appl. Chem. 54 (1982) 1853; F. Di Furia and G. Modena, Rev. Chem. Interm. 6 (1985) 51; R.I. De La Rosa, M.J. Claugue and A. Butler, J. Am. Chem. Soc. 114 (1992) 760; R.C. Thompson, Inorg. Chem. 22 (1983) 584; V. Conte, F. Di Furia and G. Modena, in: W. Ando (Ed.), Organic peroxides (1992) ch. 11.2, p. 559.
13. F. Di Furia and G. Modena, Pure Appl. Chem. 54 (1982) 1853; F. Di Furia and G. Modena, Rev. Chem. Interm. 6 (1985) 51; R.I. De La Rosa, M.J. Claugue and A. Butler, J. Am. Chem. Soc. 114 (1992) 760; R.C. Thompson, Inorg. Chem. 22 (1983) 584; V. Conte, F. Di Furia and G. Modena, in: W. Ando (Ed.), Organic peroxides (1992) ch. 11.2, p. 559.
14. F. Di Furia and G. Modena, Pure Appl. Chem. 54 (1982) 1853; F. Di Furia and G. Modena, Rev. Chem. Interm. 6 (1985) 51; R.I. De La Rosa, M.J. Claugue and A. Butler, J. Am. Chem. Soc. 114 (1992) 760; R.C. Thompson, Inorg. Chem. 22 (1983) 584; V. Conte, F. Di Furia and G. Modena, in: W. Ando (Ed.), Organic peroxides (1992) ch. 11.2, p. 559.
15. F. Di Furia and G. Modena, Pure Appl. Chem. 54 (1982) 1853; F. Di Furia and G. Modena, Rev. Chem. Interm. 6 (1985) 51; R.I. De La Rosa, M.J. Claugue and A. Butler, J. Am. Chem. Soc. 114 (1992) 760; R.C. Thompson, Inorg. Chem. 22 (1983) 584; V. Conte, F. Di Furia and G. Modena, in: W. Ando (Ed.), Organic peroxides (1992) ch. 11.2, p. 559.
16. F. Secco, Inorg. Chem. 19 (1980) 2722.
17. V. Conte and F. Di Furia, in: G. Strukul (Ed.), Catalytic Oxidations with Hydrogen Peroxide as Oxidant (Kluwer Academic Publishers, Dordrecht, 1992) ch. 7, p. 223.
18. E.H. Appelman, A.W. Jache and J.V. Muntean, J. Mol. Catal. 106 (1996) 197.
19. H. Hayatsu and S. Ilida, Tetrahedron Lett. (1969) 1031.
20. R. Ducolomb, J. Cadet and R. Teoule, Bull. Soc. Chim. Fr. (1973) 1167.
21. M.N. Schuchmann and C. von Sonntag, J. Chem Soc. Perkin Trans. 2 (1983) 1525.
22. Spartan version 3.11, Wavefunction, Inc. 18401, Von Karman, #370 Irvine, CA 92715, USA.
23. M.J. Frisch, G.W. Trucks, M. Head-Gordon, P.M.W. Gill, M.W. Wong, J.B. Foresman, B.G. Johnson, H.B. Schlegel, M.A. Robb, E.S. Repogle, R. Gomperts, J.L. Andres, K. Raghavachari, J.S. Binkley, C. Gonzalez, R.L. Martin, D.J. Fox, D.J. DeFrees, J. Baker, J.J.P. Stewart and J.A. Pople, GAUSSIAN 92, Gaussian, Inc., Pittsburgh, PA (1992).
24. V. Conte, F. Di Furia and S. Moro, Gazz. Chim. Ital. 125 (1995) 563.
25. G.A. Dean, Can. J. Chem. 39 (1961) 1174; M. Orhanovich and R.G. Wilkins, J. Am. Chem. Soc. 89 (1967) 278.
26. G.A. Dean, Can. J. Chem. 39 (1961) 1174; M. Orhanovich and R.G. Wilkins, J. Am. Chem. Soc. 89 (1967) 278.
27. H. Mimoun, in: S. Patai (Ed.), The Chemistry of Peroxides (Wiley-Interscience, Chichester, 1983) ch. 15.
28. V. Conte, F. Di Furia, G. Modena and O. Bortolini, J. Org. Chem. 53 (1988) 4581.
29. A. Bagno, V. Conte, F. Di Furia and S. Moro, submitted for publication.
30. K.D. Dobbs and W.J. Hehre, J. Comput. Chem. 8 (1987) 861.
31. A.D. Becke, J. Phys. Chem. 97 (1993) 9003; N.F. Dalleska, K. Honma, L.S. Sunderlin and P.B. Armentrout, J. Phys. Chem. 97 (1993) 596.
32. A.D. Becke, J. Phys. Chem. 97 (1993) 9003; N.F. Dalleska, K. Honma, L.S. Sunderlin and P.B. Armentrout, J. Phys. Chem. 97 (1993) 596.